Crystal detector (radio)
A crystal detector  is an electronic component used to rectify radio frequency alternating current. The "asymmetric conduction" of crystals was discovered in 1874 by Karl Ferdinand Braun, and the first crystal detectors were used to receive radio waves by Braun and Jagadish Chandra Bose in 1894, and improved around 1904 by radio researchers such as Henry H. C. Dunwoody and G. W. Pickard, this device was used as the detector in early crystal radios, from the early twentieth century through World War II, and gave this type of radio receiver its name. Crystal radios were the most popular type of radio until the mid 1920s. The crystal detector was the first type of semiconductor diode, and in fact, one of the first semiconductor electronic devices (after photoconductors).
The physical construction of the crystal detector for radio reception commonly includes a mounting base of insulating material, two binding posts or plugs for electrical connection, a metal cup that holds a metallic mineral crystal, and a metal bracket or hardware that retains a moveable metal structure equipped with a knob and a thin wire or needle to contact the crystal with controllable spring pressure. Crystal detectors have also been made in non-adjustable mountings of cartridge form and mountings within glass protective enclosures, among others.
A natural mineral crystal forms the semiconductor side of the junction. The most common crystal used is galena (PbS, lead sulfide), a naturally occurring ore of lead, although many other minerals were also used, the more common ones were silicon, iron pyrite, molybdenite and carborundum. Galena is a semiconductor with a small bandgap of about 0.4 eV and is used without treatment directly as it is mined. However, not all galena crystals would function in a detector; galena with good detecting properties was rare and had no reliable visual characteristics distinguishing it from galena samples with poor detecting properties. A rough pebble of detecting mineral about the size of a pea is mounted in a metal cup, which forms one side of the circuit. The electrical contact between the cup and the crystal has to be good, because this contact must not act as a second rectifying junction, which will prevent the device from functioning. To make good contact with the crystal, it is either clamped with setscrews or mounted in low melting point alloy metal. Because the relatively high melting temperature of tin-lead solder can damage many crystals, a low-melting-point (well under 200 °F (93 °C)) alloy such as Wood's metal is used. One surface is left exposed to allow contact with the cat's-whisker.
The "cat's whisker", a springy piece of thin metal wire, forms the metal side of the junction. Phosphor bronze wire of about 30 gauge is commonly used because it has the optimal amount of springiness. It is mounted on an adjustable arm with an insulated handle so that the entire exposed surface of the crystal can be probed from many directions to find the most sensitive spot. Cat's whiskers in simple detectors may be straight or curved, but most manufactured cat's whiskers include a coiled section in the middle that serves as a spring. The crystal requires just the right gentle pressure by the wire; too much pressure causes the device to conduct in both directions. Precision detectors often incorporate a metal needle instead of a cat's whisker, mounted on a thumbscrew-operated leaf spring to adjust the pressure applied.
The tip of the wire contacting the surface of the crystal forms an unstable point-contact metal–semiconductor junction, forming a Schottky barrier diode. This junction conducts electric current in only one direction and resists current flowing in the other direction. In a crystal radio, its function is to rectify the radio signal, converting it from alternating current to a pulsing direct current, to extract the audio signal (modulation) from the radio frequency carrier wave. The metal whisker is the anode, and the crystal is the cathode; current flows from the whisker into the crystal but not in the other direction.
Only certain sites on the crystal surface function as rectifying junctions. The device is very sensitive to the exact geometry and pressure of contact between wire and crystal. It is therefore made adjustable, and a usable point of contact is found by trial and error before each use. The wire is suspended from a moveable arm and is dragged across the crystal face by the operator until the device begins functioning. In a crystal radio, the operator tunes the radio to a strong local station if possible and then adjusts the cat's whisker until the station or static is heard in the radio's earphones. This requires some skill and a great deal of patience; even then, a good contact is easily lost by the slightest vibration. An alternative method of adjustment is to use a battery-operated buzzer to generate a test signal. The spark produced by the buzzer's contacts functions as a weak radio transmitter whose radio waves are received by the detector. When a rectifying spot has been found on the crystal, the buzz is heard in the earphones. The buzzer is then turned off.
