Viscosity

"Fluidity" redirects here. For the ship, see MV Fluidity.

Viscosity
Common symbols	μ
SI unit	Pa s = kg / (s m)
Derivations from other quantities	μ = G · t

For other uses, see Viscosity (disambiguation).

Illustration of viscosity; Green fluid to the left has higher viscosity than the clear liquid on the right.

Viscosity is a measure of the resistance of a fluid which is being deformed by either shear stress or extensional stress. In everyday terms (and for fluids only), viscosity is "thickness." Thus, water is "thin," having a lower viscosity, while honey is "thick," having a higher viscosity. Viscosity describes a fluid's internal resistance to flow and may be thought of as a measure of fluid friction. For example, high-viscosity magma will create a tall, steep stratovolcano, because it cannot flow far before it cools, while low-viscosity lava will create a wide, shallow-sloped shield volcano. Put simply, the less viscous something is, the greater its ease of movement (fluidity). All real fluids (except superfluids) have some resistance to stress, but a fluid which has no resistance to shear stress is known as an ideal fluid or inviscid fluid. The study of viscosity is known as rheology.

Etymology

The word "viscosity" derives from the Latin word "viscum" for mistletoe. A viscous glue was made from mistletoe berries and used for lime-twigs to catch birds.

Viscosity coefficients

When looking at a value for viscosity, the number that one most often sees is the coefficient of viscosity. There are several different viscosity coefficients depending on the nature of applied stress and nature of the fluid. They are introduced in the main books on hydrodynamics and rheology.

• Dynamic viscosity (or absolute viscosity) determines the dynamics of an incompressible Newtonian fluid;
• Kinematic viscosity is the dynamic viscosity divided by the density for a Newtonian fluid;
• Volume viscosity (or bulk viscosity) determines the dynamics of a compressible Newtonian fluid;
• Shear viscosity is the viscosity coefficient when the applied stress is a shear stress (valid for non-Newtonian fluids);
• Extensional viscosity is the viscosity coefficient when the applied stress is an extensional stress (valid for non-Newtonian fluids).

Shear viscosity and dynamic viscosity are much better known than the others. That is why they are often referred to as simply viscosity. Simply put, this quantity is the ratio between the pressure exerted on the surface of a fluid, in the lateral or horizontal direction, to the change in velocity of the fluid as you move down in the fluid (this is what is referred to as a velocity gradient). For example, at room temperature, water has a nominal dynamic viscosity of 1.0 × 10⁻³ Pa∙s and motor oil has a nominal apparent dynamic viscosity of 250 × 10⁻³ Pa∙s. (kinematic viscosity is measured in m²s⁻¹).

Extensional viscosity is widely used for characterizing polymers.

Volume viscosity is essential for acoustics in fluids, see Stokes' law (sound attenuation)

Newton's theory

Laminar shear of fluid between two plates. Friction between the fluid and the moving boundaries causes the fluid to shear. The force required for this action is a measure of the fluid's viscosity. This type of flow is known as a Couette flow.

Laminar shear, the non-constant gradient, is a result of the geometry the fluid is flowing through (e.g. a pipe).

In general, in any flow, layers move at different velocities and the fluid's viscosity arises from the shear stress between the layers that ultimately opposes any applied force.

Isaac Newton postulated that, for straight, parallel and uniform flow, the shear stress, τ, between layers is proportional to the velocity gradient, ∂u /∂y, in the direction perpendicular to the layers.

$\tau =\mu {\frac {\partial u}{\partial y}}.$

Here, the constant μ is known as the coefficient of viscosity, the viscosity, the dynamic viscosity, or the Newtonian viscosity. Many fluids, such as water and most gases, satisfy Newton's criterion and are known as Newtonian fluids. Non-Newtonian fluids exhibit a more complicated relationship between shear stress and velocity gradient than simple linearity.

