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Beryllium carbonate

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Beryllium carbonate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.032.740 Edit this at Wikidata
RTECS number
  • DS2350000
  • InChI=1S/CH2O3.Be/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2 checkY
    Key: ZBUQRSWEONVBES-UHFFFAOYSA-L checkY
  • InChI=1/CH2O3.Be/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
    Key: ZBUQRSWEONVBES-NUQVWONBAN
  • [Be+2].[O-]C([O-])=O
Properties
BeCO3
Molar mass 69.0211 g/mol
Melting point 54 °C
Boiling point 100 °C (decomp)
Thermochemistry
0.9417 J/K
-14.85 kJ/g
Hazards
Lethal dose or concentration (LD, LC):
150 mg/kg (guinea pig)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Beryllium carbonate is a chemical compound with the chemical formula BeCO3. There are three forms reported, anhydrous, a tetrahydrate and basic beryllium carbonate. The anhydrous form is reported to be unstable, decomposing to BeO and carbon dioxide, and requiring storage under CO2.[1] The tetrahydrate is said to be formed when CO2 is bubbled through a solution of Be(OH)2 and is also reported to be similarly unstable.[2] Basic beryllium carbonate is a mixed salt, which can be prepared by the reaction of beryllium sulfate and ammonium carbonate, and contains both carbonate and hydroxide ions, with formula Be2CO3(OH)2.[3] It is believed that in the older literature this is probably what was referred to as beryllium carbonate.[3]

See also

References

  1. ^ Egon Wiberg, Arnold Frederick Holleman (2001) Inorganic Chemistry, Elsevier ISBN 0-12-352651-5
  2. ^ David Anthony Everest, 1964, The Chemistry of Beryllium, Elsevier Pub. Co.
  3. ^ a b J.E. Macintyre, Dictionary of Inorganic Compounds 1992 CRC Press ISBN 0-412-30120-2