|Phase (matter) has been listed as a level-4 vital article in Science. If you can improve it, please do. This article has been rated as B-Class.|
|WikiProject Chemical and Bio Engineering|
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|Wikipedia Version 1.0 Editorial Team / v0.5 / Core||(Rated B-class)|
- 1 Example
- 2 Photos?
- 3 Bose-Einstein concentrate
- 4 Added "copypaste" template
- 5 Title is misleading
- 6 State of matter disambiguated
- 7 Question
- 8 Second order phase transitions
- 9 Temperature distribution of phases of the elements
- 10 General question about phases of matter
- 11 Fall 2008 re-write
- 12 IUPAC Gold Book
- 13 if water will notfunction as the solvent
- 14 Phase transitions
- 15 State Of Matter
- 16 500+ phases
- 17 List of phases?
- 18 History
I think that a water ballon is not a good example of the 'incompressibility' of water. Water balloons squish around in your hand and it is hard to tell whether the volume has changed. ike9898 13:33, 27 November 2005 (UTC)
- When I think about it, I imagine a "corked" pump (such as one used to fill a bicycle tire or even a hyperdermic needle) filled with water as opposed to air. I even think a plastic zip-top bag filled with water is a better example than the balloon, but I can understand how a water balloon can create better imagery. The_Irrelevant_One 19:03, 12 March 2006 (UTC)
Can we think of a good photo to add to the top of the article? (It's just for appearance). RJFJR 15:47, 6 October 2006 (UTC)
Following the request of PhotoCatBot to check if a photo is still needed, I have now added a nice photo of an argon crystal simultaneously melting and evaporating. Dirac66 (talk) 00:24, 14 April 2009 (UTC)
- Today 22.214.171.124 added the note "at 273K temperature" to the caption of this photo. However from the descriptions of this photo by the photographer (User:Deglr6328) at File:Argon ice 1.jpg#Summary and at greater length at Wikipedia:Featured picture candidates/Argon ice, it is clear that the temperature was not controlled or measured while the photo was taken. The sample was in the process of warming rapidly from liquid nitrogen temperature (77 K), and no specific value of the temperature at the moment of the photo is claimed. So I will now delete the note about the temperature. Dirac66 (talk) 03:29, 12 November 2012 (UTC)
The melting argon ice photo is striking, but a bit hard to understand, which might be fixed by a more thorough explanation in the caption, or a different picture. I couldn't see any solid-liquid interface in the picture, so at first I thought there was only liquid argon, wetting the inside of the glass tube and dripping out, and then evaporating. The presence of both liquid and vapor is evident, due to the falling liquid drops and the fog formed when the cold, transparent argon gas phase mixes with the surrounding humid air, but unfortunately the fog isn't itself a phase, but rather a two-phase region. This could all be explained, but maybe a cleaner approach to showing three coexisting phases would be a picture of a lump of solid bromine, melting to form a puddle of liquid bromine, with a visible cloud of red bromine gas above. The bromine article has a nice picture of a bottle of bromine showing coexisting liquid and gaseous phases, so anyone who has such a bottle shouldn't have much trouble making one with all 3 phases showing. Put the bottle on a slant in a freezer at -10C, then take it out and let the frozen bromine partly melt, meanwhile forming some bromine gas. The liquid and solid bromine would be both opaque brown but could be distinguished by the solid part still being on a slant while the liquid part was level.CharlesHBennett (talk) 14:02, 3 May 2013 (UTC)
- In the argon photo, I think the white streaks near the centre of the test tube are the solid, and the clear areas surrounding are the liquid. Dirac66 (talk) 18:52, 6 May 2013 (UTC)
shouldent it be added, it is a distinct type of matter
- Bose-Einstein condensate is already there, with a link to its own page.
Added "copypaste" template
I'm surprised this article earned a B-class assessment. Several sections use the first person and tone that strongly resembles a science textbook, leading me to believe the text has been copied from some (uncited) educational material. Some examples:
- Under General definition of phases: "When discussing the solid, liquid, and gaseous phases, we talked about rigidity and compressibility, and the effects..." and "On the other hand, when discussing paramagnetism and ferromagnetism, we looked at..." What previous discussion can these refer to, other than preceding chapters of a larger work?
