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Polycrystalline silicon

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Left side: solar cells made of polycrystalline silicon Right side: polysilicon rod (top) and chunks (bottom)

Polycrystalline silicon, or multicrystalline silicon, also called polysilicon, poly-Si, or mc-Si, is a high purity, polycrystalline form of silicon, used as a raw material by the solar photovoltaic and electronics industry.

Polysilicon is produced from metallurgical grade silicon by a chemical purification process, called the Siemens process. This process involves distillation of volatile silicon compounds, and their decomposition into silicon at high temperatures. An emerging, alternative process of refinement uses a fluidized bed reactor. The photovoltaic industry also produces upgraded metallurgical-grade silicon (UMG-Si), using metallurgical instead of chemical purification processes.[1] When produced for the electronics industry, polysilicon contains impurity levels of less than one part per billion (ppb), while polycrystalline solar grade silicon (SoG-Si) is generally less pure. In the 2010's, production shifted toward China, with China-based companies accounting for seven of the top ten producers and around 90% of total worldwide production capacity of approximately 1,400,000 MT. German, US and South Korea companies account for the remainder. [2]

The polysilicon feedstock – large rods, usually broken into chunks of specific sizes and packaged in clean rooms before shipment – is directly cast into multicrystalline ingots or submitted to a recrystallization process to grow single crystal boules. The boules are then sliced into thin silicon wafers and used for the production of solar cells, integrated circuits and other semiconductor devices.

Polysilicon consists of small crystals, also known as crystallites, giving the material its typical metal flake effect. While polysilicon and multisilicon are often used as synonyms, multicrystalline usually refers to crystals larger than one millimetre. Multicrystalline solar cells are the most common type of solar cells in the fast-growing PV market and consume most of the worldwide produced polysilicon. About 5 tons of polysilicon is required to manufacture one 1 megawatt (MW) of conventional solar modules.[3][citation needed] Polysilicon is distinct from monocrystalline silicon and amorphous silicon.

Vs monocrystalline silicon

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Comparing polycrystalline (left) to monocrystalline (right) solar cells

In single-crystal silicon, also known as monocrystalline silicon, the crystalline framework is homogeneous, which can be recognized by an even external colouring.[4] The entire sample is one single, continuous and unbroken crystal as its structure contains no grain boundaries. Large single crystals are rare in nature and can also be difficult to produce in the laboratory (see also recrystallisation). In contrast, in an amorphous structure the order in atomic positions is limited to short range.

Polycrystalline and paracrystalline phases are composed of a number of smaller crystals or crystallites. Polycrystalline silicon (or semi-crystalline silicon, polysilicon, poly-Si, or simply "poly") is a material consisting of multiple small silicon crystals. Polycrystalline cells can be recognized by a visible grain, a "metal flake effect". Semiconductor grade (also solar grade) polycrystalline silicon is converted to single-crystal silicon – meaning that the randomly associated crystallites of silicon in polycrystalline silicon are converted to a large single crystal. Single-crystal silicon is used to manufacture most Si-based microelectronic devices. Polycrystalline silicon can be as much as 99.9999% pure.[5] Ultra-pure poly is used in the semiconductor industry, starting from poly rods that are two to three meters in length. In the microelectronics industry (semiconductor industry), poly is used at both the macro and micro scales. Single crystals are grown using the Czochralski, zone melting and Bridgman–Stockbarger methods.

Components

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A rod of semiconductor-grade polysilicon

At the component level, polysilicon has long been used as the conducting gate material in MOSFET and CMOS processing technologies. For these technologies it is deposited using low-pressure chemical-vapour deposition (LPCVD) reactors at high temperatures and is usually heavily doped n-type or p-type.

More recently, intrinsic and doped polysilicon is being used in large-area electronics as the active and/or doped layers in thin-film transistors. Although it can be deposited by LPCVD, plasma-enhanced chemical vapour deposition (PECVD), or solid-phase crystallization of amorphous silicon in certain processing regimes, these processes still require relatively high temperatures of at least 300 °C. These temperatures make deposition of polysilicon possible for glass substrates but not for plastic substrates.

The deposition of polycrystalline silicon on plastic substrates is motivated by the desire to be able to manufacture digital displays on flexible screens. Therefore, a relatively new technique called laser crystallization has been devised to crystallize a precursor amorphous silicon (a-Si) material on a plastic substrate without melting or damaging the plastic. Short, high-intensity ultraviolet laser pulses are used to heat the deposited a-Si material to above the melting point of silicon, without melting the entire substrate.