The relationship between the shear stress and the velocity gradient can also be obtained by considering two plates closely spaced apart at a distance y, and separated by a homogeneous substance. Assuming that the plates are very large, with a large area A, such that edge effects may be ignored, and that the lower plate is fixed, let a force F be applied to the upper plate. If this force causes the substance between the plates to undergo shear flow (as opposed to just shearing elastically until the shear stress in the substance balances the applied force), the substance is called a fluid. The applied force is proportional to the area and velocity of the plate and inversely proportional to the distance between the plates. Combining these three relations results in the equation F = μ (Au/y), where μ is the proportionality factor called the dynamic viscosity (also called absolute viscosity, or simply viscosity). The equation can be expressed in terms of shear stress; τ = F/A = μ (u / y). The rate of shear deformation is u / y and can be also written as a shear velocity, du/dy. Hence, through this method, the relation between the shear stress and the velocity gradient can be obtained.

James Clerk Maxwell called viscosity fugitive elasticity because of the analogy that elastic deformation opposes shear stress in solids, while in viscous fluids, shear stress is opposed by rate of deformation.

Viscosity measurement

Dynamic viscosity is measured with various types of rheometer. Close temperature control of the fluid is essential to accurate measurements, particularly in materials like lubricants, whose viscosity can double with a change of only 5 °C. For some fluids, it is a constant over a wide range of shear rates. These are Newtonian fluids.

The fluids without a constant viscosity are called non-Newtonian fluids. Their viscosity cannot be described by a single number. Non-Newtonian fluids exhibit a variety of different correlations between shear stress and shear rate.

One of the most common instruments for measuring kinematic viscosity is the glass capillary viscometer.

In paint industries, viscosity is commonly measured with a Zahn cup, in which the efflux time is determined and given to customers. The efflux time can also be converted to kinematic viscosities (cSt) through the conversion equations.

A Ford viscosity cup measures the rate of flow of a liquid. This, under ideal conditions, is proportional to the kinematic viscosity.

Also used in paint, a Stormer viscometer uses load-based rotation in order to determine viscosity. The viscosity is reported in Krebs units (KU), which are unique to Stormer viscometers.

Vibrating viscometers can also be used to measure viscosity. These models such as the Dynatrol use vibration rather than rotation to measure viscosity.

Extensional viscosity can be measured with various rheometers that apply extensional stress.

Volume viscosity can be measured with acoustic rheometer.

Units of measure

Dynamic viscosity

The usual symbol for dynamic viscosity used by mechanical and chemical engineers — as well as fluid dynamicists — is the Greek letter mu (μ). The symbol η is also used by chemists and IUPAC. The SI physical unit of dynamic viscosity is the pascal-second (Pa·s), which is identical to kg·m⁻¹·s⁻¹. If a fluid with a viscosity of one Pa·s is placed between two plates, and one plate is pushed sideways with a shear stress of one pascal, it moves a distance equal to the thickness of the layer between the plates in one second.

The cgs physical unit for dynamic viscosity is the poise (P), named after Jean Louis Marie Poiseuille. It is more commonly expressed, particularly in ASTM standards, as centipoise (cP). Water at 20 °C has a viscosity of 1.0020 cP.

1 P = 1 g·cm⁻¹·s⁻¹.

The relation between poise and pascal-seconds is:

10 P = 1 kg·m⁻¹·s⁻¹ = 1 Pa·s,

1 cP = 0.001 Pa·s = 1 mPa·s.

The name 'poiseuille' (Pl) was proposed for this unit (after Jean Louis Marie Poiseuille who formulated Poiseuille's law of viscous flow), but not accepted internationally. Care must be taken in not confusing the poiseuille with the poise named after the same person.

Kinematic viscosity

In many situations, we are concerned with the ratio of the viscous force to the inertial force, the latter characterised by the fluid density ρ. This ratio is characterised by the kinematic viscosity (Greek letter nu, ν), defined as follows:

$\nu ={\frac {\mu }{\rho }},$

where μ is the dynamic viscosity (Pa·s), ρ is the density (kg/m³), and ν is the kinematic viscosity (m²/s).

The cgs physical unit for kinematic viscosity is the stokes (St), named after George Gabriel Stokes. It is sometimes expressed in terms of centistokes (cSt or ctsk). In U.S. usage, stoke is sometimes used as the singular form.