- Under Other examples of phases: "In this section, we will present several systems that exhibit phase phenomena" is entirely unnecessary and resembles the preamble to a textbook section or subsection.
- The word "we" appears at least 11 times.
I have declined to do the extensive editing required to transform this textbook chapter into proper Wikipedia article. If the source can be identified and is in the public domain, then such editing can take place; otherwise the article should be substantially rewritten. The current text is unacceptable for an article identified as a 1.0 Core Topic. -- PaulKishimoto 20:04, 2 January 2007 (UTC)
- I've identified the origin: http://en.wikipedia.org/w/index.php?title=Phase_%28matter%29&diff=18722376&oldid=18528013 126.96.36.199 05:31, 4 January 2007 (UTC)
- The text is here also but if that is the original it was already pasted into this article in 2003:
The last version before the paste:
I suggest that we trim down the article with respect to the pasted-in material and then reevaluate the 2003 material
V8rik 17:20, 12 January 2007 (UTC)
- Hmm, it looks like even that image has a questionable copyright, as it was created from an image which was recreated due to a copyright problem. As to the text, I'm going to remove all of it that seems to be in violation. The original adder is evidently no longer active here. 188.8.131.52 11:55, 10 February 2007 (UTC)
Title is misleading
Here and in the 'list of Phases of matter' article there is confusion between the usage of 'phase' to denote the difference of liquid vs. solid as opposed to the the difference between diamond and graphite. The liquid vs. solid distinction is properly a difference in 'state of matter' -- yes they are necessarily different phases, too. However, in the diamond vs. graphite case, both ate the same state of matter (solid) but different phases.
There is much in the first two paragraphs which do not belong in an article on phases, but which should instead be part of an article on 'states of matter'. Although there may be some contexts where 'phase' and 'state of matter' may be used interchangeably, it only adds to the confusion here.
I propose that the solid/liquid/gas/Bose-Einstein condensate part of this article be removed to another article dealing with states of matter, and this article focus on the other meaning (diamond vs. graphite, fcc-iron vs. bcc-iron, liquid miscibility issues like oil/water, etc.) Olof
- Confusion, or a difference in terminology? I understand "states of matter" to be a lay term referring to the three principal STP phases (solid, liquid, gas). I agree that there could be improvement, but splitting up the article is unlikely to help. Also, allotropy has its own article already. Do you have a citation for your usage of the terms? –EdC 13:49, 10 January 2007 (UTC)
- By contrast, the P.W. Atkins textbook 'Physical Chemistry' (third edition, 1986) includes this quote on page 10: "Casual inspection of the familiar world reveals the existence of three states of matter: solids, liquids and gases. Closer inspection shows that some materials existin different crystal forms (e.g. carbon can exist as diamond or graphite). These varieties of matter are called its 'phases' ... in rare instances, even the liquid state of a material may occur in different phases with sharply distinct properties" -Olof
- OK, but how are you going to explain phases without reference to the most obvious phase boundaries? Also, what could be the content of an article on "state of matter"? To provide explanations of the solid, liquid and gas phases it would have to repeatedly refer back to this article, or duplicate lots of material. I don't see we need anything more than a paragraph at most explaining when and why the solid/liquid/gas phases are referred to as states, and what the relevant physical quantities are (and possibly how they change at phase boundaries). –EdC 04:41, 11 January 2007 (UTC)
- I disagree completely. An article on states of matter need not make excess reference to the concept of phase. Making the point that the different states of matter (solid, liquid, gas) can be differentiated based on physical properties seems pretty easy. Indeed, an article about the states of matter had better be concerned with those differences. If anything, such an article would make excessive reference to the articles on gas, liquid and solid. And it would make sense for those articles to point to an article on states of matter, not phases.
