The seaborne transport of liquefied gases began in 1934 when a major international company put two combined oil/LPG tankers into operation. The ships, basically oil tankers, had been converted by fitting small, riveted, pressure vessels for the carriage of LPG into cargo tank spaces. This enabled transport over long distances of substantial volumes of an oil refinery by-product that had distinct advantages as a domestic and commercial fuel. LPG is not only odourless and non-toxic, it also has a high calorific value and a low sulphur content, making it very clean and efficient when being burnt.
Today, most fully pressurised oceangoing LPG carriers are fitted with two or three horizontal, cylindrical or spherical cargo tanks and have typical capacities between 20,000 to 1,000,000 Tonnes and Length overall ranging from 220 m to 260 m . However, in recent years a number of larger-capacity fully pressurised ships have been built, most notably a series of 10,800 m3 (380,000 cu ft) ships, built in Japan between 2003 and 2013. Fully pressurised ships are still being built in numbers and represent a cost-effective, simple way of moving LPG to and from smaller gas terminals.
These ships carried gases in a semi-pressurized/semi-refrigerated state however due to further development semi-pressurised/fully refrigerated gas carriers had become the shipowners' choice by providing high flexibility in cargo handling. These carriers, incorporating tanks either cylindrical, spherical or bi-lobe in shape, are able to load or discharge gas cargoes at both refrigerated and pressurised storage facilities.
Ethylene carriers are the most sophisticated of the gas tankers and have the ability to carry not only most other liquefied gas cargoes but also ethylene at its atmospheric boiling point of −104 °C (−155 °F). These ships feature cylindrical, insulated, stainless steel cargo tanks able to accommodate cargoes up to a maximum specific gravity of 1.8 at temperatures ranging from a minimum of −104 °C to a maximum of +80 °C (176 °F) and at a maximum tank pressure of 4 bar.
They are built to carry liquefied gases at low temperature and atmospheric pressure between terminals equipped with fully refrigerated storage tanks. However, discharge through a booster pump and cargo heater makes it possible to discharge to pressurized tanks too. The first purpose-built, lpg tanker was the m/t Rasmus Tholstrup from a Swedish shipyard to a Danish design. Prismatic tanks enabled the ship's cargo carrying capacity to be maximised, thus making fully refrigerated ships highly suitable for carrying large volumes of cargo such as LPG, ammonia and vinyl chloride over long distances. Today, fully refrigerated ships range in capacity from 20,000 to 100,000 m3 (710,000 to 3,530,000 cu ft). LPG carriers in the 50,000–80,000 m3 (1,800,000–2,800,000 cu ft) size range are often referred to as VLGCs (Very Large Gas Carriers). Although LNG carriers are often larger in terms of cubic capacity, this term is normally only applied to fully refrigerated LPG carriers.
The main type of cargo containment system utilised on board modern fully refrigerated ships are independent tanks with rigid foam insulation. The insulation used is quite commonly polyurethane foam. Older ships can have independent tanks with loosely filled perlite insulation. In the past, there have been a few fully refrigerated ships built with semi-membrane or integral tanks and internal insulation tanks, but these systems have only maintained minimal interest. The large majority of such ships currently in service have been constructed by shipbuilders in Japan and Korea.
Liquefied Natural Gas (LNG carrier)
The majority of LNG carriers are between 125,000 and 135,000 m3 (4,400,000 and 4,800,000 cu ft) in capacity. In the modern fleet of LNG carriers, there is an interesting exception concerning ship size. This is the introduction of several smaller ships of between 18,000 and 19,000 m3 (640,000 and 670,000 cu ft) having been built in 1994 and later to service the needs of importers of smaller volumes.
Compressed Natural Gas (CNG carrier)
Compressed Natural Gas carrier ships CNG carrier are designed for transportation of natural gas under high pressure. CNG carrier technology relies on high pressure, typically over 250 bar (2900 psi), to increase the density of the gas and maximize the possible commercial payload. CNG carriers are economical for medium distance marine transport  and rely on the adoption of suitable pressure vessels to store CNG during transport and on the use of suitable loading and unloading compressors to receive the CNG at the loading terminal and to deliver the CNG at the unloading terminal.