1 stokes = 100 centistokes = 1 cm²·s⁻¹ = 0.0001 m²·s⁻¹.

1 centistokes = 1 mm²·s⁻¹ = 10⁻⁶m²·s⁻¹.

The kinematic viscosity is sometimes referred to as diffusivity of momentum, because it is comparable to and has the same unit (m²s⁻¹) as diffusivity of heat and diffusivity of mass. It is therefore used in dimensionless numbers which compare the ratio of the diffusivities.

Saybolt Universal viscosity

At one time the petroleum industry relied on measuring kinematic viscosity by means of the Saybolt viscometer, and expressing kinematic viscosity in units of Saybolt Universal seconds (SUS). Other abbreviations such as SSU (Saybolt Seconds Universal) or SUV (Saybolt Universal Viscosity) are sometimes used. Kinematic viscosity in centistoke can be converted from SUS according to the arithmetic and the reference table provided in ASTM D 2161. It can also be converted in computerized method, or vice versa.

Relation to mean free path of diffusing particles

In relation to diffusion, the kinematic viscosity provides a better understanding of the behavior of mass transport of a dilute species. Viscosity is related to shear stress and the rate of shear in a fluid, which illustrates its dependence on the mean free path, λ, of the diffusing particles.

From fluid mechanics, shear stress, τ, on a unit area moving parallel to itself, is found to be proportional to the rate of change of velocity with distance perpendicular to the unit area:

$\tau =\mu {\frac {du_{x}}{dy}}.$

for a unit area parallel to the x-z plane, moving along the x axis. We will derive this formula and show how μ is related to λ.

Interpreting shear stress as the time rate of change of momentum, p, per unit area A (rate of momentum flux) of an arbitrary control surface gives

$\tau ={\frac {\dot {p}}{A}}={\frac {{\dot {m}}\langle u_{x}\rangle }{A}}.$

where $\langle u_{x}\rangle$ is the average velocity along x of fluid molecules hitting the unit area, with respect to the unit area.

Further manipulation will show

${\dot {m}}=\rho {\bar {u}}A$

$\langle u_{x}\rangle ={\frac {1}{2}}\,\lambda {\frac {du_{x}}{dy}}$, assuming that molecules hitting the unit area come from all distances between 0 and λ (equally distributed), and that their average velocities change linearly with distance (always true for small enough λ). From this follows:

$\tau =\underbrace {{\frac {1}{2}}\,\rho {\bar {u}}\lambda } _{\mu }\cdot {\frac {du_{x}}{dy}}\;\;\Rightarrow \;\;\nu ={\frac {\mu }{\rho }}={\tfrac {1}{2}}\,{\bar {u}}\lambda ,$

where

${\dot {m}}$ is the rate of fluid mass hitting the surface,

ρ is the density of the fluid,

ū is the average molecular speed (${\bar {u}}={\sqrt {\langle u^{2}\rangle }}$),

μ is the dynamic viscosity.

Dynamic versus kinematic viscosity

Conversion between kinematic and dynamic viscosity is given by ν ρ = μ.

For example,

if ν = 0.0001 m²·s⁻¹ and ρ = 1000 kg m⁻³ then μ = ν ρ = 0.1 kg·m⁻¹·s⁻¹ = 0.1 Pa·s,

if ν = 1 St (= 1 cm²·s⁻¹) and ρ = g cm⁻³ then μ = ν ρ = 1 g·cm⁻¹·s⁻¹ = 1 P.

Example: viscosity of water

Because of its density of ρ = 1 g/cm³ (varies slightly with temperature), and its dynamic viscosity is near 1 mPa·s (see Viscosity of water section), the viscosity values of water are, to rough precision, all powers of ten:

Dynamic viscosity:

μ = 1 mPa·s = 10⁻³ Pa·s = 0.001 kg/(m·s) = 1 cP = 10⁻² poise.

Kinematic viscosity:

ν = 1 cSt = 10⁻² stokes = 1 mm²/s.