- On the other hand, an article about phases can provide examples where phases can be differentiated even though the state of matter is the same (oil and water, diamond and graphite, austenite and ferrite, the various iron oxides, the two phases of liquid He, order-disorder transitions, the superconducting transition, spinodal decomposition, crystallization in glasses, phases in 2D surface reconstructions and on and on. And it makes sense for the articles on the phase rule and phase diagrams to point to an article on phases rather than an article on states of matter. The phase rule does not apply to the number of states in a system, it applies to the number of phases. -- Olof
- Yes, but what are those differences? This is physics, not taxonomy. –EdC 13:43, 11 January 2007 (UTC)
State of matter disambiguated
So I've gone and done the disambiguation between state of matter and phase. I believe a number of other articles now are more coherent, and a number of links make more sense.. However, there are plenty of loose ends to do -- and I'm not really sure what to do with the states of matter template -- Olof (talk • contribs) 10:01, 11 January 2007 (UTC).
- OK, I'm not too unhappy with what you've done. However, there are some obvious problems:
- "Phases are sometimes confused with states of matter, but there are significant differences. States of matter refers to the differences between gases, liquids and solids, etc."
- This is a content-free sentence. The article needs to explain why and how phases are clustered into states.
- Other issues, but that's all for now. –EdC 13:42, 11 January 2007 (UTC)
Some careful rewriting is certainly necessary, but note that there is a real distinction between a 2-phase system and a 2-state system. For example an oil-water system has 2 phases (for certain compositions) but only one (liquid) state. Dirac66 (talk) 01:42, 9 November 2008 (UTC)
- I think the definitions as they presently appear are wrong. A phase is a region of a system throughout which all properties are uniform. (Ref. Modell & Reid, Thermodynamics and its Applications (1974) - Maybe not the latest, but an esteemed classic.) But naming the phase and identifying its type does not tell you all the properties of matter in that phase (specific heat, density, etc.). For that, you need to specify temperature, pressure, composition, and anything else that is independently required to reproduce whatever state of matter you are taking about. See thermodynamic state. That's why you need to define "state of matter", which is something more and quite different from simply "phase". I do not see any reference on either page that points towards a different usage of the term "state of matter" from the one I propose. If I change the pages to match these definitions, is anyone going to protest?Paul V. Keller (talk) 02:27, 13 November 2008 (UTC)
- Reading some of the talk, it occured to me that the original intent may have been to use the "state of matter" page to talk about organizations of matter in systems that can be multi-phase. For example, perhaps there was some desire to talk about emulsions versus separated liquid phases or suspensions versus solutions. But I do not see any use for such a definition for "state of matter". What would be the gain in talking about suspensions, colloids, and water-ice systems all on the same page? On the other hand, I can see separate pages for phase behavior (the ways in which matter in equilibrium organizes into one or more phases), phase distribution (possibly a subset of the last, but optionally focusing more on how matter distributes in multi-phase systems, interfacial phenomena, emulsions, colloids, suspensions, liquid crystals, saturation, and solutions. (some of these present already, and some not).
- The long and short of it is I cannot think of a situation in which someone would come across the term "state of matter" and want to read about oil-water two-phase systems and solid suspensions on one page. On the other hand, any information about various kinds of phases fits better in the "phase" pagePaul V. Keller (talk) 16:27, 13 November 2008 (UTC)
Hi there. I was reading this article, and found myself amazed with those two sentences which seem contradictory to me :
- "a phase is a set of states"
- "If there are two regions in a chemical system that are in different states of matter, then they must be different phases"
So my question is : How can we have a phase as as set of states when two states have necessarily two different phases ?
Does the first sentence may in fact be "a state is a set of phases" (which is not as correct as "a system can have multiple phases which are in equilibrium with each other and also in the same state of matter" -I think the best "all-in-one" of this article)
Am I missing something or is my comment right ? --JcDenaes
- The issue is the overloading of the word 'state'. 'State of matter' as a set phrase usually refers to that property of a substance which is one of liquid state, solid state, gaseous state, and a few exotic possibilities (plasma, etc.). When we say 'two states have necessarily two different phases', that means if one thing is a liquid and another thing is a solid, they must be different phases.