These vessels are designed to transport liquefied gas. Builders of Liquefied Gas Carriers are:
- Daewoo Shipbuilding & Marine
- Hyundai Samho Heavy Industries
- Kawasaki Shipbuilding Corporation
- Damen Shipyards Group (http://products.damen.com/en/ranges/liquefied-gas-carrier)
Cargoes carried on gas carriers
- Chemical gases such as ammonia, vinyl chloride, ethylene oxide, propylene oxide and chlorine.
Gas carrier codes
The Gas Codes, developed by International Maritime Organization apply to all gas carriers regardless of size. There are three Gas Codes and these are described below.
Gas carriers built after June 1986 (the IGC Code)
The Code which applies to new gas carriers (built after 30 June 1986) is the International Code for the Construction and Equipment of Ships Carrying Liquefied Gases in Bulk. In brief, this Code is known as the IGC Code. The IGC Code, under amendments to International Convention for the Safety of Life at Sea (SOLAS), is mandatory for all new ships. As proof that a ship complies with the Code, an International Certificate of Fitness for the Carriage of Liquefied Gases in Bulk should be on board. In 1993, the IGC Code was amended and the new rules came into effect on 1 July 1994. Ships on which construction started on or after 1 October 1994 should apply the amended version of the Code but ships built earlier may comply with previous editions of the IGC Code.
Gas carriers built between 1976 and 1986 (the GC Code) The regulations covering gas carriers built after 1976 but before July 1986 are included in the Code for the Construction and Equipment of Ships Carrying Liquefied Gases in Bulk. It is known as the Gas Carrier Code or GC Code in short. Since 1975, International Maritime Organization (IMO) has approved four sets of amendments to the GC Code. The latest was adopted in June 1993. All amendments are not necessarily agreed by every government. Although this Code is not mandatory, many countries have implemented it into national law. Accordingly, most charterers will expect such ships to meet with Code standards and, as proof of this, to have on board a Certificate of Fitness for the Carriage of Liquefied Gases in Bulk.
Gas carriers built before 1977 (the Existing Ship Code) The regulations covering gas carriers built before 1977 are contained in the Code for Existing Ships Carrying Liquefied Gases in Bulk. Its content is similar to the GC Code, though less extensive. The Existing Ship Code was completed in 1976 after the GC Code had been written. It therefore summarises current shipbuilding practice at that time. It remains as an IMO recommendation for all gas carriers in this older fleet of ships. The Code is not mandatory but is applied by some countries for ship registration and in other countries as a necessary fulfilment prior to port entry. Accordingly, many ships of this age are required by charterers to meet with Code standards and to have on board a Certificate of Fitness for the Carriage of Liquefied Gases in Bulk.
Cargo containment systems
A cargo containment system is the total arrangement for containing cargo including, where fitted:
- A primary barrier (the cargo tank),
- Secondary barrier (if fitted),
- Associated thermal insulation,
- Any intervening spaces, and
- Adjacent structure, if necessary, for the support of these elements.
For cargoes carried at temperatures between −10 and −55 °C (14 and −67 °F) the ship's hull may act as the secondary barrier and in such cases it may be a boundary of the hold space.
The basic cargo tank types utilised on board gas carriers are in accordance with the list below:—
- Independent Type 'A'
Type A Independent Tanks are prismatic and supported on insulation-bearing blocks typically consisting of wooden chocks and located by anti-roll chocks located at the top of the tank inside the void space and anti-flotation chocks located inside the void space usually just above the double bottom tanks. The tanks are normally divided by a centreline liquid-tight bulkhead; by this feature, together with the chamfered upper part of the tank, the free liquid surface effect is reduced and thus the virtual rise of the Centre of gravity and the stability is increased. When these cargo tanks are designed to carry LPG (at −50 °C), the tank is constructed of fine-grained low-carbon manganese steel or even stainless steel as seen in the Maersk J class Ships. The hold space (void space) in this design is normally filled with dry inert gas or Nitrogen but may be ventilated with air during a ballast or gas free passage. The Conch design has been developed for carriage of LNG (at-163oC). The material for these cargo tanks has to be either 9% nickel steel or aluminium. The maximum allowable relief vapour setting (MARVS) is < 0. 7 bar.
