Tritium radioluminescence
Tritium illumination is the use of gaseous tritium, a radioactive isotope of hydrogen, to create visible light. Tritium emits electrons through beta decay, and, when they interact with a phosphor material, fluorescent light is created, a process called radioluminescence. As tritium illumination requires no electrical energy, it found wide use in applications such as emergency exit signs and illumination of wristwatches. More recently, many applications using radioactive materials have been replaced with photoluminescent materials.
Design
Tritium lighting is made using glass tubes with a phosphor layer in them and tritium gas inside the tube. Such a tube is known as a "gaseous tritium light source" (GTLS), or beta light, (since the tritium undergoes beta decay).
The tritium in a gaseous tritium light source undergoes beta decay, releasing electrons that cause the phosphor layer to fluoresce. [citation needed]
During manufacture, a length of borosilicate glass tube that has had the inside surface coated with a phosphor-containing material is filled with the radioactive tritium. The tube is then fused with a carbon dioxide laser at the desired length. Borosilicate is preferred for its strength and resistance to breakage. In the tube, the tritium gives off a steady stream of electrons due to beta decay. These particles excite the phosphor, causing it to emit a low, steady glow. Tritium is not the only material that can be used for self-powered lighting. Other beta particle-emitting radioisotopes can also serve. Radium was used to make self-luminous paint from the early years of the 20th Century until approximately 1970,[1] but it has been replaced by tritium, which is less hazardous.
Various preparations of the phosphor compound can be used to produce different colors of light. Some of the colors that have been manufactured in addition to the common phosphors are green, red, blue, yellow, purple, orange, and white.
The types of GTLS used in watches give off a small amount of light: not enough to be seen in daylight, but enough to be visible in the dark from a distance of several meters.[citation needed] The average such GTLS has a useful life of 10–20 years [citation needed]. As the tritium component of the lighting is often more expensive than the rest of the watch itself, manufacturers try to use as little as possible. [citation needed] Being an unstable isotope with a half-life of 12.32 years, tritium loses half its brightness in that period. The more tritium that is initially placed in the tube, the brighter it is to begin with, and the longer its useful life. Tritium exit signs usually come in three brightness levels guaranteed for 10-, 15-, or 20-year useful life expectancies.[2] The difference between the signs is how much tritium the manufacturer installs.
The light produced by GTLSs varies in colour and size. Green is usually the brightest color and white the least bright. Sizes can be found ranging from tiny tubes small enough to fit on the hand of a watch to ones the size of a pencil. When it comes to large ones (5mm diameter and up to 100mm long), they are usually only found in green and can surprisingly be not as bright as the standard 22.5mm x 3mm sized tritium; this smaller size is usually the brightest and is used mainly in key chains available commercially.
Uses
These light sources are most often seen as "permanent" illumination for the hands of wristwatches intended for diving, nighttime, or combat use. They are also used in glowing novelty keychains and in self-illuminated exit signs. They are favored by the military for applications where a power source may not be available, such as for instrument dials in aircraft, compasses, and sights for weapons.
Tritium lights are also found in some old rotary dial telephones, though due to their age they no longer produce a useful amount of light. Tritium lights or beta lights were formerly [when?] used in fishing lures. Some flashlights have slots for tritium vials so that the flashlight can be easily located in the dark.
Tritium is used to illuminate the iron sights of some small arms. The reticle on the SA80's optical SUSAT sight as well as the LPS 4x6° TIP2 telescopic sight of a PSL rifle, contains a small amount of tritium for the same effect as an example of tritium use on a rifle sight. The electrons emitted by the radioactive decay of the tritium cause phosphor to glow, thus providing a long-lasting (several years) and non-battery-powered firearms sight that is visible in dim lighting conditions. The tritium glow is not noticeable in bright conditions such as during daylight, however. As a result, some manufacturers have started to integrate fiber optic sights with tritium vials to provide bright, high-contrast firearms sights in both bright and dim conditions.
Safety
While these devices contain a radioactive substance, it is currently believed that self-powered lighting does not pose a significant health concern. A 2007 report by the UK government's Health Protection Agency Advisory Group on Ionizing Radiation declared the health risks of tritium exposure to be double than previously set by the International Commission on Radiological Protection,[3] but encapsulated tritium lighting devices, typically taking the form of a luminous glass tube embedded in a thick block of clear plastic, prevent the user from being exposed to the tritium at all unless the device is broken apart.
Tritium presents no external radiation threat via beta radiation when encapsulated in non-hydrogen-permeable containers due to its low penetration depth, which is insufficient to penetrate intact human skin. However, GTLS devices do emit low levels of X-rays due to bremsstrahlung.[4] The primary danger from tritium arises if it is inhaled, ingested, injected, or absorbed into the body. This results in the absorption of the emitted radiation in a relatively small region of the body, again due to the low penetration depth. The biological half-life of tritium—the time it takes for half of an ingested dose to be expelled from the body—is low, at only 12 days. Tritium excretion can be accelerated further by increasing water intake to 3–4 liters/day.[5]
Direct, short-term exposure to small amounts of tritium is mostly harmless. If a tritium tube breaks, one should leave the area and allow the gas to diffuse into the air. Tritium exists naturally in the environment, but in very small quantities. Persons working with the gas face another hazard: tritium reacts with the oxygen in air, forming tritiated water. This moisture is readily ingested by the body. When in contact with any hydrocarbon the tritium atom replaces the natural hydrogen. This can even occur with the natural oil on a person's skin.[citation needed]
Legislation
Because tritium in particular is an integral part of certain thermonuclear devices (though in quantities several thousand times larger than that in a keychain), consumer and safety devices containing tritium for use in the United States are subject to certain possession, resale, disposal, and use restrictions. In the US, devices such as self-luminous exit signs, gauges, wrist watches, etc. that contain small amounts of tritium are under the jurisdiction of the Nuclear Regulatory Commission, and are subject to possession, distribution, and import and export regulations found in 10 CFR Parts, 30, 32, and 110. They are also subject to regulations for possession, use and disposal in certain states. Luminous products containing quantities of tritium greater than that which is used for a wrist watch are not widely available at retail outlets in the United States.[citation needed]
They are readily sold and used in the US and are widely available in the UK and are regulated in England and Wales by environmental health departments of local councils. Tritium lighting is legal in most of Asia and Australia.[citation needed]
See also
References
- ^ Oliveira, Pedro (2012). The Elements: Periodic Table Reference. pediapress.com. p. 1192. Retrieved July 30, 2014.
- ^ https://www.usfa.fema.gov/downloads/pdf/techtalk/techtalk_v1n1_0709.pdf
- ^ "HPA Press Statement – Advice on risks from tritium" (Press release). Health Protection Agency. 29 November 2007. Archived from the original on 2 December 2007. Retrieved 5 February 2011.
- ^ "GASEOUS TRITIUM LIGHT SOURCES (GTLSs) AND GASEOUS TRITIUM LIGHT DEVICES (GTLDs)", Radiation Safety Handbook Volume 2, JSP 392, Ministry of Defence (United Kingdom)
- ^ "www.ehso.emory.edu" (PDF). Nuclide Safety Data Sheet Hydrogen-3. Archived from the original (PDF) on 2006-09-08. Retrieved 2006-11-09.