Molecular origins

Pitch has a viscosity approximately 230 billion (2.3×10¹¹) times that of water.

The viscosity of a system is determined by how molecules constituting the system interact. There are no simple but correct expressions for the viscosity of a fluid. The simplest exact expressions are the Green–Kubo relations for the linear shear viscosity or the Transient Time Correlation Function expressions derived by Evans and Morriss in 1985. Although these expressions are each exact in order to calculate the viscosity of a dense fluid, using these relations requires the use of molecular dynamics computer simulations.

Gases

Viscosity in gases arises principally from the molecular diffusion that transports momentum between layers of flow. The kinetic theory of gases allows accurate prediction of the behavior of gaseous viscosity.

Within the regime where the theory is applicable:

• Viscosity is independent of pressure and
• Viscosity increases as temperature increases.

James Clerk Maxwell published a famous paper in 1866 using the kinetic theory of gases to study gaseous viscosity. To understand why the viscosity is independent of pressure consider two adjacent boundary layers (A and B) moving with respect to each other. The internal friction (the viscosity) of the gas is determined by the probability a particle of layer A enters layer B with a corresponding transfer of momentum. Maxwell's calculations showed him that the viscosity coefficient is proportional to both the density, the mean free path and the mean velocity of the atoms. On the other hand, the mean free path is inversely proportional to the density. So an increase of pressure doesn't result in any change of the viscosity.

Effect of temperature on the viscosity of a gas

Sutherland's formula can be used to derive the dynamic viscosity of an ideal gas as a function of the temperature:

${\mu }={\mu }_{0}{\frac {T_{0}+C}{T+C}}\left({\frac {T}{T_{0}}}\right)^{3/2}$

This in turn is equal to

$\lambda \cdot {\frac {T^{3/2}}{T+C}},$ where $\lambda ={\frac {\mu _{0}(T_{0}+C)}{T_{0}^{3/2}}}$ is a constant.

in Sutherland's formula:

• μ = dynamic viscosity in (Pa·s) at input temperature T,
• μ₀ = reference viscosity in (Pa·s) at reference temperature T₀,
• T = input temperature in kelvin,
• T₀ = reference temperature in kelvin,
• C = Sutherland's constant for the gaseous material in question.

Valid for temperatures between 0 < T < 555 K with an error due to pressure less than 10% below 3.45 MPa.

Sutherland's constant and reference temperature for some gases

Gas	C [K]	T0 [K]	μ0 [10−6 Pa s]
air	120	291.15	18.27
nitrogen	111	300.55	17.81
oxygen	127	292.25	20.18
carbon dioxide	240	293.15	14.8
carbon monoxide	118	288.15	17.2
hydrogen	72	293.85	8.76
ammonia	370	293.15	9.82
sulfur dioxide	416	293.65	12.54
helium	79.4	273	19

See also [1].

Viscosity of a dilute gas

The Chapman-Enskog equation may be used to estimate viscosity for a dilute gas. This equation is based on a semi-theoretical assumption by Chapman and Enskog. The equation requires three empirically determined parameters: the collision diameter (σ), the maximum energy of attraction divided by the Boltzmann constant (є/к) and the collision integral (ω(T^*)).

${\mu }_{0}\times 10^{7}={266.93}{\frac {(MT)^{1/2}}{\sigma ^{2}\omega (T^{*})}},$

with

• T^* = κT/ε — reduced temperature (dimensionless),
• μ₀ = viscosity for dilute gas (μP),
• M = molecular mass (g/mol),
• T = temperature (K),
• σ = the collision diameter (Å),
• ε / κ = the maximum energy of attraction divided by the Boltzmann constant (K),
• ω_μ = the collision integral.

Liquids

Video showing three liquids with different Viscosities

In liquids, the additional forces between molecules become important. This leads to an additional contribution to the shear stress though the exact mechanics of this are still controversial. Thus, in liquids:

• Viscosity is independent of pressure (except at very high pressure); and
• Viscosity tends to fall as temperature increases (for example, water viscosity goes from 1.79 cP to 0.28 cP in the temperature range from 0 °C to 100 °C); see temperature dependence of liquid viscosity for more details.

