Novec 649/1230

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Novec 649/1230
Novec-1230-2D-skeletal.png
Novec-1230-3D-balls.png
Names
Preferred IUPAC name
1,1,1,2,2,4,5,5,5-Nonafluoro-4-(trifluoromethyl)pentan-3-one
Other names
FK-5-1-12 (ISO name),
C6K,
perfluoro(2-methyl-3-pentanone),
heptafluoroisopropyl pentafluoroethyl ketone,
waterless water,
dry water
Identifiers
3D model (JSmol)
Abbreviations FK
ChemSpider
ECHA InfoCard 100.103.448 Edit this at Wikidata
  • InChI=1S/C6F12O/c7-2(4(10,11)12,5(13,14)15)1(19)3(8,9)6(16,17)18 checkY
    Key: RMLFHPWPTXWZNJ-UHFFFAOYSA-N checkY
  • FC(F)(F)C(F)(C(=O)C(F)(F)C(F)(F)F)C(F)(F)F
Properties
C6F12O
Molar mass 316.046 g·mol−1
Appearance Clear, colorless
Odor Near odorless
Density 1,610 kg/m3
Melting point −108 °C (−162 °F; 165 K)
Boiling point 49 °C (120 °F; 322 K)
Vapor pressure 40.4 kPa @ 25 °C
Thermal conductivity 0.059 W/m-K
Viscosity 0.64 cP
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Novec™ 649/1230 (FK-5-1-12) are trademarked brand names for the line of electronics coolant liquids and fire protection fluid sold commercially by 3M. It is also known as “waterless water” or “dry water”. FK-5-1-12 is a fluorinated ketone with the systematic name 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-3-pentanone and the structural formula CF3CF2C(=O)CF(CF3)2, a fully-fluorinated analog of ethyl isopropyl ketone.

Applications[edit]

3M produces FK-5-1-12 under different brand names of Novec 1230 and Novec 649. These two products have different purity grades (>99% and >99.9%, respectively)[1] intended for different industrial applications.

Novec™ 1230[edit]

Novec 1230 is used as gaseous fire suppression agent in scenarios where water-based fire suppression (for example, from a fire sprinkler) would be impractical or where it could damage expensive equipment or property, such as museums, server rooms, banks, clean rooms and hospitals. It functions by rapidly removing heat to extinguish a fire before it starts. It can be used in both total/partial/localized flooding systems, and directional spray type applications; it is also used in portable extinguishers for specialized applications. The Patent for Novec 1230 as fire extinguishant has ended on July 19, 2020.[2]

Recently, it has found active use in microencapsulated form [3] [4] in the manufacture of fire-extinguishing composite materials.[5] Samsung SDI is using them to extinguish fires in the early stages of modular high-capacity storage systems (ESS) based on lithium-ion batteries for solar panels and electric vehicles. So in August 2019, Samsung SDI officially announces[6] an investment of $ 169 million in a fire extinguishing system in the form of fire-extinguishing composite materials based on microencapsulated Novec 1230. Later reports on the successful passage of the UL9540A test.

Novec™ 649[edit]

Novec 649 is a low temperature heat transfer fluid. It has been used as a full-immersion fluid in a proof of concept data center cooling system by Intel and SGI.[7] As it boils off easily due to its 49 °C (120.2 °F) boiling point, it is used in two-phase immersion cooling system with a condensing loop running cold water. Effects of evaporative cooling was utilized to remove additional heat. Novec 649 is also being considered to be used for cooling silicon photomultiplier (SiPM) sensors to −40 °C (−40 °F) in single-phase configuration as part of Large Hadron Collider’s high luminosity upgrade.[8]

Traditional Perfluorocarbons (PFCs) based compounds for cooling such as Fluorinert™ has extremely high Global Warming Potential (GWP) of over 9,000.[1] Novec 649 was chosen instead as good drop-in replacement due to having similar thermo-physical properties to Fluorinert FC-72 (perfluorohexane, C6F14) while having very low global warming potential (GWP) of 1.[1][9]

Environmental safety[edit]

Novec 649/1230 does not deplete ozone (ODP 0) and has a global warming potential of 1 (over 100 years), equivalent to that of carbon dioxide.[10] The Globally Harmonized System of Classification and Labeling of Chemicals (GHS) classifies this chemical as H412 - Harmful to aquatic life with long lasting effects.[11] Photolysis in sunlight, hydrolysis and hydration may be a significant sink of Novec 649/1230 in the environment.[12] It has very short estimated atmospheric lifetime of around five days.[13]

See also[edit]

External links[edit]

References[edit]

  1. ^ a b c "3M Novec 649 as a replacement of C6F14 in liquid cooling systems" (PDF). CERN. Retrieved April 8, 2021.
  2. ^ "Use of fluorinated ketones in fire extinguishing compositions". Google Patents. 3M Innovative Properties Co. Retrieved April 8, 2021.
  3. ^ Alexandra, Sertsova; Sergei, Krasilnikov; Lee, Sang-Sup; Kim, Jong-Sang (2019-10-31). "The Effect of Epoxy Resin on the Properties of Encapsulated Fire Extinguishing Agent". Fire Science and Engineering. 33 (5): 19–27. doi:10.7731/KIFSE.2019.33.5.019. ISSN 1738-7167.
  4. ^ "WO2020189900A1". worldwide.espacenet.com. Retrieved 2021-08-28.
  5. ^ Пожаротушащий композиционный материал на основе микрокапсулированного Novec 1230, retrieved 2021-08-28
  6. ^ Su-hyun, Song (2019-10-24). "Samsung SDI demonstrates fire-safe ESS". The Korea Herald. Retrieved 2021-08-28.
  7. ^ "Intel and SGI test full-immersion cooling for servers". ITworld. Archived from the original on 2014-04-10. Retrieved April 8, 2021.
  8. ^ "Silicon Photomultipliers in the Scintillating Fibre Tracker at the LHCb experiment" (PDF). CERN. Retrieved April 10, 2021.
  9. ^ "3M Novec fluids as alternative to perfluorocarbons for detector cooling at CERN" (PDF). CERN. Retrieved April 8, 2021.
  10. ^ "Environmental properties of Novec 1230 Fluid" (PDF). 3M. Retrieved April 8, 2021.
  11. ^ "COMPOUND SUMMARY 3-Pentanone, 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-". PubChem. Retrieved April 8, 2021.
  12. ^ "Hydrolysis and Atmospheric Oxidation Reactions of Perfluorinated Carboxylic Acid Precursors" (PDF). University of Toronto. Retrieved April 8, 2021.
  13. ^ "Technical Brief, Environmental properties of Novec 1230 Fluid" (PDF). 3M. Retrieved April 8, 2021.