Chloramines refer to derivatives of ammonia and organic amines wherein one or more N-H bonds have been replaced by N-Cl bonds. Two classes of compounds are considered: inorganic chloramines and organic chloramines.
Chloramines are commonly produced by the action of bleach on secondary amines:
- R2NH + NaOCl → R2NCl + NaOH
- R2NH + t-BuOCl → R2NCl + t-BuOH
Chloramines also refers to any chloramine formed by chlorine reacting with ammonia introduced into swimming pools by human perspiration, saliva, mucus, urine, and other biologic substances, and by insects and other pests. Chloramines are responsible for the "chlorine smell" of pools, as well as skin and eye irritation. These problems are the result of insufficient levels of free available chlorine, and indicate a pool that must be "shocked" by the addition of 5-10 times the normal amount of chlorine.
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- "Controlling Chloramines in Indoor Swimming Pools". NSW Government Health. 3 December 2012. Retrieved 20 February 2013.
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