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Natural units

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In physics, natural units are physical units of measurement in which only universal physical constants are used as defining constants, such that each of these constants acts as a coherent unit of a quantity. For example, the elementary charge e may be used as a natural unit of electric charge, and the speed of light c may be used as a natural unit of speed. A purely natural system of units has all of its units defined such that each of these can be expressed as a product of powers of defining physical constants.

Through nondimensionalization, physical quantities may then be redefined so that the defining constants can be omitted from mathematical expressions of physical laws, and while this has the apparent advantage of simplicity, it may entail a loss of clarity due to the loss of information for dimensional analysis. It precludes the interpretation of an expression in terms of constants, such as e and c, unless it is known which units (in dimensionful units) the expression is supposed to have. In this case, the reinsertion of the correct powers of e, c, etc., can be uniquely determined.

Systems of natural units

Planck units

Quantity Expression Metric value Name
Length (L) (L–H) 5.729×10−35 m Planck length
(G and original) 1.616×10−35 m
Mass (M) (L–H) 6.140×10−9 kg Planck mass
(G and original) 2.176×10−8 kg
Time (T) (L–H) 1.911×10−43 s Planck time
(G and original) 5.391×10−44 s
Electric charge (Q) (original) 1.602×10−19 C Planck charge
(L–H) 5.291×10−19 C
(G) 1.876×10−18 C
Temperature (Θ) (L–H) 3.997×1031 K Planck temperature
(G and original) 1.417×1032 K

The Planck unit system uses the following defining constants:

c, ħ, G, kB,

where c is the speed of light, ħ is the reduced Planck constant, G is the gravitational constant, and kB is the Boltzmann constant.

Planck units form a system of natural units that is not defined in terms of properties of any prototype, physical object, or even elementary particle. They only refer to the basic structure of the laws of physics: c and G are part of the structure of spacetime in general relativity, and ħ is at the foundation of quantum mechanics. This makes Planck units particularly convenient and common in theories of quantum gravity, including string theory.[citation needed]

Planck considered only the units based on the universal constants G, h, c, and kB to arrive at natural units for length, time, mass, and temperature, but no electromagnetic units.[1] The Planck system of units is now understood to use 4πG and the reduced Planck constant ħ, in place of the gravitational constant G and the Planck constant h.[2]

Stoney units

Quantity Expression Metric value
Length (L) 1.38068×10−36 m
Mass (M) 1.85921×10−9 kg
Time (T) 4.60544×10−45 s
Electric charge (Q) 1.60218×10−19 C
Temperature (Θ) 1.21028×1031 K

The Stoney unit system uses the following defining constants:

c, G, ke, e,

where c is the speed of light, G is the gravitational constant, ke is the Coulomb constant, and e is the elementary charge.

George Johnstone Stoney's unit system preceded that of Planck by 30 years. He presented the idea in a lecture entitled "On the Physical Units of Nature" delivered to the British Association in 1874.[3] Stoney units did not consider the Planck constant, which was discovered only after Stoney's proposal. The Stoney units and the Planck units differ by the constant factor [4]

Atomic units

Quantity Expression Metric value
Length (L) (both Hartree and Rydberg) 5.292×10−11 m
Mass (M) (Hartree) 9.109×10−31 kg
(Rydberg) 1.822×10−30 kg
Time (T) (Hartree) 2.419×10−17 s
(Rydberg) 4.838×10−17 s
Electric charge (Q) (Hartree) 1.602×10−19 C
(Rydberg) 1.133×10−19 C
Temperature (Θ) (Hartree) 3.158×105 K
(Rydberg) 1.579×105 K

The Hartree atomic unit system uses the following defining constants:

e, me, ħ, ke.

The Coulomb constant, ke, is generally expressed as 1/4πε0 when working with this system.

These units are designed to simplify atomic and molecular physics and chemistry, especially the hydrogen atom, and are widely used in these fields. The Hartree units were first proposed by Douglas Hartree.

The units are designed especially to characterize the behavior of an electron in the ground state of a hydrogen atom. For example, in Hartree atomic units, in the Bohr model of the hydrogen atom an electron in the ground state has orbital radius (the Bohr radius) a0 = 1 lA, orbital velocity = 1 lAtA−1, angular momentum = 1 mAlAtA−1, ionization energy = 1/2 mAlA2tA−2, etc.

The unit of energy is called the Hartree energy in the Hartree system. The speed of light is relatively large in Hartree atomic units (c = 1/α lAtA−1 ≈ 137 lAtA−1) since an electron in hydrogen tends to move much more slowly than the speed of light. The gravitational constant is extremely small in atomic units (G ≈ 10−45 mA−1lA3tA−2), which is due to the gravitational force between two electrons being far weaker than the Coulomb force between them.

A less commonly used closely related system is the system of Rydberg atomic units, in which e2/2, 2me, ħ, ke are used as the defining constants, with resulting units lR = a0 = (4πε0)ħ2/mee2, tR = 2(4πε0)2ħ3/mee4, mR = 2me, qR = e2.[5]

Natural units (particle and atomic physics)

Unit Metric value Derivation
1 eV−1 of length (L) 1.97×10−7 m
1 eV of mass (M) 1.78×10−36 kg
1 eV−1 of time (T) 6.58×10−16 s
1 unit of electric charge (Q) 5.29×10−19 C (L–H)
1.88×10−18 C (G)
1 eV of temperature (Θ) 1.16×104 K

This natural unit system, used only in the fields of particle and atomic physics, uses the following defining constants:[6]: 509 

c, me, ħ, ε0,

where c is the speed of light, me is the electron mass, ħ is the reduced Planck constant, and ε0 is the vacuum permittivity.

