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Calcium sulfite

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Calcium sulfite
Names
IUPAC name
Calcium sulfite
Other names
Sulfurous acid, calcium salt (1:1)
E226
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.529 Edit this at Wikidata
E number E226 (preservatives)
  • InChI=1S/Ca.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+2;/p-2 checkY
    Key: GBAOBIBJACZTNA-UHFFFAOYSA-L checkY
  • InChI=1/Ca.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+2;/p-2
    Key: GBAOBIBJACZTNA-NUQVWONBAU
  • [Ca+2].[O-]S([O-])=O
Properties
CaSO3
Molar mass 120.17 g/mol
Melting point 600 °C (1,112 °F; 873 K)
0.0043 g/100 mL, 18C
Hazards
Flash point Non-flammable
Related compounds
Other anions
Calcium sulfate
Other cations
Sodium sulfite
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Calcium sulfite, or calcium sulphite, is a chemical compound which is the calcium salt of sulfurous acid with the molecular formula CaSO3. As a food additive it is used as a preservative under the E number E226. It is commonly used in preserving wine, cider, fruit juice, canned fruit and vegetables.

Like other metal sulfites, calcium sulfite reacts with acids to produce a calcium salt, sulfur dioxide gas and water. For this reason, CaSO3 is not a desirable compound in drywall - when humid (with the natural acidity of carbon dioxide found in the air), it releases sulfur dioxide and carbon dioxide is absorbed to form calcium carbonate.