Jump to content

4-Hydroxybenzaldehyde

From Wikipedia, the free encyclopedia

This is an old revision of this page, as edited by Edgar181 (talk | contribs) at 12:38, 23 August 2012 (removed Category:Natural hydroxybenzaldehydes; added Category:Hydroxybenzaldehydes using HotCat). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

4-Hydroxybenzaldehyde
Names
IUPAC name
4-Hydroxybenzaldehyde
Other names
p-Hydroxybenzaldehyde
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard 100.004.182 Edit this at Wikidata
KEGG
UNII
  • InChI=1S/C7H6O2/c8-5-6-1-3-7(9)4-2-6/h1-5,9H checkY
    Key: RGHHSNMVTDWUBI-UHFFFAOYSA-N checkY
  • InChI=1/C7H6O2/c8-5-6-1-3-7(9)4-2-6/h1-5,9H
    Key: RGHHSNMVTDWUBI-UHFFFAOYAN
  • O=Cc1ccc(O)cc1
Properties
C7H6O2
Molar mass 122.123 g·mol−1
Appearance yellow to tan powder
Density 1.226 ± 0.06 g/cm3
Melting point 112–116 °C
Boiling point 310–311 °C
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

4-Hydroxybenzaldehyde is one of the three isomers of hydroxybenzaldehyde. It can be found in the orchids Gastrodia elata[1] and Galeola faberi.[2]

Chemistry

The Dakin oxidation is an organic redox reaction in which an ortho- or para-hydroxylated phenyl aldehyde (2-hydroxybenzaldehyde or 4-hydroxybenzaldehyde) or ketone reacts with hydrogen peroxide in base to form a benzenediol and a carboxylate. Overall, the carbonyl group is oxidized, and the hydrogen peroxide is reduced.

Metabolism

p-Hydroxybenzaldehyde dehydrogenase is an enzyme found in carrots (Daucus carota).[3]

See also

References

  1. ^ Attention: This template ({{cite doi}}) is deprecated. To cite the publication identified by doi:10.1016/S0378-8741(00)00313-5, please use {{cite journal}} (if it was published in a bona fide academic journal, otherwise {{cite report}} with |doi=10.1016/S0378-8741(00)00313-5 instead.
  2. ^ Template:Cite PMID
  3. ^ Attention: This template ({{cite doi}}) is deprecated. To cite the publication identified by doi:10.1016/j.jplph.2007.05.005, please use {{cite journal}} (if it was published in a bona fide academic journal, otherwise {{cite report}} with |doi=10.1016/j.jplph.2007.05.005 instead.