Environmental remediation

Environmental remediation deals with the removal of pollution or contaminants from environmental media such as soil, groundwater, sediment, or surface water. This would mean that once requested by the government or a land remediation authority, immediate action should be taken as this can impact negatively on human health and the environment.

Remedial action is generally subject to an array of regulatory requirements, and also can be based on assessments of human health and ecological risks where no legislated standards exist or where standards are advisory.

Remediation standards

In the United States, the most comprehensive set of Preliminary Remediation Goals (PRGs) is from the Environmental Protection Agency (EPA) Region 9. A set of standards used in Europe exists and is often called the Dutch standards. The European Union (EU) is rapidly moving towards Europe-wide standards, although most of the industrialised nations in Europe have their own standards at present. In Canada, most standards for remediation are set by the provinces individually, but the Canadian Council of Ministers of the Environment provides guidance at a federal level in the form of the Canadian Environmental Quality Guidelines and the Canada-Wide Standards|Canada-Wide Standard for Petroleum Hydrocarbons in Soil.

Site assessment

Once a site is suspected of being contaminated there is a need to assess the contamination. Often the assessment begins with preparation of a Phase I Environmental Site Assessment. The historical use of the site and the materials used and produced on site will guide the assessment strategy and type of sampling and chemical analysis to be done. Often nearby sites owned by the same company or which are nearby and have been reclaimed, levelled or filled are also contaminated even where the current land use seems innocuous. For example, a car park may have been levelled by using contaminated waste in the fill. Also important is to consider off site contamination of nearby sites often through decades of emissions to soil, groundwater, and air. Ceiling dust, topsoil, surface and groundwater of nearby properties should also be tested, both before and after any remediation. This is a controversial step as:

1. No one wants to have to pay for the cleanup of the site;
2. If nearby properties are found to be contaminated it may have to be noted on their property title, potentially affecting the value;
3. No one wants to pay for the cost of assessment.

Often corporations which do voluntary testing of their sites are protected from the reports to environmental agencies becoming public under Freedom of Information Acts, however a "Freedom of Information" inquiry will often produce other documents that are not protected or will produce references to the reports.

Funding remediation

In the US there has been a mechanism for taxing polluting industries to form a Superfund to remediate abandoned sites, or to litigate to force corporations to remediate their contaminated sites. Other countries have other mechanisms and commonly sites are rezoned to "higher" uses such as high density housing, to give the land a higher value so that after deducting cleanup costs there is still an incentive for a developer to purchase the land, clean it up, redevelop it and sell it on, often as apartments (home units).

Mapping remediation

There are several tools for mapping these sites and which allow the user to view additional information. One such tool is TOXMAP, a Geographic Information System (GIS) from the Division of Specialized Information Services [1] of the United States National Library of Medicine (NLM) that uses maps of the United States to help users visually explore data from the United States Environmental Protection Agency's (EPA) Superfund and Toxics Release Inventory programs.

Technologies

Remediation technologies are many and varied but can generally be categorized into ex-situ and in-situ methods. Ex-situ methods involve excavation of affected soils and subsequent treatment at the surface as well as extraction of contaminated groundwater and treatment at the surface. In-situ methods seek to treat the contamination without removing the soils or groundwater. Various technologies have been developed for remediation of oil-contaminated soil/sediments.

Traditional remediation approaches consist of soil excavation and disposal to landfill and groundwater "pump and treat". In-situ technologies include but are not limited to: solidification and stabilization, soil vapor extraction, permeable reactive barriers, monitored natural attenuation, bioremediation-phytoremediation, chemical oxidation, steam-enhanced extraction and in situ thermal desorption and have been used extensively in the USA.

Thermal desorption

Thermal desorption is a technology for soil remediation. During the process a desorber volatilizes the contaminants (e.g. oil, mercury or hydrocarbon) to separate them from especially soil or sludge. After that the contaminants can either be collected or destroyed in an offgas treatment system.