- You are right to pick on the phrase "a phase is a set of states" as being confusing. It is. Here's an example where you might use it: Some metals go through a phase transition to and from superconductivity at low temperatures -- a transition to the superconducting state. That's a different kind of state from 'state of matter', because such a metal will still be a solid, but in this case, the distinction of superconductor vs. conductor is one of the set of states that distinguish a phase. 'State of matter' is one, 'state of conductivity' is another.
Thank you a lot ! I understand now. --JcDenaes
Second order phase transitions
There are several misconceptions of phases, and specifically phase transitions in this article. Mostly, it completely ignores second-order phase transitions, in which the free energy function stays differentiable, even at the transition. This also means, that the latent heat (energy related to the change in phase) is zero at the critical value. A perfect example of this is mentioned just above here: the superconducting phase transition. At some critical temperature (or critical magnetic field strength, but this is a bit touchy, as some energy is related to displacing the magnetic field around the superconductor), metallic superconductors become superconducting, which, as mentioned, is a different phase of matter. However, no energy is released in the process, nor is any taken up. This is in clear contradiction to a number of statements in the "General definition..." section. The page on phase transitions has a much clearer description, which should be linked to in stead. 184.108.40.206 (talk) 21:59, 28 November 2007 (UTC)
Temperature distribution of phases of the elements
General question about phases of matter
Is it possible for a metal to become gaseous? I was hoping to find a definitive answer here, but this page seems to be much more technical than I was expecting. —Preceding unsigned comment added by Gforce20 (talk • contribs) 21:34, 9 October 2008 (UTC)
Definitely yes. If any metal is heated to a high enough temperature, it will first melt to become a liquid, and then boil to become a gas. For example, copper has a melting point of 1085“C and a boiling point of 2562°C , so it is a gas at temperatures above 2562°C (at atmospheric pressure). Dirac66 (talk) 22:56, 9 October 2008 (UTC)
Fall 2008 re-write
Further to a discussion above, I undertook a significant rewrite.
The definition of a phase as a "set of states" is now gone. The definition seems to be based on looking at phase diagrams and is not commensurate with the definition in my references, which I know is widely used. The "set of states" definition works poorly when you watch what happens to liquid and gas phases around and "above" the critical point.
I also took out the definition of phase boundaries in terms of the free-energy becoming "non-analytic" That definition seems to derive from experiments where you observe sudden changes in things such as heat capacity as your system moves from a single phase into a two phase region (or back the other way). This type of behavior gets treated in a different guise by the new version. Non-analytic seems to be meant with reference to the phase diagram (derivatives with respect to pressure and temperature), not with respect to space (derivatives with respect to spatial coordinates). Again, the definition based on phase diagrams and phase experiments is certainly not universal. I also wonder whether it is practical outside the study of phase diagrams.
Another problem with the old description and definition is that it was of little or no practical use to anyone who might consult this page. I know I did not understand it the first few time I read it in spite of my have background in this area.
- At the risk of belaboring the point, it occurred to me that a phase diagram-based definition of phases breaks down in the face of super-saturation and bubble nucleation. In both cases, you have a phase that exists outside its bounded domain on the phase diagram. Until you get that first crystal, or that first bubble of adequate size, the expected phase transition does not occur. —Preceding unsigned comment added by Pvkeller (talk • contribs) 20:53, 25 November 2008 (UTC)
The description under "phase separation" also received the axe. The removed material referred to a mathematical model of fluid movement in a dynamic process of phase separation. It was not a model describing when phase separations would occur. It was distracting, meaningless, and useless to nearly anyone who might consult this page. Also, the content was only remotely related to the main topic.
I removed material about solubility, which is a different topic.