Polycrystalline silicon (used to produce silicon monocrystals by Czochralski process)

The molten silicon will then crystallize as it cools. By precisely controlling the temperature gradients, researchers have been able to grow very large grains, of up to hundreds of micrometers in size in the extreme case, although grain sizes of 10 nanometers to 1 micrometer are also common. In order to create devices on polysilicon over large-areas, however, a crystal grain size smaller than the device feature size is needed for homogeneity of the devices. Another method to produce poly-Si at low temperatures is metal-induced crystallization where an amorphous-Si thin film can be crystallized at temperatures as low as 150 °C if annealed while in contact of another metal film such as aluminium, gold, or silver.

Polysilicon has many applications in VLSI manufacturing. One of its primary uses is as gate electrode material for MOS devices. A polysilicon gate's electrical conductivity may be increased by depositing a metal (such as tungsten) or a metal silicide (such as tungsten silicide) over the gate. Polysilicon may also be employed as a resistor, a conductor, or as an ohmic contact for shallow junctions, with the desired electrical conductivity attained by doping the polysilicon material.

One major difference between polysilicon and a-Si is that the mobility of the charge carriers of the polysilicon can be orders of magnitude larger and the material also shows greater stability under electric field and light-induced stress. This allows more complex, high-speed circuitry to be created on the glass substrate along with the a-Si devices, which are still needed for their low-leakage characteristics. When polysilicon and a-Si devices are used in the same process, this is called hybrid processing. A complete polysilicon active layer process is also used in some cases where a small pixel size is required, such as in projection displays.

Feedstock for PV industry

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Main article: Crystalline silicon

Polycrystalline silicon is the key feedstock in the crystalline silicon based photovoltaic industry and used for the production of conventional solar cells. For the first time, in 2006, over half of the world's supply of polysilicon was being used by PV manufacturers.[6] The solar industry was severely hindered by a shortage in supply of polysilicon feedstock and was forced to idle about a quarter of its cell and module manufacturing capacity in 2007.[7] Only twelve factories were known to produce solar-grade polysilicon in 2008; however, by 2013 the number increased to over 100 manufacturers.[8] Monocrystalline silicon is higher priced and a more efficient semiconductor than polycrystalline as it has undergone additional recrystallization via the Czochralski method.

Deposition methods

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Polysilicon deposition, or the process of depositing a layer of polycrystalline silicon on a semiconductor wafer, is achieved by the chemical decomposition of silane (SiH4) at high temperatures of 580 to 650 °C. This pyrolysis process releases hydrogen.

SiH
4(g) → Si(s) + 2 H
2(g) CVD at 500-800°C[9]

Polysilicon layers can be deposited using 100% silane at a pressure of 25–130 Pa (0.19–0.98 Torr) or with 20–30% silane (diluted in nitrogen) at the same total pressure. Both of these processes can deposit polysilicon on 10–200 wafers per run, at a rate of 10–20 nm/min and with thickness uniformities of ±5%. Critical process variables for polysilicon deposition include temperature, pressure, silane concentration, and dopant concentration. Wafer spacing and load size have been shown to have only minor effects on the deposition process. The rate of polysilicon deposition increases rapidly with temperature, since it follows Arrhenius behavior, that is deposition rate = A·exp(–qEa/kT) where q is electron charge and k is the Boltzmann constant. The activation energy (Ea) for polysilicon deposition is about 1.7 eV. Based on this equation, the rate of polysilicon deposition increases as the deposition temperature increases. There will be a minimum temperature, however, wherein the rate of deposition becomes faster than the rate at which unreacted silane arrives at the surface. Beyond this temperature, the deposition rate can no longer increase with temperature, since it is now being hampered by lack of silane from which the polysilicon will be generated. Such a reaction is then said to be "mass-transport-limited". When a polysilicon deposition process becomes mass-transport-limited, the reaction rate becomes dependent primarily on reactant concentration, reactor geometry, and gas flow.

When the rate at which polysilicon deposition occurs is slower than the rate at which unreacted silane arrives, then it is said to be surface-reaction-limited. A deposition process that is surface-reaction-limited is primarily dependent on reactant concentration and reaction temperature. Deposition processes must be surface-reaction-limited because they result in excellent thickness uniformity and step coverage. A plot of the logarithm of the deposition rate against the reciprocal of the absolute temperature in the surface-reaction-limited region results in a straight line whose slope is equal to –qEa/k.