Excavation or dredging

Excavation processes can be as simple as hauling the contaminated soil to a regulated landfill, but can also involve aerating the excavated material in the case of volatile organic compounds (VOCs). Recent advancements in bioaugmentation and biostimulation of the excavated material have also proven to be able to remediate semi-volatile organic compounds (SVOCs) onsite. If the contamination affects a river or bay bottom, then dredging of bay mud or other silty clays containing contaminants may be conducted. Recently, ExSitu Chemical oxidation has also been utilized in the remediation of contaminated soil. This process involves the excavation of the contaminated area into large bermed areas where they are treated using chemical oxidation methods.

Surfactant enhanced aquifer remediation (SEAR)

Also known as solubilization and recovery, the surfactant enhanced aquifer remediation process involves the injection of hydrocarbon mitigation agents or specialty surfactants into the subsurface to enhance desorption and recovery of bound up otherwise recalcitrant non aqueous phase liquid (NAPL).

In geologic formations that allow delivery of hydrocarbon mitigation agents or specialty surfactants, this approach provides a cost effective and permanent solution to sites that have been previously unsuccessful utilizing other remedial approaches. This technology is also successful when utilized as the initial step in a multi faceted remedial approach utilizing SEAR then In situ Oxidation, bioremediation enhancement or soil vapor extraction (SVE).

Pump and treat

Pump and treat involves pumping out contaminated groundwater with the use of a submersible or vacuum pump, and allowing the extracted groundwater to be purified by slowly proceeding through a series of vessels that contain materials designed to adsorb the contaminants from the groundwater. For petroleum-contaminated sites this material is usually activated carbon in granular form. Chemical reagents such as flocculants followed by sand filters may also be used to decrease the contamination of groundwater. Air stripping is a method that can be effective for volatile pollutants such as BTEX compounds found in gasoline.

For most biodegradable materials like BTEX, MTBE and most hydrocarbons, bioreactors can be used to clean the contaminated water to non-detectable levels. With fluidized bed bioreactors it is possible to achieve very low discharge concentrations which will meet or exceed discharge requirements for most pollutants.

Depending on geology and soil type, pump and treat may be a good method to quickly reduce high concentrations of pollutants. It is more difficult to reach sufficiently low concentrations to satisfy remediation standards, due to the equilibrium of absorption/desorption processes in the soil. However, pump and treat is typically not the best form of remediation. It is expensive to treat the groundwater, and typically is a very slow process to clean up a release with pump and treat. It is best suited to control the hydraulic gradient and keep a release from spreading further. Better options of in-situ treatment often include air sparge/soil vapor extraction (AS/SVE) or dual phase extraction/multiphase extraction(DPE/MPE). Other methods include trying to increase the dissolved oxygen content of the groundwater to support microbial degradation of the compound (especially petroleum) by direct injection of oxygen into the subsurface, or the direct injection of a slurry that slowly releases oxygen over time (typically magnesium peroxide or calium oxy-hydroxide).

Solidification and stabilization

Solidification and stabilization work has a reasonably good track record but also a set of serious deficiencies related to durability of solutions and potential long-term effects. In addition CO₂ emissions due to the use of cement are also becoming a major obstacle to its widespread use in solidification/stabilization projects.

Stabilization/solidification (S/S) is a remediation and treatment technology that relies on the reaction between a binder and soil to stop/prevent or reduce the mobility of contaminants.

• Stabilization involves the addition of reagents to a contaminated material (e.g. soil or sludge) to produce more chemically stable constituents; and
• Solidification involves the addition of reagents to a contaminated material to impart physical/dimensional stability to contain contaminants in a solid product and reduce access by external agents (e.g. air, rainfall).

Conventional S/S is an established remediation technology for contaminated soils and treatment technology for hazardous wastes in many countries in the world. However, the uptake of S/S technologies has been relatively modest, and a number of barriers have been identified including:

• the relatively low cost and widespread use of disposal to landfill;
• the lack of authoritative technical guidance on S/S;
• uncertainty over the durability and rate of contaminant release from S/S-treated material;
• experiences of past poor practice in the application of cement stabilization processes used in waste disposal in the 1980s and 1990s (ENDS, 1992); and
• residual liability associated with immobilized contaminants remaining on-site, rather than their removal or destruction.