Historically, many other minerals and compounds besides galena were used for the crystal, the most important being iron pyrite ("fool's gold", iron disulfide, FeS2), silicon, molybdenite (MoS2), and silicon carbide (carborundum, SiC). Some were used with gold or graphite cat's whiskers. Another type had a crystal-to-crystal junction instead of a cat's whisker, with two crystals mounted facing each other. One crystal was moved forward on an adjustable mount until the crystal faces touched. The most common of these was a zincite-bornite (ZnO-Cu5FeS4) junction trade-named Perikon, but zincite-chalcopyrite, silicon-arsenic and silicon-antimony junctions were also used. The goal of researchers was to find junctions that were not as sensitive to vibration and unreliable as galena and pyrite. Some of these other junctions, particularly carborundum, were stable enough that they were equipped with a more permanent spring-loaded contact rather than a cat's whisker. For this reason, carborundum detectors were preferred for use in large commercial wireless stations and military and shipboard stations that were subject to vibration from waves and gunnery exercises. Another quality desired was the ability to withstand high currents without damage, because in communication stations the fragile detector junction could be "burned out" by atmospheric electric charge from the antenna or high radio frequency current leaking into the receiver from the powerful spark-gap transmitter during transmissions. Carborundum detectors, which used large-area contacts, were also particularly robust in this regard.
To increase sensitivity, some of these junctions such as silicon carbide were biased by connecting a battery and potentiometer across them to provide a small constant forward voltage across the junction.
The oxide layers that form on many ordinary metal surfaces have semiconducting properties, and detectors for crystal radios have been improvised from a variety of everyday objects such as rusty needles and corroded pennies. The foxhole radio  was a crystal radio receiver improvised by soldiers during World War II without access to conventional sets. It used a razor blade and a safety pin or pencil lead to form a demodulating junction. Much patience was required to find an active detecting site on the blade. Unwanted rectifying junctions that form between metal parts of radio transmitter installations are still a source for interference, because they can produce harmonics of the transmitter frequency.
Unlike modern radio stations that transmit a waveform that represents sound, the radio transmitters during the first three decades of radio transmitted information by telegraphy; the operator turned the transmitter on and off with a switch called a telegraph key to spell out messages in Morse code, consisting of different length pulses of radio waves called "dots" and "dashes". Early radio receiving apparatus merely had to detect the presence or absence of the radio signal, not convert it into audio. The detection device that did this was called a detector. The crystal detector was the most successful of many detector devices that were used in the early days of radio. It replaced earlier electrolytic, magnetic, and particularly coherer detectors in radio receivers around 1906. Later, when AM radio transmission was developed to transmit sound, around World War I, crystal detectors proved able to receive this transmission as well.
The "unilateral conduction" of crystals, as it was then called, was discovered by Ferdinand Braun, a German physicist, in 1874 at the University of Würzburg, before radio had been invented. Bengali-Indian scientist Jagadish Chandra Bose was the first to use a crystal to detect radio waves, in his pioneering experiments with microwaves in 1894, applying for a patent on a galena detector in 1901. The crystal detector was developed as a practical device mainly by G. W. Pickard. His first detector, which used a silicon crystal, was patented in 1906. At nearly the same time, Henry Harrison Chase Dunwoody, a retired general in the U.S. Army Signal Corps, patented the silicon carbide (carborundum) detector, an artificial substance created accidentally during attempts by Edward Acheson to create diamonds. Pickard tested more than 30,000 combinations of crystal and wire contacts and developed several types of detectors that saw wide use. One variation consisted of a pair of different crystals with their faces touching, such as zincite touching bornite or chalcopyrite. Pickard named this the Perikon detector, from "PERfect pIcKard cONtact". Other detectors patented by Pickard employed the common crystal iron pyrite.
The temperamental, unreliable action of the crystal detector was a barrier to its acceptance as a standard component in commercial radio equipment and was one reason for its rapid replacement by vacuum tubes after 1920. Frederick Seitz, a later semiconductor researcher, wrote:
Such variability, bordering on what seemed the mystical, plagued the early history of crystal detectors and caused many of the vacuum tube experts of a later generation to regard the art of crystal rectification as being close to disreputable.
From the earliest wireless telegraphy days of radio, well into the age of commercial AM broadcasting, unamplified radio receivers were powered only by the radio energy they picked up through their antennas. The crystal radio was the most widely used of these. Manufactured and homemade by the millions, it helped introduce radio to the public, contributing to the development of radio from an experimental hobby to an entertainment medium around 1920. After about 1920, receivers using crystal detectors were largely superseded by the first amplifying receivers, which used vacuum tubes. These did not require the fussy adjustments that crystals required, were more sensitive, and also were powerful enough to drive loudspeakers. Nevertheless, the expense of the early vacuum tubes and the batteries needed to run them meant that the crystal detector remained in commercial and military use for almost a decade more. However, by the late 1920s, radios using crystal detectors were relegated to use by hobbyists and youth groups and have been used by them as educational devices to the present day.
