Penta-graphene is a carbon allotrope composed entirely of carbon pentagons and resembling the Cairo pentagonal tiling. Penta-graphene was proposed in 2014 on the basis of analyses and simulations. Further calculations showed that it is unstable in its pure form, but can be stabilized by hydrogenation. Owing to its atomic configuration, penta-graphene has an unusually negative Poisson’s ratio and very high ideal strength believed to exceed that of a similar material, graphene.
Penta-graphene contains both sp2 and sp3 hybridized carbon atoms. Contrary to graphene, which is a good conductor of electricity, penta-graphene is an insulator with an indirect band gap of 4.1–4.3 eV. Its hydrogenated form is called penta-graphane. It has a diamond-like structure with sp3 and no sp2 bonds, and therefore a wider band gap (ca. 5.8 eV) than penta-graphene. Chiral penta-graphene nanotubes have also been studied as metastable allotropes of carbon.
- Einollahzadeh, Hamideh; Fazeli, Seyed Mahdi; Dariani, Reza Sabet (2016). "Studying the electronic and phononic structure of penta-graphane". Science and Technology of Advanced Materials. 17 (1): 610–617. arXiv: . doi:10.1080/14686996.2016.1219970. PMC . PMID 27877907.
- Zhang, S.; Zhou, J.; Wang, Q.; Chen, X.; Kawazoe, Y.; Jena, P. (2015). "Penta-graphene: A new carbon allotrope". Proceedings of the National Academy of Sciences. 112 (8): 201416591. Bibcode:2015PNAS..112.2372Z. doi:10.1073/pnas.1416591112. PMC .
- Ewels, Christopher P.; Rocquefelte, Xavier; Kroto, Harold W.; Rayson, Mark J.; Briddon, Patrick R.; Heggie, Malcolm I. (2015). "Predicting experimentally stable allotropes: Instability of penta-graphene". Proceedings of the National Academy of Sciences. 112 (51): 15609–12. Bibcode:2015PNAS..11215609E. doi:10.1073/pnas.1520402112. PMC . PMID 26644554.
- Quijano-Briones, JJ.; Fernandez_escamilla, HN; Tlahuice-Flores, Alfredo. (2017). "Chiral penta-graphene nanotubes: Structure, bonding and electronic properties". Computational and Theoretical Chemistry. 1108: 201520402. doi:10.1016/j.comptc.2017.03.019.
- Avramon, P; Demin, V; Luo, M (2015). "Translation Symmetry Breakdown in Low-Dimensional Lattices of Pentagonal Rings". J. Phys. Chem. Lett. 6 (22): 4525–4531. doi:10.1021/acs.jpclett.5b02309.
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