Bismuth tribromide

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Bismuth tribromide
Bismuth bromide
Names
IUPAC name
bismuth bromide
Other names
bismuth tribromide
tribromobismuth
tribromobismuthine
tribromobismuthane
bismuth(III) bromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.201 Edit this at Wikidata
EC Number
  • 232-121-1
  • InChI=1/Bi.3BrH/h;3*1H/q+3;;;/p-3
    Key: TXKAQZRUJUNDHI-DFZHHIFOAX
  • Br[Bi](Br)Br
Properties
BiBr3
Molar mass 448.692 g·mol−1
Appearance white to light yellow crystals
Density 5.7 g/cm3 at 25 °C
Melting point 219 °C (426 °F; 492 K)
Boiling point 462 °C (864 °F; 735 K)
-147.0·10−6 cm3/mol
Explosive data
Shock sensitivity N.A.
Friction sensitivity N.A.
Detonation velocity N.A.
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
corrosive[1]
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
3
0
1
Related compounds
Other anions
bismuth trifluoride
bismuth trichloride
bismuth triiodide
Other cations
nitrogen tribromide
phosphorus tribromide
arsenic tribromide
antimony tribromide
aluminium tribromide
iron(III) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Bismuth tribromide is an inorganic chemical compound of bismuth and bromine with the chemical formula BiBr3. It may be formed by the reaction of bismuth oxide and hydrobromic acid with the equation

Bi2O3 + 6 HBr ⇌ 2 BiBr3 + 3 H2O

Bismuth tribromide can also be produced by the direct oxidation of bismuth in bromine.

Bismuth Bromide (Bismuth Tribromide) is a highly water soluble crystalline Bismuth source for uses compatible with Bromides and lower (acidic) pH. Most metal bromide compounds are water soluble for uses in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications. Bismuth Bromide is generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards.

References

  1. ^ "Sigma-Aldrich: 654981 Bismuth(III) bromide anhydrous, powder, 99.999% trace metals basis". Archived from the original on 2012-02-11. {{cite web}}: Unknown parameter |deadurl= ignored (|url-status= suggested) (help)