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Cadmium bromide

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Cadmium bromide
Cadmium bromide
Names
IUPAC name
Cadmium(II) bromide
Other names
Cadmium dibromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.241 Edit this at Wikidata
  • InChI=1/2BrH.Cd/h2*1H;/q;;+2/p-2
    Key: KPWJBEFBFLRCLH-NUQVWONBAB
  • Br[Cd]Br
Properties
CdBr2
Molar mass 272.22 g/mol
Appearance white to pale yellow crystalline solid
Density 5.192 g/cm3, solid
Melting point 568 °C
Boiling point 844 °C
56.3 g/100 mL (0 °C)
98.8 g/100 mL (20 °C)
160 g/100 mL (100 °C)
Solubility soluble in alcohol, ether, acetone and liquid ammonia.
Structure
Rhombohedral, hr9, SpaceGroup = R-3m, No. 166
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
0
0
Lethal dose or concentration (LD, LC):
225 mg/kg, oral (rat)
Related compounds
Other anions
Cadmium chloride,
Cadmium iodide
Other cations
Zinc bromide,
Calcium bromide,
Magnesium bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Cadmium bromide is a cream-coloured crystalline ionic compound that is soluble in water. It is very toxic, along with other cadmium compounds.

Uses

It is used in the manufacturing of photographic film, engraving and lithography.

Preparation

Cadmium bromide is prepared by heating cadmium with bromine vapor. Also the compound can be prepared by the treatment of dry cadmium acetate with glacial acetic acid and acetyl bromide. Alternatively, it can be obtained by dissolving cadmium or cadmium oxide in hydrobromic acid and evaporating the solution to dryness under helium in an inert atmosphere.[1]

References

  1. ^ Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0070494398