If you are looking for a description of the exemplary system having eight immiscible liquid phases, check the footnotes. My reason for removing most of that description was that it did not add enough to the discussion to deserve the space it was taking.Paul V. Keller (talk) 17:17, 25 November 2008 (UTC)
I agree that the rewritten article is at a better level for most readers including chemistry students, and that much of the deleted material was overly mathematical for this article.
- Adding references would be great, but I realized there is still work to be done on the content. Is the other, distinct definition of a phase as a "set of states" in use? Is water said to have X distinct solid phases or X distinct crystal states? If the transition from ordinary medal to superconducting metal involves a phase transition, is the superconducting state described as a distinct phase or a distinct state? I would need to research this. I think we will need to revise this page to reference the second definition or modify the state of matter page. I do not like to leave this unresolved, but do not have time to look further into it at the moment.Paul V. Keller (talk) 14:27, 28 November 2008 (UTC)
First, I realized that the reference which you did add (Modell and Reid) did not appear in the article because your rewrite accidentally omitted the ==References== section with the source code which makes references appear. I have now fixed this.
As for distinct phases vs. distinct states: The enumeration of phases is clear because a phase is well defined as a region with uniform properties. So ice I and ice III are two distinct phases because their density is different, as are normal aluminum and superconducting aluminum because their conductivity is different (one finite, one infinite). Counting phases this way is necessary to satisfy the phase rule: ice I and ice III are in equilibrium on a curve (1 degree of freedom) just like ice I and water, so F=C-P+2 requires that P=2.
The word "states" has several different meanings, as we have already discussed at Talk: State of matter#States of matter vs. Thermodynamic state. The "set of states" definition refers to "thermodynamic states", e.g. ice I at -10oC and 1 atm, ice I at -9.9oC and 1 atm, etc. These refer to one and the same phase whose properties vary slowly. If you want to put this definition back in the article, then "thermodynamic states" would be much clearer.
As for different "crystal states" such as ice I and ice III, their enumeration is variable depending on the author and often the context for the same author. Sometimes "state (of matter)" is used as a synonym for "phase", and other times phrases such as "solid state" imply that ice I and ice III are in the same state. Similarly for normal and superconducting phases of a metal. This is a confusing and unfortunate situation, but Wikipedia cannot impose precision upon the scientific world. Best I think to use "phase" (and perhaps "thermodynamic state") in this article, and keep "states of matter" in the other article without a precise enumeration. Dirac66 (talk) 03:32, 30 November 2008 (UTC)
- I think the only correct answer is to report actual usages. What I found is that various researches variously if not interchangeably use different terms to describe waters various crystal types, the terms including crystalline phases, ices types, and ice states. I personally prefer describing them as different states of matter, with the understanding that the states are differentiated in terms of organization of matter. My preferences, however, are not relevant. I think our job is to report on actual usage, although we are free to organize and explain.
- To clarify, neither phase nor thermodynamic state adequately describes regions of the phase diagram. Phase includes non-equilibrium and unstable conditions. For example, super-heated water is a phase of the liquid type. Under the "set of states" definition, it would be identified as part of the gas phase. Thermodynamic states refer to discrete conditions, not ranges of conditions. I propose to add a section to the state of matter page and a cross-reference on the phase page, pointing out how the terms are actually used on both pages.
