Arsenide iodide

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Arsenide iodides or iodide arsenides are compounds containing anions composed of iodide (I−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide bromides, phosphide iodides, and antimonide iodides.

List[edit]

formula system space group unit cell Å volume density comment ref
Ca2AsI trigonal R3m a=4.397, c = 22.29, Z = 3 3.76 brown [1][2]
Ca3AsI3 cubic I4132 a=12.42 3.99 colourless [1]
Cu2P1.8As1.2I2 monoclinic P21/c a = 15.477, b = 13.200, c = 15.421, β = 115.406°, Z = 16 Cu exchangeable with Ag; band gap 1.2 eV [3]
Ge38As8I8 cubic P43m a=10.611 metallic; water and air stable [4]
Ag2P1.8As1.2I2 monoclinic P21/c a = 15.84, b = 13.68, c = 15.58 and β = 117.63° Z=16 [5]
Sn24As19.3I8 cubic a=22.179 Z=8 black [6]
Sn20.5□3.5As22I8 cubic a=22.1837 low thermal conductivity [7]
Sn24AsxP19.3−xI8 x=0-16 cubic Pm3n a = 10.9358—11.1495 [8]
Sn19.3Cu4.7As22I8 cubic Pm3n a = 11.1736 Z = 1 1394.4 6.236 clathrate; Zintl; diamagnetic [9]
Sn24–x–δInxAs22–yI8 cubic Pm3n a = 11.088 (x = 0) to a = 11.343 (x = 10.7) clathrate [10]
La2AsI2 trigonal P3m1 a=4.3795 c=10.910 5.56 [11]
Hg4AsI5 orthorhombic Cmca a=11.927 b=12.128 c=19.776 Z=8 2859.0 7.025 red [12]
Hg4As2I3 cubic Pa3 a=12.999 Z=8 2196 8.06 black [13]
HgI2⋅As4S4 monoclinic P21/c a=9.433 b=14.986 c=11.624 β=127.72° Z=4 1299 4.509 orange; dec 212 °C [14]
Hg5AsS2I3 monoclinic C2/c a=13.339 b=8.444 c=13.428 β=118.352 Z=4 1331.2 7.599 black; dec 150 °C [15]
Hg3AsSe4I hexagonal P63mc a = 7.6902, c = 9.968 Z=2 red; air stable [16]
[Hg7As4](AgI3)2 cubic Pa a = 13.138 Z = 4 [17][18]
(Hg2As)2(CdI4) monoclinic P21 a=7.945, b=12.934, c=8.094, β=116.898° 741.7 [19]
[Hg7As4I3](SnI3) cubic P213 a = 13.110, Z = 4 2253.2 7.617 black [20]

References[edit]

