Alloy steel: Difference between revisions
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'''Alloy steel''' The Peoples Steel Mills (PSM) Peoples Steel Mills produced representatives steel grades. Peoples Steel Mills To produce steel according to all major international quality standards and to date has manufactured more than 300 Steel grades. Peoples steel mills To produce steel according to all major international quality standards representative steel grades produced by Peoples steel mills. |
'''Alloy steel''' The Peoples Steel Mills (PSM) Peoples Steel Mills produced representatives steel grades. Peoples Steel Mills To produce steel according to all major international quality standards and to date has manufactured more than 300 Steel grades. Peoples steel mills To produce steel according to all major international quality standards representative steel grades produced by Peoples steel mills. |
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The Peoples Steel Mills (PSM) Peoples Steel Mills produced representatives steel grades. Peoples Steel Mills To produce steel according to all major international quality standards and to date has manufactured more than 300 Steel grades. Peoples steel mills To produce steel according to all major international quality standards representative steel grades produced by Peoples steel mills. |
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Every steel is truly an [[alloy]], but not all steels are called "alloy steels". Even the simplest steels are [[iron]] (Fe) (about 99%) alloyed with [[carbon]] (C) (about 0.1% to 1%, depending on type). However, the term "alloy steel" is the standard term referring to steels with ''other'' alloying elements ''in addition to'' the carbon. Common alloyants include [[manganese]] (the most common one), [[nickel]], [[chromium]], [[molybdenum]], [[vanadium]], [[silicon]], and [[boron]]. Less common alloyants include [[aluminum]], [[cobalt]], [[copper]], [[cerium]], [[niobium]], [[titanium]], [[tungsten]], [[tin]], [[zinc]], [[lead]], and [[zirconium]]. |
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The following is a range of improved properties in alloy steels (as compared to [[carbon steel]]s): [[strength of materials|strength]], [[hardness]], [[toughness]], [[wear resistance]], [[hardenability]], and [[hot hardness]]. To achieve some of these improved properties the metal may require [[heat treating]]. |
The following is a range of improved properties in alloy steels (as compared to [[carbon steel]]s): [[strength of materials|strength]], [[hardness]], [[toughness]], [[wear resistance]], [[hardenability]], and [[hot hardness]]. To achieve some of these improved properties the metal may require [[heat treating]]. |
Revision as of 08:13, 27 November 2011
Steels |
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Other iron-based materials |
Alloy steel The Peoples Steel Mills (PSM) Peoples Steel Mills produced representatives steel grades. Peoples Steel Mills To produce steel according to all major international quality standards and to date has manufactured more than 300 Steel grades. Peoples steel mills To produce steel according to all major international quality standards representative steel grades produced by Peoples steel mills.
The Peoples Steel Mills (PSM) Peoples Steel Mills produced representatives steel grades. Peoples Steel Mills To produce steel according to all major international quality standards and to date has manufactured more than 300 Steel grades. Peoples steel mills To produce steel according to all major international quality standards representative steel grades produced by Peoples steel mills.
The following is a range of improved properties in alloy steels (as compared to carbon steels): strength, hardness, toughness, wear resistance, hardenability, and hot hardness. To achieve some of these improved properties the metal may require heat treating.
Some of these find uses in exotic and highly-demanding applications, such as in the turbine blades of jet engines, in spacecraft, and in nuclear reactors. Because of the ferromagnetic properties of iron, some steel alloys find important applications where their responses to magnetism are very important, including in electric motors and in transformers.
Low-alloy steel
Low-alloy steels are usually used to achieve better hardenability, which in turn improves its other mechanical properties. They are also used to increase corrosion resistance in certain environmental conditions.[1]
With medium to high carbon levels, low-alloy steel is difficult to weld. Lowering the carbon content to the range of 0.10% to 0.30%, along with some reduction in alloying elements, increases the weldability and formability of the steel while maintaining its strength. Such a metal is classed as a high-strength low-alloy steel.
