Iridium(IV) iodide: Difference between revisions
Content deleted Content added
No edit summary |
No edit summary |
||
| Line 37: | Line 37: | ||
==Synthesis== |
==Synthesis== |
||
Iridium(IV) iodide can be obtained by reacting dipotassium hexachloroiridate or hexachloroiridic acid with an aqueous solution of [[potassium iodide]].{{ |
Iridium(IV) iodide can be obtained by reacting dipotassium hexachloroiridate or hexachloroiridic acid with an aqueous solution of [[potassium iodide]].<ref>{{Cite web |url=https://discover.dtic.mil/tr_redirect/ |access-date=2023-10-16 |website=discover.dtic.mil |title=Studies on iridium compounds}}</ref><ref name="Kandiner" /> |
||
==Physical properties== |
==Physical properties== |
||
Iridium tetraiodide forms black crystals, does not dissolve in water and alcohol.<ref>{{cite book |last1=Comey |first1=Arthur Messenger |title=A Dictionary of Chemical Solubilities Inorganic: xx, 515 p |date=1896 |publisher=[[Macmillan & Company]] |page=193 |url=https://books.google.com/books?id=nZ8IAAAAMAAJ&dq=Iridium+tetraiodide&pg=PA193 |access-date=3 May 2023 |language=en}}</ref><ref>{{cite book |last1=Roscoe |first1=Henry Enfield |last2=Schorlemmer |first2=Carl |title=A Treatise on Chemistry |date=1895 |publisher=D. Appleton |page=445 |url=https://books.google.com/books?id=CExKAAAAYAAJ&dq=Iridium+tetraiodide&pg=PA445 |language=en}}</ref> |
Iridium tetraiodide forms black crystals, does not dissolve in water and alcohol.<ref>{{cite book |last1=Comey |first1=Arthur Messenger |title=A Dictionary of Chemical Solubilities Inorganic: xx, 515 p |date=1896 |publisher=[[Macmillan & Company]] |page=193 |url=https://books.google.com/books?id=nZ8IAAAAMAAJ&dq=Iridium+tetraiodide&pg=PA193 |access-date=3 May 2023 |language=en}}</ref><ref>{{cite book |last1=Roscoe |first1=Henry Enfield |last2=Schorlemmer |first2=Carl |title=A Treatise on Chemistry |date=1895 |publisher=D. Appleton |page=445 |url=https://books.google.com/books?id=CExKAAAAYAAJ&dq=Iridium+tetraiodide&pg=PA445 |language=en}}</ref><ref name="Alfa" /> In alkali metal iodide solutions, the compound dissolves easily to give a ruby red solution, forming complex salts.<ref name="Kandiner">{{Cite book |last=Kandiner |first=H. J. |url=https://books.google.com/books?id=mImABwAAQBAJ |title=Iridium |date=2013-09-03 |publisher=Springer-Verlag |isbn=978-3-662-12128-3 |language=de}}</ref> |
||
==Chemical properties== |
==Chemical properties== |
||
| Line 47: | Line 47: | ||
==Uses== |
==Uses== |
||
Iridium(IV) iodide can be used as a catalyst in organic chemistry.<ref>{{cite web |last1=Nobel |first1=Dominique |title=Method for preparing iridium iodides and use thereof as catalysts |url=https://patents.google.com/patent/WO1996023730A1/en |access-date=3 May 2023 |date=8 August 1996}}</ref><ref>{{cite web |title=Iridium(IV) iodide|url=https://www.alfa.com/ru/catalog/040424/ |publisher=[[Alfa Aesar]] |access-date=3 May 2023}}</ref> |
Iridium(IV) iodide can be used as a catalyst in organic chemistry.<ref>{{cite web |last1=Nobel |first1=Dominique |title=Method for preparing iridium iodides and use thereof as catalysts |url=https://patents.google.com/patent/WO1996023730A1/en |access-date=3 May 2023 |date=8 August 1996}}</ref><ref name="Alfa">{{cite web |title=Iridium(IV) iodide|url=https://www.alfa.com/ru/catalog/040424/ |publisher=[[Alfa Aesar]] |access-date=3 May 2023}}</ref> |
||
== References == |
== References == |
||
Revision as of 19:19, 16 October 2023
| Names | |
|---|---|
| Other names
Iridium(IV) iodide, tetraiodoiridium
| |
| Identifiers | |
3D model (JSmol)
|
|
| ChemSpider | |
| ECHA InfoCard | 100.029.279 |
| EC Number |
|
PubChem CID
|
|
CompTox Dashboard (EPA)
|
|
| |
| |
| Properties | |
| I4Ir | |
| Molar mass | 699.835 g·mol−1 |
| Appearance | Black powder |
| Melting point | 100 °C (212 °F; 373 K) |
| insoluble | |
| Structure | |
| hexagonal | |
| Related compounds | |
Related compounds
|
Iridium triiodide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Iridium(IV) iodide is a binary chemical compound of iridium and iodide with the chemical formula IrI
4.[1][2][3]
Synthesis
Iridium(IV) iodide can be obtained by reacting dipotassium hexachloroiridate or hexachloroiridic acid with an aqueous solution of potassium iodide.[4][5]
Physical properties
Iridium tetraiodide forms black crystals, does not dissolve in water and alcohol.[6][7][8] In alkali metal iodide solutions, the compound dissolves easily to give a ruby red solution, forming complex salts.[5]
Chemical properties
The compound decomposes when heated:[citation needed]
- IrI4 → Ir + 2I2
Uses
Iridium(IV) iodide can be used as a catalyst in organic chemistry.[9][8]
References
- ^ "CAS 7790-45-6 Iridium tetraiodide - Alfa Chemistry". alfa-chemistry.com. Retrieved 3 May 2023.
- ^ "Iridium tetraiodide". American Elements. Retrieved 3 May 2023.
- ^ Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 3507. ISBN 978-0-412-30120-9. Retrieved 3 May 2023.
- ^ "Studies on iridium compounds". discover.dtic.mil. Retrieved 2023-10-16.
- ^ a b Kandiner, H. J. (2013-09-03). Iridium (in German). Springer-Verlag. ISBN 978-3-662-12128-3.
- ^ Comey, Arthur Messenger (1896). A Dictionary of Chemical Solubilities Inorganic: xx, 515 p. Macmillan & Company. p. 193. Retrieved 3 May 2023.
- ^ Roscoe, Henry Enfield; Schorlemmer, Carl (1895). A Treatise on Chemistry. D. Appleton. p. 445.
- ^ a b "Iridium(IV) iodide". Alfa Aesar. Retrieved 3 May 2023.
- ^ Nobel, Dominique (8 August 1996). "Method for preparing iridium iodides and use thereof as catalysts". Retrieved 3 May 2023.
 | This inorganic compound–related article is a stub. You can help Wikipedia by expanding it. |