Borate bromide
The borate bromides are mixed anion compounds that contain borate and bromide anions. They are in the borate halide family of compounds which also includes borate fluorides, borate chlorides, and borate iodides.
List
[edit]| name | chem | mw | crystal system | space group | unit cell Å | volume | density | comment | references |
|---|---|---|---|---|---|---|---|---|---|
| Li3B8O13Br | 395.21 | orthorhombic | Pca21 | a 17.3967(5)Å b 9.4077(3)Å c 6.6750 | 1092.45 | 2.403 | birefringence 0.088@1064 nm | [1] | |
| Na3B4O7Br | hexagonal | P6522 | a = 8.146 c = 20.24 | 1163.1 | 2.605 | [2] | |||
| Na11B21O36Br2 | 1215.72 | monoclinic | C2/c | a=15.722 b=8.951 c=24.087 β=100.728 Z=4 | 3330.3 | 2.425 | [3] | ||
| KBOB | K3B6O10Br | 422.07 | trigonal | R3m | a=10.1153 c=8.8592 Z=3 | 785.02 | 2.678 | colourless | [4] |
| K9[B4O5(OH)4]3(CO3)Br·7H2O | 1191.75 | hexagonal | P6_2c | a=11243 c=17.132 Z=2 | 1875 | 2.11 | band gap 5.65 eV | [5] | |
| Zn2BO3Br·H2O | 287.48 | orthorhombic | P212121 | a=4.962 b=8.484 c=14.644 Z=4 | 616.5 | 3.097 | NLO 0.6x KDP | [6] | |
| KZn2BO3Br2 | 345.92 | trigonal | R32 | a=4.9611 c=27.221 Z=3 | 580.2 | 2.970 | white | [7] | |
| RbZn2BO3Br2 | 388.47 | trigonal | R32 | a=4.9618 c=28.199 Z=3 | 601.2 | 3.219 | white | [7] | |
| Ag4B4O7Br2 | 746.52 | hexagonal | P6122 | a=8.8291 c=44.7416 Z=12 | 3020.5 | 4.92 | [8] | ||
| Sn2B5O9Br | 515.34 | orthorhombic | Pnn2 | a = 11.398 b = 11.446 c = 6.553 Z=4 | 854.9 | 4.004 | birefringence=0.439 at 546 nm; SHG 4.8x; white | [9] | |
| NaBa4(GaB4O9)2Br3 | 1326.00 | tetragonal | P42nm | a=12.33 c=6.91 Z=2 | 1053 | 4.18 | NLO 1.1x KDP | [10] | |
| La[B5O8(OH)(H2O)2Br] | 448.87 | monoclinic | P21/n | a=6.520 b=15.213 c=10.704 β=90.017 Z=4 | 1061.6 | 2.808 | colourless | [11] | |
| LaBOBr | La[B7O10(OH)3(H2O)Br] | 518.49 | monoclinic | P21/n | a=7.944 b=15.105 c=9.836 β=90 Z=4 | 1180.3 | 2.918 | [12] | |
| Ce[B5O8(OH)(H2O)2Br] | 450.08 | monoclinic | P21/n | a=6.495 b=15.159 c=10.670 β=90.048 Z=4 | 1050.6 | 2.846 | colourless | [11] | |
| CeBOBr | Ce[B6O9(OH)2(H2O)2Br]·0.5H2O | 500.89 | monoclinic | P21/n | a=8.1507 b=14.874 c=9.867 β=90.085 Z=4 | 1196.3 | 2.781 | [12] | |
| PrBOBr | Pr[B6O9(OH)2(H2O)2Br]·0.5H2O | 501.68 | monoclinic | P21/n | a=8.1346 b=14.819 c=9.847 β=90.153 Z=4 | 1187.0 | 2.807 | green | [12] |
| Pr[B5O8(OH)(H2O)2Br] | 450.87 | monoclinic | P21/n | a=6.4910 b=15.143 c=10.664 β=90.0440 Z=4 | 1048.2 | 2.857 | [11] | ||
| NdBOBr | Nd2[B12O17.5(OH)5(H2O)4Br1.5]Br0.5·H2O | 1018.02 | orthorhombic | Fdd2 | a=30.6641 b=19.7946 c=16.0737 Z=16 | 9757.3 | 2.772 | purple | [12] |