The dynamic viscosities of liquids are typically several orders of magnitude higher than dynamic viscosities of gases.

Viscosity of blends of liquids

The viscosity of the blend of two or more liquids can be estimated using the Refutas equation. The calculation is carried out in three steps.

The first step is to calculate the Viscosity Blending Number (VBN) (also called the Viscosity Blending Index) of each component of the blend:

(1)   ${\mbox{VBN}}=14.534\times \ln \left[\ln(v+0.8)\right]+10.975\,$

where v is the kinematic viscosity in centistokes (cSt). It is important that the kinematic viscosity of each component of the blend be obtained at the same temperature.

The next step is to calculate the VBN of the blend, using this equation:

(2)   ${\mbox{VBN}}_{\text{Blend}}=\left[x_{A}\times {\mbox{VBN}}_{A}\right]+\left[x_{B}\times {\mbox{VBN}}_{B}\right]+\cdots +\left[x_{N}\times {\mbox{VBN}}_{N}\right]\,$

where x_X is the mass fraction of each component of the blend.

Once the viscosity blending number of a blend has been calculated using equation (2), the final step is to determine the kinematic viscosity of the blend by solving equation (1) for v:

(3)   $v=\exp \left(\exp \left({\frac {{\text{VBN}}_{\text{Blend}}-10.975}{14.534}}\right)\right)-0.8,$

where VBN_Blend is the viscosity blending number of the blend.

Viscosity of selected substances

The viscosity of air and water are by far the two most important materials for aviation aerodynamics and shipping fluid dynamics. Temperature plays the main role in determining viscosity.

Viscosity of air

The viscosity of air depends mostly on the temperature. At 15.0 °C, the viscosity of air is 1.78×10⁻⁵ kg/(m·s) or 1.78×10⁻⁴ P. One can get the viscosity of air as a function of temperature from the Gas Viscosity Calculator

Viscosity of water

Dynamic Viscosity of Water

The dynamic viscosity of water is 8.90 × 10⁻⁴ Pa·s or 8.90 × 10⁻³ dyn·s/cm² or 0.890 cP at about 25 °C.
As a function of temperature T (K): μ(Pa·s) = A × 10^B/(T−C)
where A=2.414 × 10⁻⁵ Pa·s ; B = 247.8 K ; and C = 140 K.

Viscosity of liquid water at different temperatures up to the normal boiling point is listed below.

Temperature [°C]	Viscosity [Pa·s]
10	1.308e-3
20	1.003e-3
30	7.978e-4
40	6.531e-4
50	5.471e-4
60	4.668e-4
70	4.044e-4
80	3.550e-4
90	3.150e-4
100	2.822e-4

Viscosity of various materials

Example of the viscosity of milk and water. Liquids with higher viscosities will not make such a splash when poured at the same velocity.

Honey being drizzled.

Peanut butter is a semi-solid and so can hold peaks.

Some dynamic viscosities of Newtonian fluids are listed below:

Gases (at 0 °C):

	viscosity [Pa·s]
hydrogen	8.4e-6
air	17.4e-6
xenon	2.12e-5

Liquids (at 25 °C):

	viscosity [Pa·s]	viscosity [cP]
acetone	3.06e-4	0.306
benzene	6.04e-4	0.604
blood (37 °C)	3e-3 to 4e-3	3–4
castor oil	0.985	985
corn syrup	1.3806	1380.6
ethanol	1.074e-3	1.074
ethylene glycol	1.61e-2	16.1
glycerol	1.5	1500
HFO-380	2.022	2022
mercury	1.526e-3	1.526
methanol	5.44e-4	0.544
nitrobenzene	1.863e-3	1.863
liquid nitrogen @ 77K	1.58e-4	0.158
propanol	1.945e-3	1.945
olive oil	.081	81
pitch	2.3e8	2.3e11
sulfuric acid	2.42e-2	24.2
water	8.94e-4	0.894

Fluids with variable compositions, such as honey, can have a wide range of viscosities.

	viscosity [cP]
honey	2,000–10,000
molasses	5,000–10,000
molten glass	10,000–1,000,000
chocolate syrup	10,000–25,000
molten chocolate*	45,000–130,000
ketchup*	50,000–100,000
peanut butter	~250,000
shortening*	~250,000

* These materials are highly non-Newtonian.

