Bismuth oxychloride

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Bismuth oxychloride
MatlockiteStructure.png
Names
Other names
bismuthyl chloride
bismuth oxochloride
bismuth oxide chloride
bismuth(III) oxide chloride
bismoclite
Identifiers
7787-59-9 YesY
ChemSpider 10606415 YesY
Jmol-3D images Image
UNII 4ZR792I587 YesY
Properties
BiClO
Molar mass 260.43 g·mol−1
Density 7.36 (meas.), 7.78 g/cm3 (calc.)[1]
insoluble
Structure
Tetragonal, tP6[2]
P4/nmm, No. 129
a = 0.3887 nm, c = 0.7354 nm
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Bismuth oxychloride is an inorganic compound of bismuth with the formula BiOCl. It is a lustrous white solid used since antiquity, notably in ancient Egypt. Light wave interference from its plate-like structure gives a pearly iridescent light reflectivity similar to nacre.

Structure[edit]

The structure of can be thought of as consisting of layers of Cl, Bi3+ and O2− ions (in the image Bi = grey, O = red, Cl = green). These ions are ordered as Cl-Bi-O-Bi-Cl-Cl-Bi-O-Bi-Cl, i.e., with alternating anions (Cl-, O2-) and cations (Bi3+). The layered structure gives rise to the pearlescent properties of this material.

Focusing on the coordination environment of the individual ions, the bismuth centers adopt a distorted square antiprismatic coordination geometry. The Bi3+ ion is coordinated to four chloride, forming one of the square faces, each at a distance of 3.06 Å from Bi, and four oxygen atoms forming the other square face, each at a distance of 2.32 Å from Bi. The oxygen atoms are tetrahedrally coordinated by four bismuth atoms.[2]

Synthesis and reactions[edit]

BiOCl is formed during the reaction of bismuth chloride with water, i.e. the hydrolysis:

BiCl3 + H2O → BiOCl + 2 HCl

When heated above 600 °C, BiOCl converts to the Bi24O31Cl10, called the "Arppe compound" which has a complex layer structure.[3][4]

Use and occurrence[edit]

It has been used in cosmetics since the days of ancient Egypt. It is part of the "pearly pigment found in eye shadow, hair sprays, powders, nail polishes, and other cosmetic products".[5] Owing to the plate-like structure of the BiOCl, its suspensions exhibit optical properties like nacre.

BiOCl exists in nature as the rare mineral bismoclite, which is part of the matlockite mineral group.

An analogous compound, bismuth oxynitrate is used as a white pigment also.

References[edit]

  1. ^ Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W. and Nichols, Monte C. (ed.). "Bismoclite". Handbook of Mineralogy (PDF). III (Halides, Hydroxides, Oxides). Chantilly, VA, US: Mineralogical Society of America. ISBN 0-9622097-2-4. Retrieved December 5, 2011. 
  2. ^ a b Keramidas, K. G.; Voutsas, G. P.; Rentzeperis, P. I. (1993). "The crystal structure of BiOCl". Zeitschrift für Kristallographie 205 (Part-1): 35–40. doi:10.1524/zkri.1993.205.Part-1.35. ISSN 0044-2968. 
  3. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 572. ISBN 0080379419. 
  4. ^ Eggenweiler, U.; Keller, E.; Krämer, V. (2000). "Redetermination of the crystal structures of the `Arppe compound' Bi24O31Cl10and the isomorphous Bi24O31Br10". Acta Crystallographica Section B Structural Science 56 (3): 431–437. doi:10.1107/S0108768100000550. ISSN 0108-7681. 
  5. ^ Völz, Hans G. et al. "Pigments, Inorganic" in Ullmann's Encyclopedia of Industrial Chemistry, 2006 Wiley-VCH, Weinheim. doi:10.1002/14356007.a20_243.pub2.