| Nd4[B18O25(OH)13Br3] | 1619.27 | monoclinic | P2/c | a=10.544 b=6.451 c=23.485 β=97.754 Z=2 | 1583 | 3.397 | purple | [11] | |
| SmBOBr | Sm4[B18O25(OH)13Br3] | 1643.71 | monoclinic | P21/n | a=10.508 b=6.427 c=23.408 β=97.585 Z=2 | 1567 | 3.484 | [12] | |
| Ba2BO3Br | P-3m1 | a = 5.516, c = 11.019, and Z = 2 | [13] | ||||||
| Ba3BO3Br3 | triclinic | P-1 | a = 9.280, b = 9.349 c = 13.025, α = 92.71°, β = 98.29°, γ = 116.20° and Z = 4 | [13] | |||||
| Ba7(BO3)3SiO4Br | orthorhombic | P63mc | [14] | ||||||
| Ba7(BO3)3GeO4Br | 1354.31 | orthorhombic | Pbam | a=20.381 b=7.477 c=11.175 Z=4 | 1702.9 | 5.283 | [14] | ||
| Pb2Ba3(BO3)3Br | 1082.74 | orthorhombic | C2221 | a=10.538 b=14.2878 c=8.107 Z=4 | 1220.7 | 5.891 | NLO 3.1×KDP; colourless | [15] |
References
[edit]- ^ Hu, Mei; Tuerhong, Nuerbiye; Chen, Zhaohui; Jing, Qun; Lee, Ming-Hsien (2023-02-16). "Li 3 B 8 O 13 X (X = Cl and Br): Two New Noncentrosymmetric Crystals with Large Birefringence Induced by BO 3 Units". Inorganic Chemistry. 62 (8): 3609–3615. doi:10.1021/acs.inorgchem.2c04376. ISSN 0020-1669. PMID 36795025. S2CID 256899976.
- ^ Bai, Chunyan; Han, Shujuan; Pan, Shilie; Zhang, Bingbing; Yang, Yun; Li, Lin; Yang, Zhihua (2015). "Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra". RSC Advances. 5 (16): 12416–12422. Bibcode:2015RSCAd...512416B. doi:10.1039/C4RA16639F. ISSN 2046-2069.
- ^ Dong, Xiaoyu; Wu, Hongping; Shi, Yunjing; Yu, Hongwei; Yang, Zhihua; Zhang, Bingbing; Chen, Zhaohui; Yang, Yun; Huang, Zhenjun; Pan, Shilie; Zhou, Zhongxiang (2013-06-03). "Na 11 B 21 O 36 X 2 (X=Cl, Br): Halogen Sodium Borates with a New Graphene-Like Borate Double Layer". Chemistry - A European Journal. 19 (23): 7338–7341. doi:10.1002/chem.201300902. PMID 23630069.
- ^ Zhang, Min; Su, Xin; Pan, Shilie; Wang, Zheng; Zhang, Hui; Yang, Zhihua; Zhang, Bingbing; Dong, Lingyun; Wang, Ying; Zhang, Fangfang; Yang, Yun (2014-06-05). "Linear and Nonlinear Optical Properties of K 3 B 6 O 10 Br Single Crystal: Experiment and Calculation". The Journal of Physical Chemistry C. 118 (22): 11849–11856. doi:10.1021/jp500858q. ISSN 1932-7447.
- ^ Zhang, Xueyan; Wu, Hongping; Cheng, Shichao; Han, Guopeng; Yang, Zhihua; Pan, Shilie (2019-05-20). "K 9 [B 4 O 5 (OH) 4 ] 3 (CO 3 )X·7H 2 O (X = Cl, Br): Syntheses, Characterizations, and Theoretical Studies of Noncentrosymmetric Halogen Borate–Carbonates with Short UV Cutoff Edges". Inorganic Chemistry. 58 (10): 6974–6982. doi:10.1021/acs.inorgchem.9b00593. ISSN 0020-1669. PMID 31042371. S2CID 143422681.
