Kipp's apparatus

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Kipp apparatus

Kipp's apparatus, also called Kipp generator, is an apparatus designed for preparation of small volumes of gases. It was invented around 1844 by the Dutch pharmacist Petrus Jacobus Kipp and widely used in chemical laboratories and for demonstrations in schools into the second half of the 20th century.

It later fell out of use, at least in laboratories, because most gases then became available in small gas cylinders. These industrial gases are much purer and drier than those initially obtained from a Kipp apparatus without further processing.

Design and operation[edit]

The apparatus is made of three vertically stacked cylinders, roughly resembling a snowman. The solid material (e.g., iron sulfide) is placed into the middle cylinder, the acid is put into the top cylinder. A tube extends from the top cylinder into the bottom cylinder. The middle cylinder has a tube with a stopcock attached, which is used to draw off the evolved gas. When the stopcock is closed, the pressure of the gas in the middle cylinder rises and expels the acid back into the top cylinder, until it is not in contact with the solid material anymore, and the chemical reaction stops.

Kipp generators only work properly in the described manner if the solid material is insoluble in the acid. They are usually made of glass, or sometimes of polyethylene.

The produced gas often requires further purification and/or drying, due to content of water vapor and possibly mist if the reaction is vigorous.

Examples for prepared gases and their educts[edit]

A version of the apparatus can be used for reaction between two liquid precursors. A mercury trap has to be added as a check valve, and the middle bulb is filled with an inert porous material, e.g. pumice, onto which one of the precursors is dropped.[1]

For further reading[edit]

References[edit]

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