At reduced pressure levels for VLSI manufacturing, polysilicon deposition rate below 575 °C is too slow to be practical. Above 650 °C, poor deposition uniformity and excessive roughness will be encountered due to unwanted gas-phase reactions and silane depletion. Pressure can be varied inside a low-pressure reactor either by changing the pumping speed or changing the inlet gas flow into the reactor. If the inlet gas is composed of both silane and nitrogen, the inlet gas flow, and hence the reactor pressure, may be varied either by changing the nitrogen flow at constant silane flow, or changing both the nitrogen and silane flow to change the total gas flow while keeping the gas ratio constant. Recent investigations have shown that e-beam evaporation, followed by SPC (if needed) can be a cost-effective and faster alternative for producing solar-grade poly-Si thin films.[10] Modules produced by such method are shown to have a photovoltaic efficiency of ~6%.[11]

Polysilicon doping, if needed, is also done during the deposition process, usually by adding phosphine, arsine, or diborane. Adding phosphine or arsine results in slower deposition, while adding diborane increases the deposition rate. The deposition thickness uniformity usually degrades when dopants are added during deposition.

Siemens process

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"Siemens process" redirects here. For other uses, see Chemical vapor deposition § Polysilicon, and Siemens–Martin process.
Schematic diagram of the traditional Siemens and the fluidized bed reactor purification process

The Siemens process is the most commonly used method of polysilicon production, especially for electronics,[12] with close to 75% of the world's production using this process as of 2005.[13]

The process converts metallurgical-grade Si, of approximately 98% purity, to SiHCl3 and then to silicon in a reactor, thus removing transition metal and dopant impurities.[12] The process is relatively expensive and slow.[12]

It is a type of chemical vapor deposition process.[14]

Upgraded metallurgical-grade silicon

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Upgraded metallurgical-grade (UMG) silicon (also known as UMG-Si) for solar cells is being produced as a low cost alternative to polysilicon created by the Siemens process. UMG-Si greatly reduces impurities in a variety of ways that require less equipment and energy than the Siemens process.[15] It is about 99% pure which is three or more orders of magnitude less pure and about 10 times less expensive than polysilicon ($1.70 to $3.20 per kg from 2005 to 2008 compared to $40 to $400 per kg for polysilicon). It has the potential to provide nearly-as-good solar cell efficiency at 1/5 the capital expenditure, half the energy requirements, and less than $15/kg.[16]

In 2008 several companies were touting the potential of UMG-Si, but in 2010 the credit crisis greatly lowered the cost of polysilicon and several UMG-Si producers put plans on hold.[17][18] The Siemens process will remain the dominant form of production for years to come due to more efficiently implementing the Siemens process. GT Solar claims a new Siemens process can produce at $27/kg and may reach $20/kg in 5 years. GCL-Poly expects production costs to be $20/kg by end of 2011.[19] Elkem Solar estimates their UMG costs to be $25/kg, with a capacity of 6,000 tonnes by the end of 2010. Calisolar expects UMG technology to produce at $12/kg in 5 years with boron at 0.3 ppm and phosphorus at 0.6 ppm.[20] At $50/kg and 7.5 g/W, module manufacturers spend $0.37/W for the polysilicon. For comparison, if a CdTe manufacturer pays spot price for tellurium ($420/kg in April 2010) and has a 3 μm thickness, their cost would be 10 times less, $0.037/Watt. At 0.1 g/W and $31/ozt for silver, polysilicon solar producers spend $0.10/W on silver.[21]

Q-Cells, Canadian Solar, and Calisolar have used Timminco UMG. Timminco is able to produce UMG-Si with 0.5 ppm boron for $21/kg but were sued by shareholders because they had expected $10/kg.[22] RSI and Dow Corning have also been in litigation over UMG-Si technology.[23]

Potential applications

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A picture of grain boundaries for polysilicon. Each grain is crystalline over the width of the grain. The grain boundary separates the grains where the adjoining grain is at a different orientation from its neighbor. The grain boundary separates regions of different crystal structure thus serving as a center for recombination. 'd' here is a characteristic grain size, which should be maximized for maximum solar cell efficiency. Typical values of d are about 1 micrometre.

