Zone melting

(left) Pfann, at left, showing the first zone refining tube, Bell Labs, 1953
(right) Vertical zone refining, 1961. The induction heating coil carrying a high frequency alternating current, melts a section of the metal bar in the tube. The coil moves slowly down the tube, moving the molten zone to the end of the bar.

Crystallization
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Crystal Crystal structure Nucleation
Concepts
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Methods and technology
Boules Bridgman–Stockbarger method Van Arkel–de Boer process Czochralski method Epitaxy Flux method Fractional crystallization Fractional freezing Hydrothermal synthesis Kyropoulos method Laser-heated pedestal growth Micro-pulling-down Shaping processes in crystal growth Skull crucible Verneuil method Zone melting

Zone melting (or zone refining or floating zone process or travelling melting zone) is a group of similar methods of purifying crystals, in which a narrow region of a crystal is melted, and this molten zone is moved along the crystal. The molten region melts impure solid at its forward edge and leaves a wake of purer material solidified behind it as it moves through the ingot. The impurities concentrate in the melt, and are moved to one end of the ingot. Zone refining was invented by John Desmond Bernal and further developed by William Gardner Pfann in Bell Labs as a method to prepare high purity materials, mainly semiconductors, for manufacturing transistors. Its early use was on germanium for this purpose, but it can be extended to virtually any solute-solvent system having an appreciable concentration difference between solid and liquid phases at equilibrium. This process is also known as the float zone process, particularly in semiconductor materials processing.

A diagram of the vertical zone refining process used to grow single crystal H₂O ice from initially polycrystalline material. The convection in the melt is a result of water's density maximum at 4 °C.

Silicon crystal in the beginning of the growth process

Growing silicon crystal

A high-purity (99.999% = 5N) tantalum single crystal, made by the floating zone process (cylindrical object in the center)

Process details

The principle is that the segregation coefficient k (the ratio of an impurity in the solid phase to that in the liquid phase) is usually less than one. Therefore, at the solid/liquid boundary, the impurity atoms will diffuse to the liquid region. Thus, by passing a crystal boule through a thin section of furnace very slowly, such that only a small region of the boule is molten at any time, the impurities will be segregated at the end of the crystal. Because of the lack of impurities in the leftover regions which solidify, the boule can grow as a perfect single crystal if a seed crystal is placed at the base to initiate a chosen direction of crystal growth. When high purity is required, such as in semiconductor industry, the impure end of the boule is cut off, and the refining is repeated.

In zone refining, solutes are segregated at one end of the ingot in order to purify the remainder, or to concentrate the impurities. In zone leveling, the objective is to distribute solute evenly throughout the purified material, which may be sought in the form of a single crystal. For example, in the preparation of a transistor or diode semiconductor, an ingot of germanium is first purified by zone refining. Then a small amount of antimony is placed in the molten zone, which is passed through the pure germanium. With the proper choice of rate of heating and other variables, the antimony can be spread evenly through the germanium. This technique is also used for the preparation of silicon for use in computer chips.

Heaters

A variety of heaters can be used for zone melting, with their most important characteristic being the ability to form short molten zones that move slowly and uniformly through the ingot. Induction coils, ring-wound resistance heaters, or gas flames are common methods. Another method is to pass an electric current directly through the ingot while it is in a magnetic field, with the resulting magnetomotive force carefully set to be just equal to the weight in order to hold the liquid suspended. Optical heaters using high powered halogen or xenon lamps are used extensively in research facilities particularly for the production of insulators, but their use in industry is limited by the relatively low power of the lamps, which limits the size of crystals produced by this method. Zone melting can be done as a batch process, or it can be done continuously, with fresh impure material being continually added at one end and purer material being removed from the other, with impure zone melt being removed at whatever rate is dictated by the impurity of the feed stock.

Indirect-heating floating zone methods use an induction-heated tungsten ring to heat the ingot radiatively, and are useful when the ingot is of a high-resistivity semiconductor on which classical induction heating is ineffective.

Mathematical expression of impurity concentration

When the liquid zone moves by a distance $dx$, the number of impurities in the liquid change. Impurities are incorporated in the melting liquid and freezing solid.

$k_{O}$: Segregation coefficient

$L$: Zone length

$C_{O}$: Initial uniform impurity concentration of the rod

$C_{L}$: Concentration of impurities in the liquid

$I$: Number of impurities in the liquid

$I_{O}$: Number of impurities in zone when first formed at bottom

The number of impurities in the liquid changes in accordance with the expression below during the movement $dx$ of the molten zone

$dI=(C_{O}-k_{O}C_{L})\,dx\;$

$C_{L}=I/L\;$

$\int _{0}^{x}dx=\int _{I_{O}}^{I}{\frac {dI}{C_{O}-{\frac {k_{O}I}{L}}}}$

$I_{O}=C_{O}L\;$

$C_{S}=k_{O}I/L\;$

$C_{S}(x)=C_{O}\left(1-(1-k_{O})e^{-{\frac {k_{O}x}{L}}}\right)$

Applications

Solar cells

In solar cells float zone processing is particularly useful because the single crystal silicon grown has desirable properties. The bulk charge carrier lifetime in float-zone silicon is the highest among various manufacturing processes. Float-zone carrier lifetimes are around 1000 microseconds compared to 20-200 microseconds with Czochralski process, and 1–30 microseconds with cast multi-crystalline silicon. A longer bulk lifetime increases the efficiency of solar cells significantly.

Related processes

Zone remelting

Another related process is zone remelting, in which two solutes are distributed through a pure metal. This is important in the manufacture of semiconductors, where two solutes of opposite conductivity type are used. For example, in germanium, pentavalent elements of group V such as antimony and arsenic produce negative (n-type) conduction and the trivalent elements of group III such as aluminum and boron produce positive (p-type) conduction. By melting a portion of such an ingot and slowly refreezing it, solutes in the molten region become distributed to form the desired n-p and p-n junctions.

See also

• Float-zone silicon
• Fractional freezing
• Freeze distillation
• Laser-heated pedestal growth
• Wafer (electronics)
• Verneuil process
• Melting
• Melting point
• Heat
• Pressure
• Phase diagram
• List of chemical elements

References

• William G. Pfann (1966) Zone Melting, 2nd edition, John Wiley & Sons.
• Hermann Schildknecht (1966) Zone Melting, Verlag Chemie.
• Georg Müller (1988) Crystal growth from the melt Springer-Verlag, Science 138 pages ISBN 3-540-18603-4, ISBN 978-3-540-18603-8