Bromoiodomethane
Appearance
This article includes a list of general references, but it lacks sufficient corresponding inline citations. (June 2012) |
Names | |
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Preferred IUPAC name
Bromoiodomethane[citation needed] | |
Systematic IUPAC name
Bromo(iodo)methane[1] | |
Other names
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Identifiers | |
3D model (JSmol)
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ChemSpider | |
ECHA InfoCard | 100.156.567 |
PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
CH2BrI | |
Molar mass | 220.835 g·mol−1 |
Appearance | Colourless liquid |
Density | 2.93 g mL−1 |
Melting point | 1 °C; 34 °F; 274 K |
Boiling point | 138 to 141 °C (280 to 286 °F; 411 to 414 K) |
Refractive index (nD)
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1.6382 |
Hazards | |
GHS labelling: | |
Danger | |
H315, H318, H335 | |
P261, P280, P305+P351+P338 | |
Related compounds | |
Related alkanes
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Bromoiodomethane is a liquid mixed halomethane very soluble in chloroform.
Its critical point is at 367.85 °C and 6.3 MPa and refractive index is 1.6382 (20 °C, D).
References
- Tarnovsky A. N., Wall M., Gustafsson M., Lascoux N., Sundström V., Åkesson E. (March 2002). "Ultrafast Study of the Photodissociation of Bromoiodomethane in Acetonitrile upon 266 nm Excitation". J. Phys. Chem. A. 106 (25): 5999–6005(7). doi:10.1021/jp014306j. Retrieved 2007-06-29.
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: CS1 maint: multiple names: authors list (link) - Liu Y.-J., Ajitha D., Krogh J. W., Tarnovsky A. N., Lindh R. (December 2005). "Spin-Orbit Ab Initio Investigation of the Photolysis of Bromoiodomethane". ChemPhysChem. 7 (4): 955–963(9). doi:10.1002/cphc.200500654. PMID 16596616. Retrieved 2007-06-29.
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: CS1 maint: multiple names: authors list (link) - Zheng, X.; Phillips, D. L. (August 2000). "Photoisomerization reaction of CH2BrI following A-band and B-band photoexcitation in the solution phase: Transient resonance Raman observation of the iso-CH2I-Br photoproduct". J. Chem. Phys. 113 (8): 3194–3203(10). Bibcode:2000JChPh.113.3194Z. doi:10.1063/1.1286920.
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: CS1 maint: multiple names: authors list (link) - Liu K., Zhao H., Wang C., Zhang A., Ma S., Li Z. (January 2005). "A theoretical study of bond selective photochemistry in CH2BrI". J. Chem. Phys. 122 (4): 044310. Bibcode:2005JChPh.122d4310L. doi:10.1063/1.1835955. PMID 15740251. Retrieved 2007-06-29.
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: CS1 maint: multiple names: authors list (link)
- ^ "bromoiodomethane - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 27 March 2005. Identification. Retrieved 15 June 2012.