- Btw, I read the transition to a superconducting state does involve the crossing of a phase boundary.Paul V. Keller (talk) 20:51, 30 November 2008 (UTC)
- I removed material about solubility, which is a different topic. If you are looking for a description of the exemplary system having eight immiscible liquid phases, check the footnotes. My reason for removing most of that description was that it did not add enough to the discussion to deserve the space it was taking. Solubility isn't really a "different topic". Wikipedia isn't a physics textbook, but rather a general reference. When people search for "phases", this is hopefully the first relevant page they'll find. It must be mentioned on this page that certain substances separate into phases, which are mixtures of the compounds. This phenomenon is not off-topic. Also, what kind of phases can form is also helpful. The short summary doesn't have to deleted because there is a general article Solubility, which, at the current state, actually discusses the issue in a rather cursory manner. Furthermore, there are instances where solubility, or the simple description of it, does not correspond to spontaneous phase separation. Aside from these specifics, removing the link to solubility and the advice "check the footnotes" is not acceptable. To answer to the question of the space it takes, it is a technical/copyediting question. --Vuo (talk) 12:45, 1 December 2008 (UTC)
- I'll grant you I took out more than was necessary and that it was not accurate to say solubility is an entirely seperate topic. However, I object to the way you left the content: it introduce solubility without tying the term to the main topic. The discussion of the Hidebrand solubility parameter is out of place, and to say immiscibility shows mutual insolubilty overlooks that there is often a certain amount of component A in the B-rich phase and vice versa. I am making changes accordingly.Paul V. Keller (talk) 20:47, 1 December 2008 (UTC)
IUPAC Gold Book
(continues previous section: Fall 2008 re-write)
In chemistry the recognized authority for definition of terms is IUPAC, at least for the limited number of terms they consider. The IUPAC Gold Book defines "Phase" as "An entity of a material system which is uniform in chemical composition and physical state."  This is similar to what we have now, and I think we should use the words of IUPAC as the initial definition to start the article, with a link to the Gold Book.
IUPAC does not refer to a set of states, but we could add a remark after the definition. Perhaps something like "For systems in equilibrium, a phase may be considered as a set (or range) of thermodynamic states whose properties vary continuously." Yes, I did forget about non-equilibrium states until reading your last edit; if we follow IUPAC and do not present this remark as a general definition, then we can just exclude them with the initial phrase "For systems in equilibrium".
- It has to be clear that we are not merely putting the definition in a different way, but talking about an overloaded word.
- Gold standard or not, the Modell & Reid definition is more precise, although I agree the difference is small. The authors were MIT professors researching and teaching thermodynamics. I have no idea who writes the IUPAC. I trust my authors thought about the words of their definition very carefully and were informed by many issues that arise in the field. It seems to me "entity" could be ambiguous if not confusing, as could the meaning of "material system". We have useful definitions of system and thermodynamic state and it makes sense to leverage those in the absence of equivalent options.Paul V. Keller (talk) 01:58, 1 December 2008 (UTC)
Well, the Modell-Reid definition is certainly clearer, and close enough to the official IUPAC version so that I think it is acceptable. I agree that "entity" is certainly a confusing word, and "region" is much clearer. The important point is that the basic definition should contain the idea of a uniform subsystem (entity or region in physical space), rather than the idea of a set of states (in parameter space) which is more complicated and also only applies to equilibrium systems. Dirac66 (talk) 04:09, 1 December 2008 (UTC)
if water will notfunction as the solvent
State Of Matter
- That redirect dated from 2004, when there was no State of matter article. I have now fixed the redirect. Dirac66 (talk) 18:00, 5 October 2011 (UTC)
Yes, there are more than 500+ phases. In fact, the Inorganic Crystal Structure Database has 161,030 entries, each of which represent a phase (although some might not have a phase boundary between them). As the authors of the Science paper state in their abstratc, by symmetry arguments alone, there are 230 possible different crystal structures, each of which would need to be its own phase. More phases are indeed possible when one considers additional degrees of freedom. Are you asking us to clarify the number of topologically distinct phases possible in general? Mgibby5 (talk) 14:44, 5 February 2015 (UTC)
List of phases?
I would like to have all known phases of matter listed somewhere, either in the form of a bullet list or as a table. Currently, you just have to read the text in hope of finding them all implicitly listed somewhere, although they are not. Could anyone who know which all these phases are please make a list of them? —Kri (talk) 21:03, 21 July 2014 (UTC)
It is fairly inconvenient to list all possible, distinct phases: each different crystal structure is a different phase, by symmetry arguments. Further, several different phases can exist in equilibrium with each other, but each have the same crystal structure, just as liquids can exist in equilibrium with one another (oil and water are separate phases, despite possessing the same symmetries). It is not useful in practice to provide a list of all possible phases. Mgibby5 (talk) 14:37, 5 February 2015 (UTC)