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Thallium(I) bromide

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This is an old revision of this page, as edited by Beetstra (talk | contribs) at 11:41, 13 December 2010 (Script assisted update of identifiers from ChemSpider, CommonChemistry and FDA for the Chem/Drugbox validation project - Updated: InChI1->InChI StdInChI StdInChIKey.). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

Thallium(I) bromide
Thallium(I) bromide
Names
Other names
Thallium monobromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.239 Edit this at Wikidata
  • InChI=1S/BrH.Tl/h1H;/q;+1/p-1
    Key: PGAPATLGJSQQBU-UHFFFAOYSA-M
  • InChI=1/BrH.Tl/h1H;/q;+1/p-1
    Key: PGAPATLGJSQQBU-REWHXWOFAZ
  • Br[Tl]
Properties
TlBr
Molar mass 284.29 g/mol
Appearance yellow-white crystalline solid
Density 7.557 g/cm3
Melting point 480 °C
Boiling point 815 °C
very slightly soluble
Related compounds
Other anions
Thallium(I) fluoride,
Thallium(I) chloride,
Thallium(I) iodide
Other cations
Indium(I) bromide,
Lead(II) bromide
Bismuth bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Thallium(I) bromide (TlBr), a chemical compound, available in an ultra-pure state is a compound semiconductor; used in room temperature X- and gamma-ray detectors and blue sensitive photodetectors; used as a real-time x-ray image sensor; also used as a standard for elemental thallium.

The crystalline structure is of cubic CsCl type at room temperature, but it lowers to the orthorombic thallium iodide type upon cooling, the transition temperature being likely affected by the impurities [1][2][3].

A Material safety data sheet (MSDS) is available at http://www.espimetals.com/msds's/thalliumbromide.pdf. Thallium is extremely toxic and a cumulative poison which can be absorbed through the skin. Acute and chronic effects include fatigue, limb pain, peripheral neuritis, joint pain, loss of hair, Central nervous System effects, diarrhea, vomiting, liver and kidney damage.

References

  1. ^ M Blackman et al "The Polymorphism of Thallium and Other Halides at Low Temperatures" Proc. Phys. Soc. 77 (1961) 471
  2. ^ A-V Mudring "Thallium Halides - New Aspects of the Stereochemical Activity of Electron Lone Pairs of Heavier Main-Group Elements" Eur. J. Inorg. Chem. 6 (2007) 882
  3. ^ R. P. Lowndes and C. H. Perry "Molecular structure and anharmonicity in thallium iodide" J. Chem. Phys. 58, 271 (1973)