Jump to content

Metam sodium

From Wikipedia, the free encyclopedia

This is an old revision of this page, as edited by DePiep (talk | contribs) at 17:41, 7 July 2015 (Chembox: rm/replace deprecated params. Fix unknown parameters (via AWB script)). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

Metam sodium[1]
Ball-and-stick model of the component ions of metham sodium
Names
IUPAC name
Sodium methylaminomethanedithioate
Other names
Metham sodium
Carbathion
Carbathione
Carbothion
Metamsodium
Metam-sodium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.004.812 Edit this at Wikidata
  • InChI=1S/C2H5NS2.Na/c1-3-2(4)5;/h1H3,(H2,3,4,5);/q;+1/p-1 checkY
    Key: AFCCDDWKHLHPDF-UHFFFAOYSA-M checkY
  • InChI=1/C2H5NS2.Na/c1-3-2(4)5;/h1H3,(H2,3,4,5);/q;+1/p-1
    Key: AFCCDDWKHLHPDF-REWHXWOFAS
  • [Na+].[S-]C(=S)NC
Properties
C2H4NNaS2
Molar mass 129.18 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Metam sodium is an organosulfur compound (formally a dithiocarbamate), which is used as a soil fumigant, pesticide, herbicide, and fungicide. It is one of the most widely used pesticides in the United States, with approximately 60 million pounds used in 2001.[2] Metam sodium is the sodium salt of methyl dithiocarbamate.

Metam sodium can be prepared from methylamine, carbon disulfide, and sodium hydroxide; or from methyl isothiocyanate and sodium thiolate.[1]

Upon exposure to the environment, metam sodium decomposes to form methyl isothiocyanate.[3]

See also

References

  1. ^ a b Merck Index, 11th Edition, 5860.
  2. ^ 2000-2001 Pesticide Market Estimates, U.S. Environmental Protection Agency
  3. ^ Review of Metam Sodium, Dazomet, Methylisothiocyanate (MITC), Australian Pesticides and Veterinary Medicines Authority, June 1997