The point-contact semiconductor detector was subsequently resurrected around World War II because of the military requirement for microwave radar detectors. Vacuum-tube detectors do not work at microwave frequencies. The small area of the point contact minimized minority carrier storage and capacitance, making these diodes fast enough to function at radar frequencies. Silicon and germanium point-contact diodes were developed. Wartime research on p-n junctions in crystals paved the way for the invention of the point-contact transistor in 1947.
The germanium diodes that became widely available after the war proved to be as sensitive as galena and did not require any adjustment, so germanium diodes replaced crystal detectors in the few crystal radios still being made, largely putting an end to the manufacture of this antique radio component. Although crystal detectors are obsolete, modern point-contact silicon detectors are still commercially produced. Thus, the point-contact method used to make these first semiconductor diodes 100 years ago is still being used today.
Copies of original crystal detectors are still manufactured and sold, for antique radio hobbyists.
- Barretter detector
- Electrolytic detector
- List of historic technological nomenclature
- Point-contact transistor
- Reginald Fessenden
- Marx & Van Muffling (1922) Radio Reception, pp.46-49
- The Principles Underlying Radio Communication, 2nd Ed., Radio pamphlet no. 40. USA: Prepared by US National Bureau of Standards, United States Army Signal Corps. 1922. pp. 421–425.
- H. C. Torrey, C. A. Whitmer, Crystal Rectifiers, New York: McGraw-Hill, 1948, pp. 1-4
- The Concise Household Encyclopedia (ca. 1935) The Amalgamated Press, London
- Sievers, Maurice L. (2008). Crystal Clear: Vintage American Crystal Sets, Crystal Detectors, and Crystals. Sonoran Publishing. p. 6. ISBN 1-886606-01-3.
- Campbell, John W. (October 1944). "Radio Detectors and How They Work". Popular Science. New York: Popular Science Publishing Co. 145 (4): 206–209. Retrieved 2010-03-06.
- Pender, Harold; William Arthur del Mar (1922). Handbook for Electrical Engineers, 2nd Ed. New York: J. Wiley & Sons. p. 1268.
- Braun, F. (1874), "Ueber die Stromleitung durch Schwefelmetalle" [On current conduction through metal sulfides], Annalen der Physik und Chemie (in German), 153 (4): 556–563, doi:10.1002/andp.18752291207
- US 755840, Bose, Jagadis Chunder, "Detector for electrical disturbances", published September 30, 1901, issued March 29, 1904
- US 836531, Pickard, Greenleaf Whittier, "Means for receiving intelligence communicated by electric waves", published August 30, 1906, issued November 20, 1905
- Some biographical information on General Henry H.C. Dunwoody is available at: Arlington National Cemetery.
- US 837616, Dunwoody, Henry H. C., "Wireless-telegraph system", published March 23, 1906, issued December 4, 1906
- Lee, Thomas H. (2004). Planar Microwave Engineering: A practical guide to theory, measurements, and circuits. UK: Cambridge Univ. Press. pp. 297–300. ISBN 978-0-521-83526-8.
- Braun, Ernest; Stuart MacDonald (1982). Revolution in Miniature: The history and impact of semiconductor electronics, 2nd Ed. UK: Cambridge Univ. Press. pp. 11–12. ISBN 978-0-521-28903-0.
- Riordan, Michael; Lillian Hoddeson (1988). Crystal fire: the invention of the transistor and the birth of the information age. USA: W. W. Norton & Company. pp. 19–21. ISBN 0-393-31851-6.
- For example, Advanced Semiconductor Inc. (North Hollywood, California, USA) is selling Si point-contact detectors which will cover from UHF (ultra high frequency) to 16 GHz.
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- Crystal and Solid Contact Rectifiers 1909 publication describes experiments to determine the means of rectification (PDF file).
- Radio Detector Development from 1917 The Electrical Experimenter
- The Crystal Experimenters Handbook 1922 London publication devoted to point-contact diode detectors (PDF file courtesy of Lorne Clark via earlywireless.com)
- U.S. Patent 906,991 - Oscillation detector (multiple metallic sulfide detectors), Clifford D. Babcock, 1908
- U.S. Patent 912,613 - Oscillation detector and rectifier ("plated" silicon carbide detector with DC bias), G.W. Pickard, 1909
- U.S. Patent 912,726 - Oscillation receiver (fractured surface red zinc oxide (zincite) detector), G.W. Pickard, 1909
- U.S. Patent 933,263 - Oscillation device (iron pyrite detector), G.W. Pickard, 1909
- U.S. Patent 1,118,228 - Oscillation detectors (paired dissimilar minerals), G.W. Pickard, 1914