Viscosity of solids

On the basis that all solids such as granite flow to a small extent in response to small shear stress, some researchers have contended that substances known as amorphous solids, such as glass and many polymers, may be considered to have viscosity. This has led some to the view that solids are simply liquids with a very high viscosity, typically greater than 10¹² Pa·s. This position is often adopted by supporters of the widely held misconception that glass flow can be observed in old buildings. This distortion is more likely the result of the glass making process rather than the viscosity of glass.

However, others argue that solids are, in general, elastic for small stresses while fluids are not. Even if solids flow at higher stresses, they are characterized by their low-stress behavior. This distinction can become muddled if measurements are continued over long time periods, such as the Pitch drop experiment. Viscosity may be an appropriate characteristic for solids in a plastic regime. The situation becomes somewhat confused as the term viscosity is sometimes used for solid materials, for example Maxwell materials, to describe the relationship between stress and the rate of change of strain, rather than rate of shear.

These distinctions may be largely resolved by considering the constitutive equations of the material in question, which take into account both its viscous and elastic behaviors. Materials for which both their viscosity and their elasticity are important in a particular range of deformation and deformation rate are called viscoelastic. In geology, earth materials that exhibit viscous deformation at least three times greater than their elastic deformation are sometimes called rheids.

Viscosity of amorphous materials

Common glass viscosity curves.

Viscous flow in amorphous materials (e.g. in glasses and melts) is a thermally activated process:

$\mu =A\cdot e^{Q/RT},$

where Q is activation energy, T is temperature, R is the molar gas constant and A is approximately a constant.

The viscous flow in amorphous materials is characterized by a deviation from the Arrhenius-type behavior: Q changes from a high value Q_H at low temperatures (in the glassy state) to a low value Q_L at high temperatures (in the liquid state). Depending on this change, amorphous materials are classified as either

• strong when: Q_H − Q_L < Q_L or
• fragile when: Q_H − Q_L ≥ Q_L.

The fragility of amorphous materials is numerically characterized by the Doremus’ fragility ratio:

$R_{D}={\frac {Q_{H}}{Q_{L}}}$

and strong material have R_D < 2 whereas fragile materials have R_D ≥ 2.

The viscosity of amorphous materials is quite exactly described by a two-exponential equation:

$\mu =A_{1}\cdot T\cdot \left[1+A_{2}\cdot e^{B/RT}]\cdot [1+C\cdot e^{D/RT}\right],$

with constants A₁, A₂, B, C and D related to thermodynamic parameters of joining bonds of an amorphous material.

Not very far from the glass transition temperature, T_g, this equation can be approximated by a Vogel-Tammann-Fulcher (VTF) equation or a Kohlrausch-type stretched-exponential law.

If the temperature is significantly lower than the glass transition temperature, T < T_g, then the two-exponential equation simplifies to an Arrhenius type equation:

$\mu =A_{L}T\cdot e^{Q_{H}/RT}$

with:

$Q_{H}=H_{d}+H_{m},\,$

where H_d is the enthalpy of formation of broken bonds (termed configurons) and H_m is the enthalpy of their motion. When the temperature is less than the glass transition temperature, T < T_g, the activation energy of viscosity is high because the amorphous materials are in the glassy state and most of their joining bonds are intact.

If the temperature is highly above the glass transition temperature, T > T_g, the two-exponential equation also simplifies to an Arrhenius type equation:

$\mu =A_{H}T\cdot e^{Q_{L}/RT},$

with:

$Q_{L}=H_{m}.\,$

When the temperature is higher than the glass transition temperature, T > T_g, the activation energy of viscosity is low because amorphous materials are melt and have most of their joining bonds broken which facilitates flow.