- Independent Type 'B'
Type B Independent Tanks are generally spherical and welded to a vertical cylindrical skirt, which is the lone connection to the ship's main hull. The hold space (void space) in this design is normally filled with dry inert gas or Nitrogen but may be ventilated with air during a ballast or gas free passage. A protective steel dome covers the primary barrier above deck level, and insulation encloses the outside of the primary barrier surface. This containment system has been used for carriage of LNG. The material of construction is either 9% nickel steel or aluminium. The maximum Allowable relief vapour setting (MARVS) is < 0. 7 bar.
- Independent Type 'C'
Type C Independent Tanks are deck pressure vessels or cylindrical pressure tanks mounted horizontally on two or more cradle-shaped foundations. The tanks may be fitted on, below or partly below deck and be both longitudinally and transversely located. Lobe-type tanks are commonly used at the forward end of the ship, to improve the poor utilization of the hull volume. This containment system is used for LPG, Ethylene and small scale LNG carriers. The material, if used for the construction of tanks designed to carry ethylene, is 5% nickel steel. The maximum Allowable relief vapour setting (MARVS) is > 0. 7 bar.
Some other types such as:
- Internal insulation Type '1'
- Internal insulation Type '2'
have been fully designed and approved but have not been commercially used yet.
Hazards on gas carriers
Vinyl chloride commonly carried on gas carriers is a known as a human carcinogen, particularly liver cancer. It is not only dangerous when inhaled but can also be absorbed by the skin. Skin irritation and watering of the eyes indicate dangerous levels of VCM may be present in the atmosphere. Caution must be exerted while dealing with such cargoes, precautions such as use of Chemical suits Self-contained Breathing Apparatus (SCBA's) and gas tight goggles must be worn at all times to prevent exposure. Chlorine and ammonia are other toxic cargoes carried.
Almost all cargo vapours are flammable. When ignition occurs, it is not the liquid which burns but the evolved vapour that burns. Flameless explosions which result out of cold cargo liquid coming into sudden contact with water do not release much energy. Pool fires which are the result of a leaked pool of cargo liquid catching fire and jet fires which are the result of the leak catching fire are grave hazards. Flash fires occur when there is a leak and does not ignite immediately but after the vapours travel some distance downwind and getting ignited and are extremely dangerous. Vapour cloud explosions and boiling liquid expanding vapor explosions are the most grave flammability hazards on gas carriers.
Asphyxia occurs when the blood cannot take a sufficient supply of oxygen to the brain. A person affected may experience headache, dizziness and inability to concentrate, followed by loss of consciousness. In sufficient concentrations any vapour may cause asphyxiation, whether toxic or not.
Health effects of specific cargoes carried on gas carriers
1. Exposure to more than 2,000 ppm – fatal in 30 minutes, 6,000 ppm – fatal in minutes, 10,000 ppm – fatal and intolerable to unprotected skin.
2. Anhydrous ammonia is not dangerous when handled properly, but if not handled carefully it can be extremely dangerous. It is not as combustible as many other products that we use and handle every day. However, concentrations of gas burn and require precautions to avoid fires.