The vacuum permittivity ε0 is implicitly used as a nondimensionalization constant, as is evident from the physicists' expression for the fine-structure constant, written α = e2/(4π),[7][8] which may be compared to the same expression in SI: α = e2/(4πε0ħc).[9]: 128 

Quantum chromodynamics units

Quantity Expression Metric value
Length (L) 2.103×10−16 m
Mass (M) 1.673×10−27 kg
Time (T) 7.015×10−25 s
Electric charge (Q) (original) 1.602×10−19 C
(L–H) 5.291×10−19 C
(G) 1.876×10−18 C
Temperature (Θ) 1.089×1013 K

Defining constants:

c, mp, ħ, ε0.

Here, mp is the proton rest mass. Strong units, also called quantum chromodynamics (QCD) units, are "convenient for work in QCD and nuclear physics, where quantum mechanics and relativity are omnipresent and the proton is an object of central interest".[10]

Schrödinger units

Quantity Expression Metric value
Length (L) 2.593×10−32 m[11]
Mass (M) 1.859×10−9 kg[11]
Time (T) 1.185×10−38 s[11]
Electric charge (Q) 1.602×10−19 C[12]
Temperature (Θ) 6.445×1026 K[11]

The Schrödinger unit system uses the following defining constants:

e, G, ħ, ke.

This system is seldom mentioned in literature as Schrödinger's system of units (after Austrian physicist Erwin Schrödinger).[13][14][11]

In this system of units the speed of light changes in inverse proportion to the fine structure constant, therefore it has gained some interest recent years in the niche hypothesis of time-variation of fundamental constants.[15]

Geometrized units

Defining constants:

c, G.

The geometrized unit system, used in general relativity, is an incompletely defined system. In this system, the base physical units are chosen so that the speed of light and the gravitational constant are coherent units and often used for nondimensionalization. Other units may be treated however desired. Planck units and Stoney units are examples of geometrized unit systems.

Summary table

System
Quantity
Planck Stoney Schrödinger Atomic "Natural" Quantum chromodynamics
original with L–H with Gauss Hartree Rydberg new with L–H with Gauss original with L–H with Gauss
Speed of light
Reduced Planck constant
Vacuum permittivity
Coulomb constant
Gravitational constant
Boltzmann constant
Elementary charge
Electron rest mass
Proton rest mass
Vacuum permeability
Impedance of free space
Bohr radius
Bohr magneton
Josephson constant
von Klitzing constant
Rydberg constant
Stefan–Boltzmann constant

where:

See also

Notes and references

  1. ^ However, if it is assumed that at the time the Gaussian definition of electric charge was used and hence not regarded as an independent quantity, 4πε0 would be implicitly in the list of defining constants, giving a charge unit 4πε0ħc, we can also use the Lorentz–Heaviside units to define ε0, and giving a charge unit ε0ħc.
  2. ^ Tomilin, K. A., 1999, "Natural Systems of Units: To the Centenary Anniversary of the Planck System Archived 2020-12-12 at the Wayback Machine", 287–296.
  3. ^ Ray, T.P. (1981). "Stoney's Fundamental Units". Irish Astronomical Journal. 15: 152. Bibcode:1981IrAJ...15..152R.
  4. ^ Barrow, John D. "Natural units before Planck." Quarterly Journal of the Royal Astronomical Society, Vol. 24, P. 24, 1983 24 (1983): 24.
  5. ^ "Atomic Rydberg Units" (PDF).
  6. ^ Guidry, Mike (1991). "Appendix A: Natural Units". Gauge Field Theories. Weinheim, Germany: Wiley-VCH Verlag. pp. 509–514. doi:10.1002/9783527617357.app1.
  7. ^ Frank Wilczek (2005), "On Absolute Units, I: Choices" (PDF), Physics Today, 58 (10): 12, Bibcode:2005PhT....58j..12W, doi:10.1063/1.2138392, retrieved 2020-05-31
  8. ^ Frank Wilczek (2006), "On Absolute Units, II: Challenges and Responses" (PDF), Physics Today, 59 (1): 10, Bibcode:2006PhT....59a..10W, doi:10.1063/1.2180151, retrieved 2020-05-31
  9. ^ The International System of Units (PDF) (9th ed.), International Bureau of Weights and Measures, Dec 2022, ISBN 978-92-822-2272-0
  10. ^ Wilczek, Frank (2007). "Fundamental Constants". arXiv:0708.4361 [hep-ph].. Further see.
  11. ^ a b c d e Natural Units – The Spectrum Of Riemannium
  12. ^ "2022 CODATA Value: elementary charge". The NIST Reference on Constants, Units, and Uncertainty. NIST. May 2024. Retrieved 2024-05-18.
  13. ^ Duff, Michael James (11 July 2004). "Comment on time-variation of fundamental constants". p. 3. arXiv:hep-th/0208093.
  14. ^ Stohner, Jürgen; Quack, Martin (2011). "Conventions, Symbols, Quantities, Units and Constants for High-Resolution Molecular Spectroscopy". Handbook of High‐resolution Spectroscopy (PDF). p. 304. doi:10.1002/9780470749593.hrs005. ISBN 9780470749593. Retrieved 19 March 2023.
  15. ^ Davis, Tamara Maree (12 February 2004). "Fundamental Aspects of the Expansion of the Universe and Cosmic Horizons". p. 103. arXiv:astro-ph/0402278. In this set of units the speed of light changes in inverse proportion to the fine structure constant. From this we can conclude that if c changes but e and ℏ remain constant then the speed of light in Schrödinger units, cψ changes in proportion to c but the speed of light in Planck units, cP stays the same. Whether or not the "speed of light" changes depends on our measuring system (three possible definitions of the "speed of light" are c, cP and cψ). Whether or not c changes is unambiguous because the measuring system has been defined.