Currently, polysilicon is commonly used for the conducting gate materials in semiconductor devices such as MOSFETs; however, it has potential for large-scale photovoltaic devices.[24][25] The abundance, stability, and low toxicity of silicon, combined with the low cost of polysilicon relative to single crystals makes this variety of material attractive for photovoltaic production.[25] Grain size has been shown to have an effect on the efficiency of polycrystalline solar cells. Solar cell efficiency increases with grain size. This effect is due to reduced recombination in the solar cell. Recombination, which is a limiting factor for current in a solar cell, occurs more prevalently at grain boundaries, see figure 1.[25]

The resistivity, mobility, and free-carrier concentration in monocrystalline silicon vary with doping concentration of the single crystal silicon. Whereas the doping of polycrystalline silicon does have an effect on the resistivity, mobility, and free-carrier concentration, these properties strongly depend on the polycrystalline grain size, which is a physical parameter that the material scientist can manipulate.[25] Through the methods of crystallization to form polycrystalline silicon, an engineer can control the size of the polycrystalline grains which will vary the physical properties of the material.

Novel ideas

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The use of polycrystalline silicon in the production of solar cells requires less material and therefore provides higher profits and increased manufacturing throughput. Polycrystalline silicon does not need to be deposited on a silicon wafer to form a solar cell, rather it can be deposited on other-cheaper materials, thus reducing the cost. Not requiring a silicon wafer alleviates the silicon shortages occasionally faced by the microelectronics industry.[26] An example of not using a silicon wafer is crystalline silicon on glass (CSG) materials [26]

A primary concern in the photovoltaics industry is cell efficiency. However, sufficient cost savings from cell manufacturing can be suitable to offset reduced efficiency in the field, such as the use of larger solar cell arrays compared with more compact/higher efficiency designs. Designs such as CSG are attractive because of a low cost of production even with reduced efficiency.[26] Higher efficiency devices yield modules that occupy less space and are more compact; however, the 5–10% efficiency of typical CSG devices still makes them attractive for installation in large central-service stations, such as a power station.[26] The issue of efficiency versus cost is a value decision of whether one requires an "energy dense" solar cell or sufficient area is available for the installation of less expensive alternatives. For instance, a solar cell used for power generation in a remote location might require a more highly efficient solar cell than one used for low-power applications, such as solar accent lighting or pocket calculators, or near established power grids.

Manufacturers

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Capacity

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Polysilicon production by country in 2013 (company head-quarter, not location of facility). World total of 227,000 tonnes.[27]

  China (36.1%)
  USA (25.9%)
  South Korea (11.4%)
  Germany (21.6%)
  Japan (4.9%)
Chemical processing at a P.S.T. polysilicon plant

The polysilicon manufacturing market is growing rapidly. According to Digitimes, in July 2011, the total polysilicon production in 2010 was 209,000 tons. First-tier suppliers account for 64% of the market while China-based polysilicon firms have 30% of market share. The total production is likely to increase 37.4% to 281,000 tons by end of 2011.[28] For 2012, EETimes Asia predicts 328,000 tons production with only 196,000 tons of demand, with spot prices expected to fall 56%. While good for renewable energy prospects, the subsequent drop in price could be brutal for manufacturers.[29] As of late 2012, SolarIndustryMag reports a capacity of 385,000 tons will be reached by yearend 2012.[30]

But as established producers (mentioned below) expand their capacities, additional newcomers – many from Asia – are moving into the market. Even long-time players in the field have recently had difficulties expanding plant production. It is yet unclear which companies will be able to produce at costs low enough to be profitable after the steep drop in spot-prices of the last months.[31][32]

Leading producers

[edit]

Wacker's projected its total hyperpure-polysilicon production capacity to increase to 67,000 metric tons by 2014, due to its new polysilicon-production facility in Cleveland, Tennessee (US) with an annual capacity of 15,000 metric tons.[33][34]

Largest polysilicon producers in 2013 (market-share in %)
GCL-Poly Energy China 65,000 tons 22%
Wacker Chemie Germany 52,000 tons 17%
OCI South Korea 42,000 tons 14%
Hemlock Semiconductor USA 36,000 tons 12%
REC Norway 21,500 tons 7%
Source: Market Realist cites World production capacity at 300,000 tons in 2013.[3]
BNEF estimated actual production for 2013 at 227,000 tons[27]
Other manufacturers

