Hazard symbol

"Danger of death" redirects here. For other uses, see Near-death (disambiguation).

Skull and crossbones, a common symbol for poison and other sources of lethal danger (GHS hazard pictograms).

Hazard symbols or warning symbols are recognisable symbols designed to warn about hazardous materials, locations, or objects, including electric currents, poisons, and radioactivity. The use of hazard symbols is often regulated by law and directed by standards organisations. Hazard symbols may appear with different colors, backgrounds, borders and supplemental information in order to specify the type of hazard. Warning symbols are used in many places in lieu of or addition to written warnings as they are quickly recognized (faster than reading a written warning) and more universally understood (the same symbol can be recognized as having the same meaning to speakers of different languages).

List of hazard symbols

See also: GHS hazard pictograms

Type of hazard	Unicode glyph	Unicode	Image
Generic caution	⚠	U+26A0
Poison	☠	U+2620
Ionizing radiation	☢	U+2622
Radiation – high-level source	?	?
Non-ionizing radiation	?	?
Biological hazard	☣	U+2623
Carcinogen	?	?
High voltage	⚡	U+26A1
Laser hazard	?	?
Chemical weapon	?	?
Accident	⛌	U+26CC
Disabled car	⛍	U+26CD
Icy road	⛐	U+26D0
More hazard symbols can be found on the list of GHS hazard pictograms and the list of DIN 4844-2 warning symbols

Generic warning symbol

Further information: Warning sign

German road warning symbol

On roadside warning signs, an exclamation mark is often used to draw attention to a generic warning of danger, hazards, and the unexpected. In Europe, this type of sign is used if there are no more-specific signs to denote a particular hazard. When used for traffic signs, it is accompanied by a supplementary sign describing the hazard, usually mounted under the exclamation mark.

This symbol has also been more widely adopted for generic use in many other contexts not associated with road traffic. It often appears on hazardous equipment or in instruction manuals to draw attention to a precaution, when a more-specific warning symbol is not available.

Poison symbol

Main article: Skull and crossbones (poison)

Skull and crossbones

The skull-and-crossbones symbol (☠), consisting of a human skull and two bones crossed together behind the skull, is today generally used as a warning of danger, particularly in regard to poisonous substances.

The symbol, or some variation thereof, specifically with the bones (or swords) below the skull, was also featured on the Jolly Roger, the traditional flag of European and American seagoing pirates. It is also part of the Canadian WHMIS home symbols placed on containers to warn that the contents are poisonous.

In the United States, due to concerns that the skull-and-crossbones symbol's association with pirates might encourage children to play with toxic materials, the Mr. Yuk symbol is also used to denote poison.

Ionizing radiation trefoil warning symbol

The international radiation symbol (also known as the trefoil) first appeared in 1946, at the University of California, Berkeley Radiation Laboratory. At the time, it was rendered as magenta, and was set on a blue background. The modern version used in the US is magenta against a yellow background, and it is drawn with a central circle of radius R, an internal radius of 1.5R and an external radius of 5R for the blades, which are separated from each other by 60°. The trefoil is black in the international version, which is also acceptable in the US.

The sign is commonly referred to as a radioactivity warning sign, but it is actually a warning sign of ionizing radiation. Ionizing radiation is a much broader category than radioactivity alone, as many non-radioactive sources also emit potentially dangerous levels of ionizing radiation. This includes x-ray apparatus, medical beam cannons and particle accelerators. Non-ionizing radiation can also reach potentially dangerous levels, but this warning sign is different from the trefoil ionizing radiation warning symbol.

On February 15, 2007, two groups—the International Atomic Energy Agency (IAEA) and the International Organization for Standardization (ISO)—jointly announced the adoption of a new ionizing radiation warning symbol to supplement the traditional trefoil symbol. The new symbol, to be used on sealed radiation sources, is aimed at alerting anyone, anywhere to the danger of being close to a strong source of ionizing radiation. It depicts, on a red background, a black trefoil with waves of radiation streaming from it, along with a black skull and crossbones, and a running figure with an arrow pointing away from the scene. The radiating trefoil suggests the presence of radiation, while the red background and the skull and crossbones warn of the danger. The figure running away from the scene is meant to suggest taking action to avoid the labeled material. The new symbol is not intended to be generally visible, but rather to appear on internal components of devices that house radiation sources so that if anybody attempts to disassemble such devices they will see an explicit warning not to proceed any further.

• 
  International ionizing radiation trefoil symbol
• 
  Yellow and magenta ionizing radiation trefoil used in the US
• 
  Early ionizing radiation symbol (1946)
• 
  ISO 21482 high-level sealed-source ionizing radiation symbol

Biohazard symbol

Biohazard symbol used since 1966

History

The biohazard symbol was developed by the Dow Chemical Company in 1966 for their containment products.