- ^ Song, Yunxia; Yang, Guangsai; Gong, Pifu; Luo, Min; Lin, Zheshuai; Ye, Ning (2020-06-01). "Hydrogen-Bond-Assisted Reinforcement of Interlayer Connections in Zn 2 BO 3 X·H 2 O (X = Cl, Br): Two UV Nonlinear Optical Crystals with KBBF-Type Structure". Inorganic Chemistry. 59 (11): 7789–7794. doi:10.1021/acs.inorgchem.0c00874. ISSN 0020-1669. PMID 32401026. S2CID 218618490.
- ^ a b Yang, Guangsai; Gong, Pifu; Lin, Zheshuai; Ye, Ning (2016-12-27). "AZn 2 BO 3 X 2 (A = K, Rb, NH 4 ; X = Cl, Br): New Members of KBBF Family Exhibiting Large SHG Response and the Enhancement of Layer Interaction by Modified Structures". Chemistry of Materials. 28 (24): 9122–9131. doi:10.1021/acs.chemmater.6b04272. ISSN 0897-4756.
- ^ Volkov, Sergey N.; Charkin, Dmitri O.; Arsent’ev, Maxim Yu.; Povolotskiy, Alexey V.; Stefanovich, Sergey Yu.; Ugolkov, Valery L.; Krzhizhanovskaya, Maria G.; Shilovskikh, Vladimir V.; Bubnova, Rimma S. (2020-03-02). "Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag 4 B 4 O 7 X 2 (X = Br, I) Borate Halides". Inorganic Chemistry. 59 (5): 2655–2658. doi:10.1021/acs.inorgchem.0c00306. ISSN 0020-1669. PMID 32049501. S2CID 211101969.
- ^ Guo, Jingyu; Cheng, Shichao; Han, Shujuan; Yang, Zhihua; Pan, Shilie (March 2021). "Sn 2 B 5 O 9 Br as an Outstanding Bifunctional Material with Strong Second-Harmonic Generation Effect and Large Birefringence". Advanced Optical Materials. 9 (5): 2001734. doi:10.1002/adom.202001734. ISSN 2195-1071. S2CID 230528677.
- ^ Wen, Ming; Su, Xin; Wu, Hongping; Lu, Juanjuan; Yang, Zhihua; Pan, Shilie (2016-03-24). "NaBa 4 (GaB 4 O 9 ) 2 X 3 (X = Cl, Br) with NLO-Active GaO 4 Tetrahedral Unit: Experimental and ab Initio Studies". The Journal of Physical Chemistry C. 120 (11): 6190–6197. doi:10.1021/acs.jpcc.6b00265. ISSN 1932-7447.
- ^ a b c d Polinski, Matthew J.; Wang, Shuao; Cross, Justin N.; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2012-07-16). "Effects of Large Halides on the Structures of Lanthanide(III) and Plutonium(III) Borates". Inorganic Chemistry. 51 (14): 7859–7866. doi:10.1021/ic3009317. ISSN 0020-1669. PMID 22734798.
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- ^ a b Zhao, Jing; Li, R.K. (October 2013). "Two new barium borate bromides: Ba2BO3Br and Ba3BO3Br3". Solid State Sciences. 24: 54–57. Bibcode:2013SSSci..24...54Z. doi:10.1016/j.solidstatesciences.2013.07.009.
- ^ a b Wen, Ming; Lian, Zhipeng; Wu, Hongping; Su, Xin; Yan, Qingfeng; Lu, Juanjuan; Yang, Zhihua; Pan, Shilie (2015). "Ba 7 (BO 3 ) 3 GeO 4 X (X = Cl, Br): borogermanate halides with rigid GeO 4 tetrahedra and flexible XBa 6 octahedra". RSC Advances. 5 (66): 53448–53454. Bibcode:2015RSCAd...553448W. doi:10.1039/C5RA07450A. ISSN 2046-2069.
- ^ Jing, Qun; Dong, Xiaoyu; Yang, Zhihua; Pan, Shilie (2015). "Synthesis and optical properties of the first lead borate bromide with isolated BO 3 groups: Pb 2 Ba 3 (BO 3 ) 3 Br". Dalton Transactions. 44 (38): 16818–16823. doi:10.1039/C5DT02652K. ISSN 1477-9226. PMID 26347088.