Sodium silicide

From Wikipedia, the free encyclopedia

This is an old revision of this page, as edited by Monkbot (talk | contribs) at 16:21, 15 October 2019 (→‎top: Task 16: replaced (1×) / removed (0×) deprecated |dead-url= and |deadurl= with |url-status=;). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

Sodium silicide (NaSi, Na4Si4) is a binary inorganic compound consisting of sodium and silicon. It is a solid black or grey crystalline material.[1]

Sodium silicide reacts readily with water yielding gaseous hydrogen and aqueous sodium silicate in an exothermic reaction (~175 kJ·mol−1):[2]

2 NaSi + 5 H2O → 5 H2 + Na2Si2O5

This is used in hydrogen technologies to generate hydrogen as a fuel. And is also used as high energy dense storage for hydrogen under low pressure.[3]

See also

External links

References

  1. ^ Material Safety Data Sheet, SiGNa Chemistry, Inc.
  2. ^ Hydrogen Production from Sodium Silicide Powder; Prospects for On-Board Generation, 14 July 2006
  3. ^ "Silicide-Based Hydrogen Generation for Back-Up Power and Portable Fuel Cells" (PDF). www.signachem.com/. July 2013. Archived from the original (PDF) on 25 Mar 2019. Retrieved 25 Mar 2019.