The song was a hit on the Hot Country Songs chart where it spent one week at number one, notably ending the record-breaking eight-week reign of country group Lonestar's single "Amazed".[2] It was also a success in Canada, topping the RPM Canadian Country Tracks and becoming the third most successful country song of 1999 in the country.[3]
The music video takes place entirely on a city bus, with Chely performing by herself in the back of the bus, and in another scene with two backup singers and two guitarists while standing on the bus. In the beginning, it shows many of the bus's patrons, before moving to a "single white female looking for a special lover". A man gets on and eventually leaves the bus (having been seated in the row next to her and behind her, respectively) before he comes on a third time and sits next to her, where they glance at each other. The man eventually gets up, accidentally leaving his book on his seat. The woman grabs it and returns it to him, then they both walk off smiling at each other.
"Single White Female" debuted at number 66 on the U.S. Billboard Hot Country Singles & Tracks for the week of March 13, 1999, and peaked at number 36 on the Billboard Hot 100 chart.