Silver chlorate: Difference between revisions

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'''Silver chlorate''' (AgClO<sub>3</sub>) forms white, tetragonal crystals. Like all chlorates, it is water-soluble and an oxidizing agent. As a simple metal salt, it is a common chemical in basic inorganic chemistry experiments. It is light-sensitive, so it must be stored in tightly closed dark-coloured containers.
'''Silver chlorate''' (AgClO<sub>3</sub>) forms white, tetragonal crystals.<ref>{{cite journal|last1=Náray-Szabó|first1=St. v.|last2=Pócza|first2=J.|title=Die Struktur des Silberchlorats AgClO3|journal=Zeitschrift für Kristallographie - Crystalline Materials|date=January 1942|volume=104|issue=1|doi=10.1524/zkri.1942.104.1.28|language=German}}</ref><ref>{{cite journal|last1=Deshpande|first1=Vilas|last2=Suryanarayana|first2=S V|last3=Frantz|first3=C|title=Tetragonal to cubic phase transition in silver chlorate|journal=Bulletin of Materials Science|date=December 1982|volume=4|issue=5|pages=563–568|doi=10.1007/BF02824963}}</ref> Like all chlorates, it is water-soluble and an oxidizing agent. As a simple metal salt, it is a common chemical in basic inorganic chemistry experiments. It is light-sensitive, so it must be stored in tightly closed dark-coloured containers.


The substance exhibits [[brisance|blasting]] properties, therefore it is sometimes use as a primary explosive.
The substance exhibits [[brisance|blasting]] properties, therefore it is sometimes use as a primary explosive.
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==References==
==References==
{{Unreferenced|date =September 2007}}
{{reflist}}
{{reflist}}



Revision as of 11:06, 1 July 2015

Silver(I) chlorate
Silver(I) chlorate
Names
Other names
chloric acid silver salt
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.122 Edit this at Wikidata
EC Number
  • 232-034-9
  • InChI=1S/Ag.ClHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1 checkY
    Key: SDLBJIZEEMKQKY-UHFFFAOYSA-M checkY
  • InChI=1/Ag.ClHO3/c;2-1(3)4/h;(H,2,3,4)/q+1;/p-1
    Key: SDLBJIZEEMKQKY-REWHXWOFAI
  • [Ag+].[O-]Cl(=O)=O
Properties
AgClO3
Molar mass 191.319 g/mol
Appearance white crystals
Density 4.443 g/cm3, solid
Melting point 230 °C (446 °F; 503 K)
Boiling point 250 °C (482 °F; 523 K)
slightly soluble
Solubility soluble in water and ethanol alcohol
Structure
tetragonal
Hazards
NFPA 704 (fire diamond)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Silver chlorate (AgClO3) forms white, tetragonal crystals.[1][2] Like all chlorates, it is water-soluble and an oxidizing agent. As a simple metal salt, it is a common chemical in basic inorganic chemistry experiments. It is light-sensitive, so it must be stored in tightly closed dark-coloured containers.

The substance exhibits blasting properties, therefore it is sometimes use as a primary explosive.

Silver(I) means silver is in its normal +1 oxidation state.

Production

Silver chlorate is produced by the reaction of silver nitrate with sodium chlorate to produce both silver chlorate and sodium nitrate.

Alternatively, it may be produced by the transmission of chlorine through a suspension of silver oxide.

See also

References

  1. ^ Náray-Szabó, St. v.; Pócza, J. (January 1942). "Die Struktur des Silberchlorats AgClO3". Zeitschrift für Kristallographie - Crystalline Materials (in German). 104 (1). doi:10.1524/zkri.1942.104.1.28.
  2. ^ Deshpande, Vilas; Suryanarayana, S V; Frantz, C (December 1982). "Tetragonal to cubic phase transition in silver chlorate". Bulletin of Materials Science. 4 (5): 563–568. doi:10.1007/BF02824963.