Some common low alloy steels are:
- D6AC
- 300M
- 256A
SAE designation | Composition |
---|---|
13xx | Mn 1.75% |
40xx | Mo 0.20% or 0.25% or 0.25% Mo & 0.042% S |
41xx | Cr 0.50% or 0.80% or 0.95%, Mo 0.12% or 0.20% or 0.25% or 0.30% |
43xx | Ni 1.82%, Cr 0.50% to 0.80%, Mo 0.25% |
44xx | Mo 0.40% or 0.52% |
46xx | Ni 0.85% or 1.82%, Mo 0.20% or 0.25% |
47xx | Ni 1.05%, Cr 0.45%, Mo 0.20% or 0.35% |
48xx | Ni 3.50%, Mo 0.25% |
50xx | Cr 0.27% or 0.40% or 0.50% or 0.65% |
50xxx | Cr 0.50%, C 1.00% min |
50Bxx | Cr 0.28% or 0.50% |
51xx | Cr 0.80% or 0.87% or 0.92% or 1.00% or 1.05% |
51xxx | Cr 1.02%, C 1.00% min |
51Bxx | Cr 0.80% |
52xxx | Cr 1.45%, C 1.00% min |
61xx | Cr 0.60% or 0.80% or 0.95%, V 0.10% or 0.15% min |
86xx | Ni 0.55%, Cr 0.50%, Mo 0.20% |
87xx | Ni 0.55%, Cr 0.50%, Mo 0.25% |
88xx | Ni 0.55%, Cr 0.50%, Mo 0.35% |
92xx | Si 1.40% or 2.00%, Mn 0.65% or 0.82% or 0.85%, Cr 0.00% or 0.65% |
94Bxx | Ni 0.45%, Cr 0.40%, Mo 0.12% |
ES-1 | Ni 5%, Cr 2%, Si 1.25%, W 1%, Mn 0.85%, Mo 0.55%, Cu 0.5%, Cr 0.40%, C 0.2%, V 0.1% |
Material science
Alloying elements are added to achieve certain properties in the material. As a guideline, alloying elements are added in lower percentages (less than 5%) to increase strength or hardenability, or in larger percentages (over 5%) to achieve special properties, such as corrosion resistance or extreme temperature stability.[3]
Manganese, silicon, or aluminium are added during the steelmaking process to remove dissolved oxygen, sulfur and phosphorus from the melt.
Manganese, silicon, nickel, and copper are added to increase strength by forming solid solutions in ferrite. Chromium, vanadium, molybdenum, and tungsten increase strength by forming second-phase carbides. Nickel and copper improve corrosion resistance in small quantities. Molybdenum helps to resist embrittlement. Zirconium, cerium, and calcium increase toughness by controlling the shape of inclusions. Manganese sulfide, lead, bismuth, selenium, and tellurium increase machinability.[4]
The alloying elements tend to form either compounds or carbides. Nickel is very soluble in ferrite; therefore, it forms compounds, usually Ni3Al. Aluminium dissolves in the ferrite and forms the compounds Al2O3 and AlN. Silicon is also very soluble and usually forms the compound SiO2•MxOy. Manganese mostly dissolves in ferrite forming the compounds MnS, MnO•SiO2, but will also form carbides in the form of (Fe,Mn)3C. Chromium forms partitions between the ferrite and carbide phases in steel, forming (Fe,Cr3)C, Cr7C3, and Cr23C6. The type of carbide that chromium forms depends on the amount of carbon and other types of alloying elements present. Tungsten and molybdenum form carbides if there is enough carbon and an absence of stronger carbide forming elements (i.e., titanium & niobium), they form the carbides Mo2C and W2C, respectively. Vanadium, titanium, and niobium are strong carbide forming elements, forming vanadium carbide, titanium carbide, and niobium carbide, respectively.[5]
Alloying elements also have an effect on the eutectoid temperature of the steel. Manganese and nickel lower the eutectoid temperature and are known as austenite stabilizing elements. With enough of these elements the austenitic structure may be obtained at room temperature. Carbide-forming elements raise the eutectoid temperature; these elements are known as ferrite stabilizing elements.[6]
Element | Percentage | Primary function |
---|---|---|
Aluminium | 0.95–1.30 | Alloying element in nitriding steels |
Bismuth | - | Improves machinability |
Boron | 0.001–0.003 | A powerful hardenability agent |
Chromium | 0.5–2 | Increases hardenability |
4–18 | Increases corrosion resistance | |
Copper | 0.1–0.4 | Corrosion resistance |
Lead | - | Improved machinability |
Manganese | 0.25–0.40 | Combines with sulfur and with phosphorus to reduce the brittleness. Also helps to remove excess oxygen from molten steel. |
>1 | Increases hardenability by lowering transformation points and causing transformations to be sluggish | |
Molybdenum | 0.2–5 | Stable carbides; inhibits grain growth. Increases the toughness of steel, thus making molybdenum a very valuable alloy metal for making the cutting parts of machine tools and also the turbine blades of turbojet engines. Also used in rocket motors. |
Nickel | 2–5 | Toughener |
12–20 | Increases corrosion resistance | |
Silicon | 0.2–0.7 | Increases strength |
2.0 | Spring steels | |
Higher percentages | Improves magnetic properties | |
Sulfur | 0.08–0.15 | Free-machining properties |
Titanium | - | Fixes carbon in inert particles; reduces martensitic hardness in chromium steels |
Tungsten | - | Also increases the melting point. |
Vanadium | 0.15 | Stable carbides; increases strength while retaining ductility; promotes fine grain structure. Increases the toughness at high temperatures |
See also
References
Notes
Bibliography
- Degarmo, E. Paul; Black, J T.; Kohser, Ronald A. (2007), Materials and Processes in Manufacturing (10th ed.), Wiley, ISBN 978-0-470-05512-0.
- Groover, M. P., 2007, p. 105-106, Fundamentals of Modern Manufacturing: Materials, Processes and Systems, 3rd ed, John Wiley & Sons, Inc., Hoboken, NJ, ISBN 978-0-471-74485-6.
- Smith, William F.; Hashemi, Javad (2001), Foundations of Material Science and Engineering (4th ed.), McGraw-Hill, p. 394, ISBN 0-07-295358-6