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Pekka Pyykkö

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Pekka Pyykkö in 1991.

Veli Pekka Pyykkö (born October 12, 1941)[1] is a Finnish academic. He is professor of Chemistry at the University of Helsinki.[1] From 2009–2012, he was the chairman of the International Academy of Quantum Molecular Science. He is known for his extension to the periodic table of elements,[2][3] known as the Pyykkö model.[4]

Pyykkö model

Pekka Pyykkö predicts that the orbital shells will fill up in this order:

  • 8s,
  • 5g,
  • the first two spaces of 8p,
  • 6f,
  • 7d,
  • 9s,
  • the first two spaces of 9p,
  • the rest of 8p.[5]

He also suggests that period 8 be split into three parts:

  • 8a, containing 8s,
  • 8b, containing the first two elements of 8p,
  • 8c, containing 7d and the rest of 8p.[5]

Template:Extended periodic table (by Pyykkö, 50 columns, periods 8–9)

The compact version:[5]

Extended periodic table. P. Pyykkö, PCCP 2011, 13, 161. @RSC. Reprinted with permission.
Extended periodic table. P. Pyykkö, PCCP 2011, 13, 161. @RSC. Reprinted with permission.

Pekka Pyykkö successfully predicted the possibility of a chemical bond between gold and the noble gas xenon, which is usually inert; this bond is known to occur in the cationic complex tetraxenonogold(II) (AuXe2+
4
). He also successfully predicted the possibility of a gold–carbon triple bond.[6]

References

  1. ^ a b "Curriculum vitae". chem.helsinki.fi. 2012-04-25. Archived from the original on 2012-02-19. Retrieved 2012-05-28.
  2. ^ Roberts, Siobhan (27 August 2019). "Is It Time to Upend the Periodic Table?". The New York Times. Retrieved 7 December 2019.
  3. ^ Kean, Sam (30 January 2019). "A storied Russian lab is trying to push the periodic table past its limits—and uncover exotic new elements". Science. Retrieved 7 December 2019.
  4. ^ Atsumi, Michiko (2013). "SCCJ Cafe -Season 3-Theoretical Chemistry in Nordic (2)"The Extended Periodic Table − Pyykkö Model"". Journal of Computer Chemistry, Japan. 12 (2): A18–A20. doi:10.2477/jccj.2013-0008.
  5. ^ a b c Pyykkö, Pekka (2011). "A suggested periodic table up to Z≤ 172, based on Dirac–Fock calculations on atoms and ions". Physical Chemistry Chemical Physics. 13 (1): 161–8. Bibcode:2011PCCP...13..161P. doi:10.1039/c0cp01575j. PMID 20967377.
  6. ^ Scientific American June 2013, "Cracks in the Periodic Table". p. 72.