John F. Hartwig

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John F. Hartwig
John Hartwig at the 2007 Boston ACS meeting
Born
John F. Hartwig

1964 (Elmhurst, IL)
United States
NationalityAmerican
Alma materPh.D (1990) University of California, Berkeley
A.B. (1986) Princeton University
Known forOrganometallic chemistry, inorganic chemistry, Catalysis
AwardsWillard Gibbs Award (2015)
Wolf Prize in Chemistry (2019)
Scientific career
FieldsChemistry
InstitutionsUniversity of California, Berkeley
Doctoral advisorsRobert G. Bergman and Richard A. Anderson

John F. Hartwig is an American organometallic chemist who holds the position of Henry Rapoport Professor of Chemistry at the University of California, Berkeley. His laboratory traditionally focuses on developing transition metal-catalyzed reactions. Hartwig is known for helping develop the Buchwald–Hartwig amination, a chemical reaction used in organic chemistry for the synthesis of carbon–nitrogen bonds via the palladium-catalyzed cross-coupling of amines with aryl halides.

Education and training

Hartwig received his A.B. from Princeton University in 1986. With Robert Bergman and Richard Andersen as coadvisors, he earned his Ph.D. from the University of California, Berkeley in 1990. Thereafter he was an American Cancer Society Postdoctoral Associate at MIT, where he worked in the laboratory of Stephen J. Lippard.

Independent career

He assumed an independent position at Yale University in 1992. Over the next 14 years, he was promoted to associate professor, full professor and finally the Irénée duPont professorship. During this period, the Buchwald–Hartwig amination. Here is an example of this reaction (OTf = triflate or trifluoromethanesulfonate):

The Buchwald–Hartwig reaction
The Buchwald–Hartwig reaction

Also while at Yale, he discovered the metal-catalyzed borylation of unactivated C-H bonds.[1][2]

Aliphatic C–H borylation
Aliphatic C–H borylation

In 2006, he assumed the Kenneth L. Reinhart Jr. professorship at the University of Illinois at Urbana–Champaign. There he published "Organotransition Metal Chemistry: From Bonding to Catalysis."[3] In 2011 he returned to Berkeley as Henry Rapoport Professor of Chemistry as well as a member of the Lawrence Berkeley National Laboratory. He was elected to the National Academy of Sciences in 2012. In 2019, together with Stephen Buchwald, he was awarded the Wolfe Prize.

Memberships, fellowships, and awards

2020 Clarivate Citation Laureate
2019 Wolf Prize in Chemistry[4]
2015 Member, American Academy of Arts and Sciences[5]
2015 Willard Gibbs Award[6]
2014 Janssen Pharmaceutical Prize
2013 Herbert C. Brown Award for Creative Research in Synthetic Methods[8]
2012 Member, National Academy of Sciences
2010 GlaxoSmithKline Scholars Award
2009 Edward Mack Jr. Memorial Award, Ohio State University
2009 Mitsui Chemicals Catalysis Science Award, Japan[9]
2009 Joseph Chatt Award of the Royal Society of Chemistry[10]
2008 International Catalysis Award from the International Association of Catalysis Society[11]
2008 Mukaiyama Award from the Society of Synthetic Organic Chemistry, Japan[12]
2008 Paul N. Rylander Award [de] of the Organic Reactions Catalysis Society
2007 Raymond and Beverly Sackler Prize in the Physical Sciences
2007 Tetrahedron Young Investigator Award in Organic Synthesis[13]
2006 ACS Award in Organometallic Chemistry[14]
2005 Fellow of the American Association for the Advancement of Science
2004 Thieme-IUPAC Prize in Synthetic Organic Chemistry[15]
2003 Leo Hendrik Baekeland Award[16]
1998 Arthur C. Cope Scholar Award[17]
1997 Camille Dreyfus Teacher-Scholar Award[18]
1992 Dreyfus Foundation New Faculty Award


References

  1. ^ Chen, H.; Schlecht, S.; Semple, T. C.; Hartwig, J. F. (2000). "Thermal, Catalytic, Regiospecific Functionalization of Alkanes". Science. 287 (5460): 1995–1997. Bibcode:2000Sci...287.1995C. doi:10.1126/science.287.5460.1995. PMID 10720320.
  2. ^ Hartwig, J.F. Accounts of Chemical Research 2012, 45, 864-873.
  3. ^ Hartwig, John (2010). Organotransition Metal Chemistry: From Bonding to Catalysis. New York: University Science Books. p. 1160. ISBN 978-1-938787-15-7.
  4. ^ Wolf Prize 2019 - Jerusalem Post
  5. ^ American Academy of Arts and Sciences - 2015 Class list
  6. ^ American Chemical Society - Chicago Section
  7. ^ Nagoya Medals of Organic Chemistry 2014
  8. ^ ACS Awards - Herbert C. Brown Award for Creative Research in Synthetic Methods
  9. ^ Mitsui Chemicals Catalysis Science Award
  10. ^ RSC Joseph Chatt Award page
  11. ^ The International Association of the Catalysis Societies
  12. ^ Society of Synthetic Organic Chemistry, Japan - "What's the Mukaiyama Award?
  13. ^ Tetrahedron Young Investigator Award Archived 2015-04-19 at the Wayback Machine
  14. ^ ACS Awards - ACS Award in Organometallic Chemistry
  15. ^ Thieme-IUPAC Prize in Synthetic Organic Chemistry (Previous Winners)
  16. ^ American Chemical Society - North Jersey Section (Awards)
  17. ^ ACS Awards - Arthur C. Cope Scholar Awards Archived 2015-06-09 at the Wayback Machine
  18. ^ Camille Dreyfus Teacher-Scholar Awards
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