Lead(II) sulfide
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| Names | |
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| Other names
Plumbous sulfide
Galena, Sulphuret of lead | |
| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
| ECHA InfoCard | 100.013.861 |
CompTox Dashboard (EPA)
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| Properties | |
| PbS | |
| Molar mass | 239.30 g/mol |
| Density | 7.60 g/cm3[1] |
| Melting point | 1,118 °C (2,044 °F; 1,391 K) |
| Boiling point | 1,281 °C (2,338 °F; 1,554 K) |
| 2.6×10−11 kg/kg (calculated, at pH=7)[2] 8.6×10−7 kg/kg[3] | |
Solubility product (Ksp)
|
9.04×10−29 |
Refractive index (nD)
|
3.91 |
| Structure | |
| Halite (cubic), cF8 | |
| Fm3m, No. 225 | |
a = 5.936 Angstroms [4]
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| Octahedral (Pb2+) Octahedral (S2−) | |
| Thermochemistry | |
Heat capacity (C)
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46.02 J/degree mol |
Std molar
entropy (S⦵298) |
91.3 J/mol |
Std enthalpy of
formation (ΔfH⦵298) |
–98.7 kJ/mol |
| Hazards | |
| NFPA 704 (fire diamond) | |
| Flash point | Non-flammable |
| Safety data sheet (SDS) | External MSDS |
| Related compounds | |
Other anions
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Lead(II) oxide Lead selenide Lead telluride |
Other cations
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Carbon monosulfide Silicon monosulfide Germanium(II) sulfide Tin(II) sulfide |
Related compounds
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Thallium sulfide Lead(IV) sulfide Bismuth sulfide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Lead(II) sulfide (also spelled sulphide) is an inorganic compound with the formula PbS. PbS, also known as galena, is the principal ore, and most important compound of lead. It is a semiconducting material with niche uses.
Formation, basic properties, related materials
Addition of hydrogen sulfide or sulfide salts to a solution of lead ions gives PbS as an insoluble black precipitate.
- Pb2+ + H2S → PbS + 2 H+
The equilibrium constant for this reaction is 3×106 M.[5] This reaction, which entails a dramatic color change from colourless or white to black, was once used in qualitative inorganic analysis. The presence of hydrogen sulfide or sulfide ions is still routinely tested using "lead acetate paper."
Like the related materials PbSe and PbTe, PbS is a semiconductor.[6] In fact, lead sulfide was one of the earliest materials to be used as a semiconductor.[7] Lead sulfide crystallizes in the sodium chloride motif, unlike many other IV-VI semiconductors.
Since PbS is the main ore of lead, much effort has focused on its conversion. A major process involves smelting of PbS followed by reduction of the resulting oxide. Idealized equations for these two steps are:[8]
- 2 PbS + 3 O2 → 2 PbO + 2 SO2
- PbO + C → Pb + CO
The sulfur dioxide is converted to sulfuric acid.
Nanoparticles
Lead sulfide-containing nanoparticle and quantum dots have been well studied.[9] Traditionally, such materials are produced by combining lead salts with a variety of sulfide sources.[10][11] PbS nanoparticles have been recent examined for use in solar cells.[12]
Applications
PbS was once used as a black pigment, but current applications exploit its semiconductor properties, which have long been recognized.[13]
Infrared sensor (Photoconductor)
PbS is one of the oldest and most common detection element materials in various infrared detectors. As an infrared detector, PbS functions as a photon detector, responding directly to the photons of radiation, as opposed to thermal detectors, which respond to a change in detector element temperature caused by the radiation. A PbS element can be used to measure radiation in either of two ways: by measuring the tiny photocurrent the photons cause when they hit the PbS material, or by measuring the change in the material's electrical resistance that the photons cause. Measuring the resistance change is the more commonly used method. At room temperature, PbS is sensitive to radiation at wavelengths between approximately 1 and 2.5 μm. This range corresponds to the shorter wavelengths in the infra-red portion of the spectrum, the so-called short-wavelength infrared (SWIR). Only very hot objects emit radiation in these wavelengths.
Cooling the PbS elements, for example using liquid nitrogen or a Peltier element system, shifts its sensitivity range to between approximately 2 and 4 μm. Objects that emit radiation in these wavelengths still have to be quite hot—several hundred degrees Celsius—but not as hot as those detectable by uncooled sensors. (Other compounds used for this purpose include indium antimonide (InSb) and mercury-cadmium telluride (HgCdTe), which have somewhat better properties for detecting the longer IR wavelengths.) The high dielectric constant of PbS leads to relatively slow detectors (compared to silicon, germanium, InSb, or HgCdTe).