3. Mild exposure can cause irritation to eye, nose and lung tissues. Prolonged breathing can cause suffocation. When large amounts are inhaled, the throat swells shut and victims suffocate. Exposure to vapours or liquid also can cause blindness
4. The water-absorbing nature of anhydrous ammonia that causes the greatest injury (especially to the eyes, nose, throat or lungs), and which can cause permanent damage. It is a colourless gas at atmospheric pressure and normal temperature, but under pressure readily changes into a liquid. Anhydrous ammonia has a high affinity for water. Anhydrous ammonia is a hygroscopic compound, this means it will seek moisture source that may be the body of the operator, which is composed of 90 percent water. When a human body is exposed to anhydrous ammonia the chemical freeze burns its way into the skin, eyes or lungs. This attraction places the eyes, lungs, and skin at greatest risk because of their high moisture content. Caustic burns result when the anhydrous ammonia dissolves into body tissue. Most deaths from anhydrous ammonia are caused by severe damage to the throat and lungs from a direct blast to the face. An additional concern is the low boiling point of anhydrous ammonia. The chemical freezes on contact at room temperature. It will cause burns similar to, but more severe than, those caused by dry ice. If exposed to severe cold flesh will become frozen. At first, the skin will become red (but turn subsequently white); the affected area is painless, but hard to touch, if left untreated the flesh will die and may become gangrenous.
5. The human eye is a complex organ made up of about 80 percent water. Ammonia under pressure can cause extensive, almost immediate damage to the eye. The ammonia extracts the fluid and destroys eye cells and tissue in minutes.
6. Draining of ammonia into sea while pre-cooling of the hard-arm or during disconnection operations is not an eco-friendly operation. As a small quantity of ammonia as low as 0.45 mg/L (1.6×10−8 lb/cu in)(LC50) is hazardous to Salmon as per ICSC, USA. Consumption of such fish could be dangerous to humans.
- Gas Carrier definition as per DNV http://www.dnv.com/industry/maritime/shiptypes/gascarrier/index.asp Archived 2012-04-30 at the Wayback Machine
- Fully Pressurised Ships http://www.liquefiedgascarrier.com/fully-pressurized-ships.html
- Semi-Pressurised Ships http://www.liquefiedgascarrier.com/semi-pressurized-ships.html
- Ethylene and gas/chemical carriers http://www.liquefiedgascarrier.com/ethylene-carriers.html
- Fully refrigerated ships http://www.liquefiedgascarrier.com/Fully-Refrigerated-Ships.html
- "Launch of Jayanti Baruna: World's First CNG Carrier". Archived from the original on 10 September 2017. Retrieved 17 August 2017.
- "Marine CNG Transportation" (PDF). Retrieved 17 March 2017.
- "H2020 Project GASVESSEL - Compressed Natural Gas Transport System". Retrieved 16 November 2019.
- IGC Code http://www.imo.org/OurWork/Environment/PollutionPrevention/ChemicalPollution/Pages/IGCCode.aspx
- Code for Existing Ships Carrying Liquefied Gases in Bulk https://books.google.com/books/about/Code_for_Existing_Ships_Carrying_Liquefi.html?id=V5YniR_ssTAC&redir_esc=y
- Liquefied Gas Carrier with Independent Tanks http://www.eagle.org/eagleExternalPortalWEB/ShowProperty/BEA%20Repository/Rules&Guides/Current/144_LGCarrierswithIndependentTanks/Pub144_LGC_Guide
- Aluminium Cargo Tank Independent Type B, DSME Gas Tank Technology Approved By Lloyd’s Register http://marineinsight.com/news/new-dsme-gas-tank-technology-approved-by-lloyds-register/ Archived 2013-09-09 at the Wayback Machine
- Gaztransport and Technigaz Cargo Containment Systems "Archived copy". Archived from the original on 2012-04-18. Retrieved 2012-04-18.CS1 maint: archived copy as title (link)
- VCM and health effects http://www.pvc.org/en/p/vinyl-chloride-monomer
- Health Effects of Ammonia http://www.ccohs.ca/oshanswers/chemicals/chem_profiles/ammonia/health_ammonia.html
- http://www.ccohs.ca/oshanswers/chemicals/chem_profiles/ammonia/health_ammonia.html Canadian Centre for Occupational Health and Safety, Health Effects of Ammonia Gas
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