Talk:Gallic acid
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The COOH group has a pKa of 4.5, and the phenolic OHs have pKa of 10.
this is wrong a priori, you cannot deprotonate all three phenols at once. I don't know which one deprotonates first so i'm not changing it but my guess is on meta. 24.181.29.106
Synthetic route for Gallic acid -> Mescaline
I don't know how to add a citation to this page, but a synthesis of Mescaline from Gallic acid can be found here :
[1] A New Synthesis of Mescaline, Makepeace U. Tsao, J. Am. Chem. Soc. 5495-5496 (1951) —Preceding unsigned comment added by 212.238.246.56 (talk) 11:35, 9 August 2008 (UTC)
Corrrection - following line removed
Early photographers, including Joseph Bancroft Reade (1801–1870) and William Fox Talbot (1800–1877), used gallic acid for developing latent images in calotypes. It has also been used as a coating agent in zincography.
Claims made on behalf of Joseph Bancroft Reade (1801–1870) were shown by RD Wood to be erroneous he was working with Silver Nitrate; only AgNo3, AgBr, AgI, and theoretically AgF [ie silver chloride/bromide/iodide] have the potential to develop the latent negative image.[See British Journal of Photography, 28 July 1972, Volume 119, No. 5845, pp.644–646, 643]
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chemical properties citation needed
do you think, phytochemicals.info is a site worth a citation??? esp. because half the article is a citation from there -hig- —Preceding unsigned comment added by 77.132.208.48 (talk) 23:12, 25 April 2009 (UTC)
pKa-Value
As I am a German Wikipedia user, I read in the German article that the pKa (or pKs as it is called in german) is not 4.5 but 3.13 wich seems correct according to the literature (e.g. Bykova L.N., Petrov S.I.& Blagodatskava Z.G. (1970). Relative acidity of phenol and its derivatives in a medium of nonaqueous solvents. Zh. Obshch. Khim., 40, 2295-3000. and the citation No 3 from the german article). I also think that a higher acidity could be expected than for benzoic acid. This thought also fits following german article (you SHOULD translate that one too, if possible) http://de.wikipedia.org/wiki/Hydroxybenzoes%C3%A4uren (Hydroxybenzoesäuren). — Preceding unsigned comment added by 134.130.112.64 (talk) 20:04, 2 November 2011 (UTC)
George Washington & his spies
That George Washington's spies used gallic acid as an invisible ink is supposedly mentioned in "Episode 2: Revolution" of the series "America: The Story of Us", which was broadcast by the U.S. cable TV channel, the "History Channel".
However, in "Chapter 4: 711 and the Sympathetic Stain" (pages 101-124) of his book Washington's Spies: The story of America's first spy ring (New York, New York: Bantam, 2006), author Alexander Rose states that one of Washington's spies, Abraham Woodhull, used an invisible ink when he wrote to George Washington, who then used a developing solution to read the writing. However, Rose states that the nature of the invisible ink and the developing solution are unknown -- although Rose speculates that the invisible ink was gallic acid and that the developing solution was iron sulfate.
So I think that this claim -- that Washington's spies used gallic acid -- should either be deleted or tagged as "dubious". Cwkmail (talk) 01:13, 5 August 2012 (UTC)
Plagiarized content unacceptable
The site "http://www.phytochemicals.info/phytochemicals/gallic-acid.php' reads:
"Gallic acid seems to have anti-fungal and anti-viral properties. Gallic acid acts as a antioxidant and helps to protect our cells against oxidative damage. Gallic acid was found to show cytotoxicity against cancer cells, without harming healthy cells. Gallic acid is used a remote astringent in cases of internal haemorrhage. Gallic acid is also used to treat albuminuria and diabetes. Some ointment to treat psoriasis and external haemorrhoids contain gallic acid."
The wikipedia article reads:
Gallic acid seems to have anti-fungal and anti-viral properties. Gallic acid acts as an antioxidant and helps to protect human cells against oxidative damage. Gallic acid was found to show cytotoxicity against cancer cells, without harming healthy cells. Gallic acid is used as a remote astringent in cases of internal haemorrhage. Gallic acid is also used to treat albuminuria and diabetes. Some ointments to treat psoriasis and external haemorrhoids contain gallic acid.
[i.e., without quotation marks to indicate that the content was lifted in entirety from another source].
This is plagiarized content, even with citation, and is wholely unacceptable. Please correct immediately. LeProf — Preceding unsigned comment added by 71.201.123.248 (talk) 20:22, 3 March 2013 (UTC)