Gold monoiodide

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Template:Chembox identifiers
Gold monoiodide
Names
IUPAC name
Iodogold
Systematic IUPAC name
Gold(1+) iodide
Other names
Gold monoiodide
Properties
AuI
Appearance Yellowish to greenish-yellow powder
Density 8.25 g/cm3[1]
Structure
tetragonal, Pearson symbol tP8, Z = 4
P42/ncm (No. 138)[1]
a = 0.435, b = 0.435, c = 1.373 nm
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Gold monoiodide (AuI) is a chemical compound of gold and iodine. It is the only known binary iodide of gold. This compound is commercially available. It can be synthesized by heating gold and iodine in a sealed tube at 120°C for about four months. It decomposes when treated with hot water.[2] But its related complexes are much more stable.[3]

References

  1. ^ a b Jagodzinski H. (1959). Z. Kristallogr. 112: 80–87. {{cite journal}}: Missing or empty |title= (help)
  2. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
  3. ^ Tang, Zhongjia (1 September 1998). "Crystal Structure and Vibrational Spectra of a New Viologen Gold(I) Iodide". Inorganic Chemistry. 37 (19): 4752–4753. doi:10.1021/ic980141q. {{cite journal}}: Unknown parameter |coauthors= ignored (|author= suggested) (help)