User:Benjah-bmm27/Task list

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Articles where skeletal formulae need to be explained[edit]

Articles to illustrate[edit]

Inorganic, organometallic, and organic lists[edit]


Article Structure info
Mellite J. Solid State Chem. (1991) 92, 101-109
Trichloroisocyanuric acid Monatsh. Chem. (1987) 118, 1077-1085
Trispyrazolylborate  ?
1,2-Bis(diphenylarsino)ethane Acta Cryst. (2001). E57, o700-o701
1,2-Bis(dimethylarsino)benzene various complexes from CSD
Pyridinium chlorochromate  ?
Sextuple bond MO cartoons
Arsabenzene Chem. Phys. (2009) 356, 187-194
Dalton Trans. (2008) 92-95
Sorafenib  ?
Interstitial compound  ?
Periodic table (crystal structure)  ?
Sulfilimine gas-phase structure of parent
Dichloroacetylene 7572-29-4, Struct. Chem. (1992) 3, 245-252 IR and structure
Neosalvarsan  ?
Arsole Lett. Org. Chem. (2005) 2, 469-474
Melamine cyanurate J. Am. Chem. Soc. (1999) 121, 1752–1753
Tetramesityldisilene Heteroat. Chem. (1990) 1, 1-7
Organometallics (1984) 3, 793–800
J. Chem. Soc., Chem. Commun. (1983) 1010-1011
Cyclohexanehexone  ?
Cyclopentanepentone  ?
Dodecahydroxycyclohexane Acta Cryst. (2005). E61, o1393-o1395
Cinnamic acid Acta Cryst. (2009). B65, 230-237
Carbamic acid Spectrochim. Acta, Part A (1999) 55, 961
Chem. Commun. (2000), 1099-1100
Quadruple bond LCAO, molecular orbital descriptions
4-Hydroxy-3-nitrobenzenearsonic acid Acta Cryst. (1995). C51, 2342-2344

Data unavailable online[edit]

Article Structure info
Amitriptyline J. Pharm. Sci. (1994) 83, 1253–1256
Bis(triphenylphosphine)iminium chloride check CSD
Pirimiphos-methyl check CSD -

In the news[edit]

News story Article Structure info
Trial drugs 'reverse' Alzheimer's, BBC News Online, 6 May 2009 Histone deacetylase inhibitor  ?
Kidney cancer drug gets go-ahead, BBC News Online, 4 February 2009
Cancer drug rejected for NHS use, BBC News Online, 9 July 2007
Sunitinib  ?

Jmol to make[edit]

Jmol models on my website:


Articles to expand[edit]

Articles to start[edit]

Article Synonyms CAS number Type Date first considered Sources of information Related articles
Iron(II) iodide ferrous iodide 7783-86-0 inorganic compound 2012-05-08 G&E, pp. 1083-1084 Iron(II) fluoride, iron(II) chloride, iron(II) bromide
Diiodides: Barium iodide, Beryllium iodide, Cadmium iodide, Calcium iodide, Cobalt(II) iodide, Germanium(II) iodide, Lead(II) iodide, Manganese(II) iodide, Magnesium iodide, Mercury(II) iodide, Nickel(II) iodide, Palladium(II) iodide, Samarium(II) iodide, Strontium iodide, Tin(II) iodide, Zinc iodide
Iron(III) iodide ferric iodide 15600-49-4 inorganic compound 2012-05-08 G&E, pp. 1083-1084 Iron(III) fluoride, iron(III) chloride, iron(III) bromide
Triiodides: Nitrogen triiodide, Phosphorus triiodide, Bismuth(III) iodide, Gallium(III) iodide, Aluminium iodide, Antimony triiodide, Arsenic triiodide, Boron triiodide, , Vanadium(III) iodide, Terbium(III) iodide
 ? N/A reaction 2011-03-01 Nature (2008) 456, 778-782
J. Am. Chem. Soc. (2010) 132, 4025–4028
Organoboron chemistry
Carbamoyl chloride
Asymmetric synthesis
Pivalonitrile tert-Butyl cyanide, Trimethylacetonitrile 630-18-2 organic compound 2010-06-26 MSDS
ChemSpider: pivalonitrile
Rhodium(III) iodide Rhodium triiodide 15492-38-3 inorganic compound 2010-05-11 CrystalWeb
ChemSpider: RhI3
Rhodium(III) chloride
Zeitschrift für Kristallographie Z. Krist. N/A journal 2010-04-26 Category:Scientific journals A B C
Germanium tetrafluoride Germanium(IV) fluoride
Germanium tetrafluoride
7783-58-6 inorganic compound 2010-04-15 Carbon tetrafluoride
Silicon tetrafluoride
Tin(IV) fluoride
Lead tetrafluoride Lead(IV) fluoride
7783-59-7 inorganic compound 2010-04-15 Tin(IV) fluoride
Lead(IV) chloride
Lead(II) fluoride
Hexacyclinol  ????-??-? organic compound 2010 ChemSpider: hexacyclinol
Acta Cryst. (2010). E66, o342-o343
C&EN 2006
Org. Lett. (2009) 11, 1409–1412

Completed articles[edit]

Questions to answer[edit]

  • Why are Sn(IV) and Pb(IV) alkyls and aryls common whereas their Sn(II) and Pb(II) equivalents are almost unknown? Opposite effect is seen for halides, oxides, etc. Inert pair effect any use? G&E 399-405.
  • Why are some metals magnetic and others not?
  • Why do electronegative elements always have lone pairs?
  • Is Gillespie's ionic model of BF3 widely accepted? If so, hypervalency becomes much less of a problem for classical bonding theories, since e.g. PF5 can be simply described as a resonance hybrid of various [PF4]+F species. This was Langmuir's view.