  1. ^ a b Hadenfeldt, C.; Fester, W. (July 1982). "Reindarstellung und thermische Stabilität von Calcium-phosphid- und -arsenidiodiden: Ca3PI3, Ca3AsI3, Ca2PI und Ca2AsI". Zeitschrift für anorganische und allgemeine Chemie (in German). 490 (1): 25–30. doi:10.1002/zaac.19824900105. ISSN 0044-2313.
  2. ^ Hadenfeldt, C.; Herdejürgen, H. (February 1987). "Darstellung und Kristallstruktur der Calciumnitridhalogenide Ca2NCl und Ca2NBr". Zeitschrift für anorganische und allgemeine Chemie (in German). 545 (2): 177–183. doi:10.1002/zaac.19875450220. ISSN 0044-2313.
  3. ^ Jayasekera, Buddhimathie; Aitken, Jennifer A.; Heeg, Mary Jane; Brock, Stephanie L. (2003-02-01). "Toward an Arsenic Analogue of Hittorf's Phosphorus: Mixed Pnicogen Chains in Cu 2 P 1.8 As 1.2 I 2". Inorganic Chemistry. 42 (3): 658–660. doi:10.1021/ic0258936. ISSN 0020-1669. PMID 12562174.
  4. ^ von Schnering, Hans-Georg; Menke, Heinz (January 1972). "Ge38P8I8 and Ge38As8I8, a New Class of Compounds with Clathrate Structure". Angewandte Chemie International Edition in English. 11 (1): 43–44. doi:10.1002/anie.197200431. ISSN 0570-0833.
  5. ^ Jayasekera, Buddhimathie; Brock, Stephanie L. (2002). "Ag Ion-Exchange Reactions of Cu 2 P 3 I 2 and Cu 2 P 1.8 As 1.2 I 2". MRS Proceedings. 755: DD6.12. doi:10.1557/PROC-755-DD6.12. ISSN 0272-9172.
  6. ^ Shatruk, Mikhail M.; Kovnir, Kirill A.; Shevelkov, Andrei V.; Presniakov, Igor A.; Popovkin, Boris A. (1999-07-01). "First Tin Pnictide Halides Sn 24 P 19.3 I 8 and Sn 24 As 19.3 I 8 : Synthesis and the Clathrate-I Type of the Crystal Structure". Inorganic Chemistry. 38 (15): 3455–3457. doi:10.1021/ic990153r. ISSN 0020-1669. PMID 11671088.
  7. ^ Zaikina, Julia V.; Kovnir, Kirill A.; Sobolev, Alexei V.; Presniakov, Igor A.; Prots, Yuri; Baitinger, Michael; Schnelle, Walter; Olenev, Andrei V.; Lebedev, Oleg I.; Van Tendeloo, Gustaaf; Grin, Yuri (2007-06-15). "Sn20.5□3.5As22I8: A Largely Disordered Cationic Clathrate with a New Type of Superstructure and Abnormally Low Thermal Conductivity". Chemistry - A European Journal. 13 (18): 5090–5099. doi:10.1002/chem.200601772. PMID 17385200.
  8. ^ Kelm, E. A.; Zaikina, Yu. V.; Dikarev, E. V.; Shevelkov, A. V. (April 2009). "Distribution of phosphorus and arsenic atoms in the solid solution Sn24As x P19.3-x I8 with the structure of clathrate-I". Russian Chemical Bulletin. 58 (4): 746–750. doi:10.1007/s11172-009-0089-0. ISSN 1066-5285. S2CID 93897495.
  9. ^ Kovnir, Kirill A.; Sobolev, Alexei V.; Presniakov, Igor A.; Lebedev, Oleg I.; Van Tendeloo, Gustaaf; Schnelle, Walter; Grin, Yuri; Shevelkov, Andrei V. (2005-11-01). "Sn 19.3 Cu 4.7 As 22 I 8 : a New Clathrate-I Compound with Transition-Metal Atoms in the Cationic Framework" (PDF). Inorganic Chemistry. 44 (24): 8786–8793. doi:10.1021/ic051160k. ISSN 0020-1669. PMID 16296833.
  10. ^ Kelm, Evgeny A.; Olenev, Andrei V.; Bykov, Mikhail A.; Sobolev, Alexey V.; Presniakov, Igor A.; Kulbachinskii, Vladimir A.; Kytin, Vladimir G.; Shevelkov, Andrei V. (November 2011). "Synthesis, Crystal Structure, and Thermoelectric Properties of Clathrates in the Sn-In-As-I System". Zeitschrift für anorganische und allgemeine Chemie. 637 (13): 2059–2067. doi:10.1002/zaac.201100287.
  11. ^ Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds". Zeitschrift für Naturforschung B. 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. S2CID 95077294.
  12. ^ Oleneva, O. S.; Shestimerova, T. A.; Olenev, A. V.; Dikarev, E. V.; Shevelkov, A. V. (May 2006). "Synthesis and the crystal and electronic structure of Hg4AsI5". Russian Chemical Bulletin. 55 (5): 762–765. doi:10.1007/s11172-006-0329-5. ISSN 1066-5285. S2CID 97240594.
  13. ^ Labbé, Ph.; Ledésert, M.; Raveau, B.; Rebbah, A. (1989-08-01). "Crystal structure of Hg 4 As 2 I 3". Zeitschrift für Kristallographie - Crystalline Materials. 187 (1–4): 117–124. doi:10.1524/zkri.1989.187.14.117. ISSN 2196-7105. S2CID 101349696.
  14. ^ Bräu, Michael F.; Pfitzner, Arno (2006-07-03). "HgI2⋅As4S4: An Adduct from HgI2 Molecules and Undistorted As4S4 Cages". Angewandte Chemie International Edition. 45 (27): 4464–4467. doi:10.1002/anie.200600690. ISSN 1433-7851. PMID 16758498.
  15. ^ Liu, Yong; Zeng, Hui-Yi; Liu, Bin-Wen; Wang, Geng-E; Guo, Guo-Cong (May 2015). "Hg 5 AsS 2 I 3 – A Narrow-Band-Gap 2D Layered Compound with Different Trapped I – Anions". European Journal of Inorganic Chemistry. 2015 (14): 2402–2406. doi:10.1002/ejic.201500150. ISSN 1434-1948.
  16. ^ Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (2000-12-01). "Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure". Inorganic Chemistry. 39 (25): 5847–5850. doi:10.1021/ic0003527. ISSN 0020-1669. PMID 11151388.
  17. ^ Olenev, Andrei V.; Baranov, Alexei I.; Oleneva, Olga S.; Vorontsov, Ivan I.; Antipin, Mikhail Yu.; Shevelkov, Andrei V. (March 2003). "Synthesis, Crystal and Electronic Structure of [Hg 7 As 4 ](AgI 3 ) 2 , a Novel Supramolecular Complex with the Off-Plane AgI 3 2− Guest Anion". European Journal of Inorganic Chemistry. 2003 (6): 1053–1057. doi:10.1002/ejic.200390137. ISSN 1434-1948.
  18. ^ Borisov, S. V.; Pervukhina, N. V.; Magarill, S. A. (February 2020). "Crystallographic Analysis and Symmetry Generation for Some Structures with [As2] and [Hgn] (n = 2, 3) Cluster Groups". Journal of Structural Chemistry. 61 (2): 259–266. doi:10.1134/S0022476620020109. ISSN 0022-4766. S2CID 220540955.
  19. ^ Zou, Jian-Ping; Wu, Dong-Sheng; Huang, Shu-Ping; Zhu, Jing; Guo, Guo-Cong; Huang, Jin-Shun (March 2007). "Synthesis, crystal and band structures, and properties of a new supramolecular complex (Hg2As)2(CdI4)". Journal of Solid State Chemistry. 180 (3): 805–811. Bibcode:2007JSSCh.180..805Z. doi:10.1016/j.jssc.2006.11.018.
  20. ^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2000). "[Hg7As4I3](SnI3): Trapping the SnI31– Anion in the Cavities of the Unprecedented Mercury-Arsenic-Iodine Network". European Journal of Inorganic Chemistry. 2000 (2): 265–270. doi:10.1002/(SICI)1099-0682(200002)2000:2<265::AID-EJIC265>3.0.CO;2-A.
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