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Rhenium(IV) oxide

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Rhenium(IV) oxide
Names
IUPAC name
Rhenium(IV) oxide
Other names
Rhenium dioxide
Identifiers
ECHA InfoCard 100.031.659 Edit this at Wikidata
Properties
ReO2
Molar mass 218.206 g/mol
Appearance gray orthorhombic crystals
Density 11.4 g/cm³[1]
Melting point decomposes at 1000°C[2]
insoluble
Solubility in alkali insoluble
Structure
Orthorohmbic, oP12
Pbcn, No. 60
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
Related compounds
Other anions
Rhenium(VII) oxide
Rhenium(III) oxide
Rhenium(III) chloride
Other cations
manganese(IV) oxide
Technetium(VII) oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Rhenium(IV) oxide or rhenium dioxide is the chemical compound composed of rhenium and oxygen with the formula ReO2. This gray to black crystalline solid is a laboratory reagent that can be used as a catalyst. It form perrhenates with alkaline hydrogen peroxide and oxidizing acids.[3] It disproportionates when heated.[4]

References

  1. ^ Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). CRC Press. p. 484. ISBN 0-8493-0594-2. Retrieved 2008-06-05.
  2. ^ Perry, Dale L.; Phillips, Sidney L. (1995). Handbook of Inorganic Compounds. San Diego: CRC Press. p. 328. ISBN 0-8493-8671-3. Retrieved 2008-06-05.
  3. ^ http://www.aaamolybdenum.com/RheniumDioxide.html
  4. ^ http://www.chemyq.com/En/xz/xz4/34495anufv.htm