Astronomy
Elevations above 2.6 km (1.63 mi) on the planet Venus are coated with a shiny substance. Though the composition of this coat is not entirely certain, one theory is that Venus "snows" crystallized lead sulfide much as Earth snows frozen water. If this is the case, it would be the first time the substance was identified on a foreign planet. Other less likely candidates for Venus' "snow" are bismuth sulfide and tellurium.[14]
Safety
Lead(II) sulfide is so insoluble that it is almost nontoxic, but pyrolysis of the material, as in smelting, gives dangerous fumes.[15] Lead sulfide is insoluble and a stable compound in the pH of blood and so is probably one of the less toxic forms of lead.[16] A large safety risk occurs in the synthesis of PbS using lead carboxylates, as they are particularly soluble and can cause negative physiological conditions.
References
- ^ Patnaik, Pradyot (2003). Handbook of Inorganic Chemical Compounds. McGraw-Hill. ISBN 0-07-049439-8. Retrieved 2009-06-06.
- ^ W. Linke (1965). Solubilities. Inorganic and Metal-Organic Compounds. Vol. 2. Washington, D.C.: American Chemical Society. p. 1318.
- ^ Ronald Eisler (2000). Handbook of Chemical Risk Assessment. CRC Press. ISBN 1-56670-506-1.
- ^ http://www.springermaterials.com/docs/pdf/10681727_889.html
- ^ Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton, Florida: CRC Press. ISBN 0-8493-0486-5.
- ^ Vaughan, D. J.; Craig, J. R. (1978). Mineral Chemistry of Metal Sulfides. Cambridge: Cambridge University Press. ISBN 0-521-21489-0.
{{cite book}}: CS1 maint: multiple names: authors list (link); - ^ C.Michael Hogan. 2011. Sulfur. Encyclopedia of Earth, eds. A.Jorgensen and C.J.Cleveland, National Council for Science and the environment, Washington DC
- ^ Charles A. Sutherland, Edward F. Milner, Robert C. Kerby, Herbert Teindl, Albert Melin, Hermann M. Bolt (2005). Lead. in Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a15_193.pub2.
{{cite book}}: CS1 maint: multiple names: authors list (link) - ^ "The Quantum Mechanics of Larger Semiconductor Clusters ("Quantum Dots")". Annual Review of Physical Chemistry. 41 (1): 477–496. 1990-01-01. doi:10.1146/annurev.pc.41.100190.002401.
- ^ Zhou, H. S.; Honma, I.; Komiyama, H.; Haus, Joseph W. (2002-05-01). "Coated semiconductor nanoparticles; the cadmium sulfide/lead sulfide system's synthesis and properties". The Journal of Physical Chemistry. 97 (4): 895–901. doi:10.1021/j100106a015.
- ^ Wang, Wenzhong; Liu, Yingkai; Zhan, Yongjie; Zheng, Changlin; Wang, Guanghou (2001-09-15). "A novel and simple one-step solid-state reaction for the synthesis of PbS nanoparticles in the presence of a suitable surfactant". Materials Research Bulletin. 36 (11): 1977–1984. doi:10.1016/S0025-5408(01)00678-X.
- ^ Lee, HyoJoong; Leventis, Henry C.; Moon, Soo-Jin; Chen, Peter; Ito, Seigo; Haque, Saif A.; Torres, Tomas; Nüesch, Frank; Geiger, Thomas (2009-09-09). "PbS and CdS Quantum Dot-Sensitized Solid-State Solar Cells: "Old Concepts, New Results"". Advanced Functional Materials. 19 (17): 2735–2742. doi:10.1002/adfm.200900081. ISSN 1616-3028.
- ^ Putley, E H; Arthur, J B (1951). "Lead Sulphide – An Intrinsic Semiconductor". Proceedings of the Physical Society. Series B. 64: 616. doi:10.1088/0370-1301/64/7/110.
- ^ "'Heavy metal' snow on Venus is lead sulfide". Washington University in St. Louis. Retrieved 2009-07-07.
- ^ Lead sulfide MSDS
- ^ Fritz Bischoff, L. C. Maxwell, Richard D. Evens and Franklin R. Nuzum (1928). "Studies on the Toxicity of Various Lead Compounds Given Intravenously". Journal of Pharmacology and Experimental Therapeutics. 34 (1): 85–109.
{{cite journal}}: CS1 maint: multiple names: authors list (link)
External links