Volume (bulk) viscosity

The negative-one-third of the trace of the stress tensor is often identified with the thermodynamic pressure,

$-{1 \over 3}T_{a}^{a}=p,$

which only depends upon the equilibrium state potentials like temperature and density (equation of state). In general, the trace of the stress tensor is the sum of thermodynamic pressure contribution plus another contribution which is proportional to the divergence of the velocity field. This constant of proportionality is called the volume viscosity.

Eddy viscosity

In the study of turbulence in fluids, a common practical strategy for calculation is to ignore the small-scale vortices (or eddies) in the motion and to calculate a large-scale motion with an eddy viscosity that characterizes the transport and dissipation of energy in the smaller-scale flow (see large eddy simulation). Values of eddy viscosity used in modeling ocean circulation may be from 5x10⁴ to 10⁶ Pa·s depending upon the resolution of the numerical grid.

Fluidity

The reciprocal of viscosity is fluidity, usually symbolized by φ = 1 / μ or F = 1 / μ, depending on the convention used, measured in reciprocal poise (cm·s·g⁻¹), sometimes called the rhe. Fluidity is seldom used in engineering practice.

The concept of fluidity can be used to determine the viscosity of an ideal solution. For two components $a$ and $b$, the fluidity when a and b are mixed is

$F\approx \chi _{a}F_{a}+\chi _{b}F_{b},$

which is only slightly simpler than the equivalent equation in terms of viscosity:

$\mu \approx {\frac {1}{\chi _{a}/\mu _{a}+\chi _{b}/\mu _{b}}},$

where χ_a and χ_b is the mole fraction of component a and b respectively, and μ_a and μ_b are the components pure viscosities.

The linear viscous stress tensor

Viscous forces in a fluid are a function of the rate at which the fluid velocity is changing over distance. The velocity at any point r is specified by the velocity field v(r). The velocity at a small distance dr from point r may be written as a Taylor series:

$\mathbf {v} (\mathbf {r} +d\mathbf {r} )=\mathbf {v} (\mathbf {r} )+{\frac {d\mathbf {v} }{d\mathbf {r} }}d\mathbf {r} +\ldots ,$

where dv / dr is shorthand for the dyadic product of the del operator and the velocity:

${\frac {d\mathbf {v} }{d\mathbf {r} }}={\begin{bmatrix}{\frac {\partial v_{x}}{\partial x}}&{\frac {\partial v_{x}}{\partial y}}&{\frac {\partial v_{x}}{\partial z}}\\{\frac {\partial v_{y}}{\partial x}}&{\frac {\partial v_{y}}{\partial y}}&{\frac {\partial v_{y}}{\partial z}}\\{\frac {\partial v_{z}}{\partial x}}&{\frac {\partial v_{z}}{\partial y}}&{\frac {\partial v_{z}}{\partial z}}\end{bmatrix}}.$

This is just the Jacobian of the velocity field.

Viscous forces are the result of relative motion between elements of the fluid, and so are expressible as a function of the velocity field. In other words, the forces at r are a function of v(r) and all derivatives of v(r) at that point. In the case of linear viscosity, the viscous force will be a function of the Jacobian tensor alone. For almost all practical situations, the linear approximation is sufficient.

If we represent x, y, and z by indices 1, 2, and 3 respectively, the i,j component of the Jacobian may be written as ∂_i v_j where ∂_i is shorthand for ∂/∂x_i. Note that when the first and higher derivative terms are zero, the velocity of all fluid elements is parallel, and there are no viscous forces.

