Gold monoiodide
Names | |
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IUPAC name
Iodogold
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Systematic IUPAC name
Gold(1+) iodide | |
Other names
Gold monoiodide
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Identifiers | |
3D model (JSmol)
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ChemSpider | |
ECHA InfoCard | 100.030.584 |
PubChem CID
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UNII | |
CompTox Dashboard (EPA)
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Properties | |
AuI | |
Molar mass | 323.871 g/mol |
Appearance | Yellowish to greenish-yellow powder |
Density | 8.25 g/cm3[1] |
−91.0·10−6 cm3/mol | |
Structure | |
tetragonal, Pearson symbol tP8, Z = 4 | |
P42/ncm (No. 138)[1] | |
a = 0.435, b = 0.435, c = 1.373 nm
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Gold monoiodide (AuI) is a chemical compound of gold and iodine. This compound is commercially available. It can be synthesized by heating gold and iodine in a sealed tube at 120°C for about four months. It decomposes when treated with hot water.[2] But its related complexes are much more stable.[3]
References
- ^ a b Jagodzinski H. (1959). "Die Kristallstruktur des AuJ". Z. Kristallogr. 112: 80–87.
- ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
- ^ Tang, Zhongjia; Litvinchuk, A. P.; Lee, Hye-G.; Guloy, Arnold M. (1 September 1998). "Crystal Structure and Vibrational Spectra of a New Viologen Gold(I) Iodide". Inorganic Chemistry. 37 (19): 4752–4753. doi:10.1021/ic980141q.