Price

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History of polysilicon spot prices

Prices of polysilicon are often divided into two categories, contract and spot prices, and higher purity commands higher prices. While in booming installation times, price rally occurs in polysilicon. Not only spot prices surpass contract prices in the market; but it is also hard to acquire enough polysilicon. Buyers will accept down payment and long-term agreements to acquire a large enough volume of polysilicon. On the contrary, spot prices will be below contract prices once the solar PV installation is in a down trend. In late 2010, booming installation brought up the spot prices of polysilicon. In the first half of 2011, prices of polysilicon kept strong owing to the FIT policies of Italy. The solar PV price survey and market research firm, PVinsights,[47] reported that the prices of polysilicon might be dragged down by lack of installation in the second half of 2011.[48] As recently as 2008 prices were over $400/kg spiking from levels around $200/kg, while seen falling to $15/kg in 2013.[49]

Dumping

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The Chinese government accused United States and South Korean manufacturers of predatory pricing or "dumping". As a consequence, in 2013 it imposed import tariffs of as much as 57 percent on polysilicon shipped from these two countries in order to stop the product from being sold below cost.[50]

Waste

[edit]

Due to the rapid growth in manufacturing in China and the lack of regulatory controls, there have been reports of the dumping of waste silicon tetrachloride.[51] Normally the waste silicon tetrachloride is recycled but this adds to the cost of manufacture as it needs to be heated to 1,800 °F (980 °C).

See also

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References

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  17. ^ Dow Corning stopped UMG Solar Grade Silicon Production. GUNTHER Portfolio (2010-04-29). Retrieved on 2011-04-02.
  18. ^ Press Release. Timminco. Retrieved on 2011-04-02. Note regarding Timminco: On May 14, 2009, Timminco Limited, Photon Consulting LLC, Rogol Energy Consulting LLC, Michael Rogol, Dr. Heinz Schimmelbusch, Robert Dietrich, René Boisvert, Arthur R. Spector, Jack L. Messman, John C. Fox, Michael D. Winfield, Mickey P. Yakisch and John P. Walsh were named as defendants in a lawsuit. The claim was for $500 million plus punitive damages. The Superior Court of Justice decision in favor of the defendants is available here: https://www.canlii.org/en/on/onsc/doc/2016/2016onsc3124/2016onsc3124.html An appeal to the Ontario Superior Court is available at the following link. The Court again found in favor of the defendants and awarded costs accordingly. https://www.canlii.org/en/on/onca/doc/2017/2017onca369/2017onca369.html An appeal to the Canadian Supreme Court was made. The final decision by the Canadian Supreme Court fully vindicating the defendants' position with partial costs awarded to the defendants. The final decision is available here: https://scc-csc.lexum.com/scc-csc/scc-l-csc-a/en/16947/1/document.do A summary of this case is available here: https://www.canadianunderwriter.ca/insurance/court-shuts-door-case-may-muddied-water-limitation-periods-1004126598/
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  33. ^ http://www.wacker.com WACKER TENNESSEE Frequently Asked Questions, 2015
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  36. ^ Solarserver | Das Internetportal für erneuerbare Energien
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  40. ^ "Samsung Fine Chemicals And MEMC Sign Polysilicon Joint Venture Agreement". www.chemicalonline.com. Retrieved 10 April 2018.
  41. ^ Solarserver | Das Internetportal für erneuerbare Energien
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  44. ^ [1][dead link]
  45. ^ "Beijing Lier Plans 1.4 Billion Yuan Polysilicon Project in Henan". Bloomberg. 2011-07-12.
  46. ^ Gulf Times Ras Laffan to get $1bn polysilicon plant
  47. ^ "PVinsights". www.pvinsights.com. Retrieved 10 April 2018.
  48. ^ Price cut of solar PV supply chain spreads and the price of poly-silicon might be dragged down by others
  49. ^ DIGITIMES (23 November 2012). "Login to DIGITIMES archive & research". www.digitimes.com. Retrieved 10 April 2018.
  50. ^ "China Imposes Duties on Polysilicon From U.S., S. Korea". Bloomberg. 18 July 2013. Archived from the original on 2017-03-14. Retrieved 14 March 2017.
  51. ^ "Solar Energy Firms Leave Waste Behind in China". Washington Post. 9 March 2008. Retrieved 8 March 2015.
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