According to Charles Baldwin, an environmental-health engineer who contributed to its development: "We wanted something that was memorable but meaningless, so we could educate people as to what it means." In an article in Science in 1967, the symbol was presented as the new standard for all biological hazards ("biohazards"). The article explained that over 40 symbols were drawn up by Dow artists, and all of the symbols investigated had to meet a number of criteria: "(i) striking in form in order to draw immediate attention; (ii) unique and unambiguous, in order not to be confused with symbols used for other purposes; (iii) quickly recognizable and easily recalled; (iv) easily stenciled; (v) symmetrical, in order to appear identical from all angles of approach; and (vi) acceptable to groups of varying ethnic backgrounds." The chosen scored the best on nationwide testing for memorability.

It is used in the labeling of biological materials that carry a significant health risk, including viral samples and used hypodermic needles (see Sharps waste).

Geometry

All parts of the biohazard sign can be drawn with a compass and straightedge. The basic outline of the symbol is a plain trefoil, which is three circles overlapping each other equally like in a triple Venn diagram with the overlapping parts erased. The diameter of the overlapping part is equal to half the radius of the three circles. Then three inner circles are drawn in with ⅔ radius of the original circles so that it is tangent to the outside three overlapping circles. A tiny circle in center has a diameter ½ of the radius of the three inner circles, and arcs are erased at 90°, 210°, and 330°. The arcs of the inner circles and the tiny circle are connected by a line. Finally, the ring under is drawn from the distance to the perimeter of the equilateral triangle that forms between the centers of the three intersecting circles. An outer circle of the ring under is drawn and finally enclosed with the arcs from the center of the inner circles with a shorter radius from the inner circles.

Chemical hazard symbol

A chemical hazard label is a pictogram applied to containers of dangerous chemical compounds to indicate the specific risk, and thus the required precautions. There are several systems of labels, depending on the purpose, such as on the container for end use, or on a vehicle during transportation.

GHS chemical hazard symbols and statements

Main article: GHS hazard pictograms

A United Nations agency has designed GHS hazard pictograms and GHS hazard statements, intended to internationally harmonize chemical hazard warnings. Several European countries have started to implement these new global standards, but older warning symbols are still used in many parts of the world.

Europe

Main article: European hazard symbols

European standards are set by:

• CLP regulation(2008) for chemical containers, following international GHS recommendations; see European CLP/GHS hazard symbols
• European Agreement concerning the International Carriage of Dangerous Goods by Road (ADR) for additional packaging for transportation. Vehicles carrying dangerous goods must be equipped with orange signs, where the upper code number identifies the type of hazard, and the lower code number identifies the specific substance. These symbols cannot be readily interpreted without the aid of a table to translate the numerical codes.

• Examples of European warning for flammable substances
• 
  Obsolete German symbol
• 
  Another old symbol
• 
  CLP/GHS symbol
• 
  ADR European hazard sign, meaning "highly flammable" (33)—"gasoline" (1203)

Canada

Main article: Workplace Hazardous Materials Information System

United States

NFPA 704 standard hazard sticker or placard

Main article: Toxic Substances Control Act

The US-based National Fire Protection Association (NFPA) has a standard NFPA 704 using a diamond with four colored sections each with a number indicating severity 0—4 (0 for no hazard, 4 indicates a severe hazard). The red section denotes flammability. The blue section denotes health risks. Yellow represents reactivity (tendency to explode). The white section denotes special hazard information. One example of a special hazard would be the capital letter W crossed out (pictured left) indicating it is water reactant.

Non-standard warning symbols

Sign on a fence around the Beromünster Reserve Broadcasting Tower in Switzerland, warning of high voltage and lethal danger

A large number of warning symbols with non-standard designs are in use around the world.

Some warning symbols have been redesigned to be more comprehensible to children, such as the Mr. Ouch (depicting an electricity danger as a snarling, spiky creature) and Mr. Yuk (a green frowny face sticking its tongue out, to represent poison) designs in the United States.

See also

• GHS hazard pictograms, part of the United Nations Globally Harmonized System of Classification and Labelling of Chemicals; and UN number
• International Standard ISO 3864: Graphical symbols—Safety colors and safety signs
• NFPA 704 Fire Diamond
• Pictogram
• British Standard BS 5499: Graphical symbols and signs
• Canada's Workplace Hazardous Materials Information System
• Warning sign
• Dangerous goods

External links

• Hazchem Guide from The National Chemical Emergency Centre
• European Chemicals Bureau
• Directive 2001/59/EC
• Hazchem panel information