Any matrix may be written as the sum of an antisymmetric matrix and a symmetric matrix, and this decomposition is independent of coordinate system, and so has physical significance. The velocity field may be approximated as:

$v_{j}(\mathbf {r} +d\mathbf {r} )=v_{j}(\mathbf {r} )+{\frac {1}{2}}\left(\partial _{i}v_{j}-\partial _{j}v_{i}\right)dr_{i}+{\frac {1}{2}}\left(\partial _{i}v_{j}+\partial _{j}v_{i}\right)dr_{i},$

where Einstein notation is now being used in which repeated indices in a product are implicitly summed. The second term from the right is the asymmetric part of the first derivative term, and it represents a rigid rotation of the fluid about r with angular velocity ω where:

$\omega ={\frac {1}{2}}\mathbf {\nabla } \times \mathbf {v} ={\frac {1}{2}}{\begin{bmatrix}\partial _{2}v_{3}-\partial _{3}v_{2}\\\partial _{3}v_{1}-\partial _{1}v_{3}\\\partial _{1}v_{2}-\partial _{2}v_{1}\end{bmatrix}}.$

For such a rigid rotation, there is no change in the relative positions of the fluid elements, and so there is no viscous force associated with this term. The remaining symmetric term is responsible for the viscous forces in the fluid. Assuming the fluid is isotropic (i.e. its properties are the same in all directions), then the most general way that the symmetric term (the rate-of-strain tensor) can be broken down in a coordinate-independent (and therefore physically real) way is as the sum of a constant tensor (the rate-of-expansion tensor) and a traceless symmetric tensor (the rate-of-shear tensor):

${\frac {1}{2}}\left(\partial _{i}v_{j}+\partial _{j}v_{i}\right)=\underbrace {{\frac {1}{3}}\partial _{k}v_{k}\delta _{ij}} _{\text{rate-of-expansion tensor}}+\underbrace {\left({\frac {1}{2}}\left(\partial _{i}v_{j}+\partial _{j}v_{i}\right)-{\frac {1}{3}}\partial _{k}v_{k}\delta _{ij}\right)} _{\text{rate-of-shear tensor}},$

where δ_ij is the unit tensor. The most general linear relationship between the stress tensor σ and the rate-of-strain tensor is then a linear combination of these two tensors:

$\sigma _{{\text{visc}};ij}=\zeta \partial _{k}v_{k}\delta _{ij}+\mu \left(\partial _{i}v_{j}+\partial _{j}v_{i}-{\frac {2}{3}}\partial _{k}v_{k}\delta _{ij}\right),$

where ς is the coefficient of bulk viscosity (or "second viscosity") and μ is the coefficient of (shear) viscosity.

The forces in the fluid are due to the velocities of the individual molecules. The velocity of a molecule may be thought of as the sum of the fluid velocity and the thermal velocity. The viscous stress tensor described above gives the force due to the fluid velocity only. The force on an area element in the fluid due to the thermal velocities of the molecules is just the hydrostatic pressure. This pressure term (−p δ_ij) must be added to the viscous stress tensor to obtain the total stress tensor for the fluid.

$\sigma _{ij}=-p\delta _{ij}+\sigma _{{\text{visc}};ij}.\,$

The infinitesimal force dF_i on an infinitesimal area dA_i is then given by the usual relationship:

$dF_{i}=\sigma _{ij}\,dA_{j}.\,$

See also

• Deborah number
• Dilatant
• Hyperviscosity syndrome
• Inviscid flow
• Physics of glass
• Reyn
• Reynold's number
• Rheology
• Thixotropy
• Viscometer
• Viscometry
• Viscoelasticity
• Viscosity index
• Joback method (Estimation of the liquid viscosity from molecular structure)

Additional reading

• Massey, B. S. (1983). Mechanics of Fluids (Fifth ed.). Van Nostrand Reinhold (UK). ISBN 0-442-30552-4.

External links

• Fluid Characteristics Chart A table of viscosities and vapor pressures for various fluids
• Gas Dynamics Toolbox Calculate coefficient of viscosity for mixtures of gases
• Glass Viscosity Measurement Viscosity measurement, viscosity units and fixpoints, glass viscosity calculation
• Kinematic Viscosity conversion between kinematic and dynamic viscosity.
• Physical Characteristics of Water A table of water viscosity as a function of temperature
• Project Trajectory Java Web Start Application for simulation of moving bodies through different and user definable media.
• Vogel–Tammann–Fulcher Equation Parameters
• Calculation of temperature-dependent dynamic viscosities for some common components