Jump to content

Palladium(II) nitrate

From Wikipedia, the free encyclopedia

This is an old revision of this page, as edited by CheMoBot (talk | contribs) at 02:22, 26 March 2017 (Updating {{chembox}} (changes to verified fields - added verified revid - updated 'UNII_Ref', 'Verifiedfields', 'verifiedrevid') per Chem/infobox_drug validation (report errors or [[user talk:Ch...). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

Palladium(II) nitrate
Palladium(II) nitrate
Names
IUPAC name
Palladium(II) nitrate
Other names
Palladium nitrate
Palladous nitrate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.228 Edit this at Wikidata
UNII
  • InChI=1S/2NO3.Pd/c2*2-1(3)4;/q2*-1;+2 checkY
    Key: GPNDARIEYHPYAY-UHFFFAOYSA-N checkY
  • InChI=1/2NO3.Pd/c2*2-1(3)4;/q2*-1;+2
    Key: GPNDARIEYHPYAY-UHFFFAOYAP
  • [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O
Properties
Pd(NO3)2
Molar mass 230.43 g/mol
Appearance red-brown solid
Melting point Decomposes >100 °C
Soluble
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Irritant, possibility of allergic reaction
Flash point Non-flammable
Related compounds
Other anions
Palladium(II) chloride
Other cations
Nickel(II) nitrate
Related compounds
Silver nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Palladium(II) nitrate is the inorganic compound with the formula Pd(NO3)2. It is a red-brown deliquescent solid. As a solution in nitric acid, it catalyzes the conversion of alkenes to dinitrate esters. Its pyrolysis affords palladium oxide.[1]

Preparation

Palladium nitrate may be prepared by dissolving palladium oxide hydrate in dilute nitric acid followed by crystallization. The nitrate crystallizes as yellow-brown deliquescent prisms. Alternatively, the compound may be obtained by treating palladium metal with nitric acid.

References

  1. ^ Timothy T. Wenzel "Palladium(II) Nitrate" Encyclopedia of Reagents for Organic Synthesis 2001, John Wiley & Sons. doi:10.1002/047084289X.rp013