Strontium hydroxide

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Strontium hydroxide
Identifiers
CAS number 18480-07-4 YesY
1311-10-0 (octahydrate)
ChemSpider 79094 YesY
ChEBI CHEBI:35105 YesY
Jmol-3D images Image 1
Properties
Molecular formula Sr(OH)2
Molar mass 121.63 g/mol (anhydrous)
139.65 g/mol (monohydrate)
265.76 g/mol (octahydrate)
Appearance prismatic colourless crystals
deliquescent
Density 3.625 g/cm3 (anhydrous)
1.90 g/cm3 (octahydrate)
Melting point

375 °C (anhydrous)

Boiling point

710 °C, decomp (anhydrous)

Solubility in water 0.41 g/100 mL (0 °C)
1.77 g/100 mL (20 °C)
21.83 g/100 mL (100 °C) [1]
Solubility insoluble in acetone
soluble in acid, NH4Cl
Basicity (pKb) −2.19
Structure
Crystal structure tetragonal (octahydrate)
Hazards
EU Index Not listed
Flash point Non-flammable
Related compounds
Other anions Strontium oxide
Strontium peroxide
Other cations Beryllium hydroxide
Magnesium hydroxide
Calcium hydroxide
Barium hydroxide
 YesY (verify) (what is: YesY/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Strontium hydroxide, Sr(OH)2, is a caustic alkali composed of one strontium ion and two hydroxide ions. It is synthesized by combining a strontium salt with a strong base. Sr(OH)2 exists in anhydrous, monohydrate, or octahydrate form.

Contents

[edit] Preparation

Because Sr(OH)2 is very slightly soluble in water, its preparation can be easily carried out by the addition of a strong base such as NaOH or KOH, drop by drop to a solution of any strontium salt, most commonly Sr(NO3)2 (strontium nitrate). The Sr(OH)2 will precipitate out as a fine white powder. From here, the solution is filtered, and the Sr(OH)2 is washed with cold water and dried.[2]

[edit] Applications

Strontium hydroxide is used chiefly in the refining of beet sugar and as a stabilizer in plastic. It may be used as a source of strontium ions when the chlorine from strontium chloride is undesirable. Strontium hydroxide absorbs carbon dioxide from the air to form strontium carbonate.

[edit] Safety

Strontium hydroxide is a severe skin, eye and respiratory irritant. It is harmful if swallowed.

[edit] References

  1. ^ Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0070494398
  2. ^ Brauer, Georg (1963). Handbook Of Preparative Inorganic Chemistry. Academic Press. p. 935. 

[edit] External links

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