In situ oxidation

New in situ oxidation technologies have become popular, for remediation of a wide range of soil and groundwater contaminants. Remediation by chemical oxidation involves the injection of strong oxidants such as hydrogen peroxide, ozone gas, potassium permanganate or persulfates.

Oxygen gas or ambient air can also be injected to promote growth of aerobic bacteria which accelerate natural attenuation of organic contaminants. One disadvantage of this approach is the possibility of decreasing anaerobic contaminant destruction natural attenuation where existing conditions enhance anaerobic bacteria which normally live in the soil prefer a reducing environment. In general though, aerobic activity is much faster than anaerobic and overall destruction rates are typically greater when aerobic activity can be successfully promoted.

The injection of gases into the groundwater may also cause contamination to spread faster than normal depending on the site's hydrogeology. In these cases, injections downgradient of groundwater flow may provide adequate microbial destruction of contaminants prior to exposure to surface waters or drinking water supply wells.

Migration of metal contaminants must also be considered whenever modifying subsurface oxidation-reduction potential. Certain metals are more soluble in oxidizing environments while others are more mobile in reducing environments.

Soil vapor extraction

Soil vapor extraction (SVE) is an effective remediation technology for soil. "Multi Phase Extraction" (MPE) is also an effective remediation technology when soil and groundwater are to be remediated coincidentally. SVE and MPE utilize different technologies to treat the off-gas volatile organic compounds (VOCs) generated after vacuum removal of air and vapors (and VOCs) from the subsurface and include granular activated carbon (most commonly used historically), thermal and/or catalytic oxidation and vapor condensation. Generally, carbon is used for low (below 500 ppmV) VOC concentration vapor streams, oxidation is used for moderate (up to 4,000 ppmV) VOC concentration streams, and vapor condensation is used for high (over 4,000 ppmV) VOC concentration vapor streams. Below is a brief summary of each technology.

1. Granular activated carbon (GAC) is used as a filter for air or water. Commonly used to filter tap water in household sinks. GAC is a highly porous adsorbent material, produced by heating organic matter, such as coal, wood and coconut shell, in the absence of air, which is then crushed into granules. Activated carbon is positively charged and therefore able to remove negative ions from the water such as organic ions, ozone, chlorine, fluorides and dissolved organic solutes by adsorption onto the activated carbon. The activated carbon must be replaced periodically as it may become saturated and unable to adsorb (i.e. reduced absorption efficiency with loading). Activated carbon is not effective in removing heavy metals.
2. Thermal oxidation (or incineration) can also be an effective remediation technology. This approach is somewhat controversial because of the risks of dioxins released in the atmosphere through the exhaust gases or effluent off-gas. Controlled, high temperature incineration with filtering of exhaust gases however should not pose any risks. Two different technologies can be employed to oxidize the contaminants of an extracted vapor stream. The selection of either thermal or catalytic depends on the type and concentration in parts per million by volume of constituent in the vapor stream. Thermal oxidation is more useful for higher concentration (~4,000 ppmV) influent vapor streams (which require less natural gas usage) than catalytic oxidation at ~2,000 ppmV.

• Thermal oxidation which uses a system that acts as a furnace and maintains temperatures ranging from 1,350 to 1,500 °F (730 to 820 °C).
• Catalytic oxidation which uses a catalyst on a support to facilitate a lower temperature oxidation. This system usually maintains temperatures ranging from 600 to 800 °F (316 to 427 °C).

1. Vapor condensation is the most effective off-gas treatment technology for high (over 4,000 ppmV) VOC concentration vapor streams. The process involves cryogenically cooling the vapor stream to below 40 degrees C such that the VOCs condensate out of the vapor stream and into liquid form where it is collected in steel containers. The liquid form of the VOCs is referred to as dense non-aqueous phase liquids (DNAPL) when the source of the liquid consists predominantly of solvents or light non-aqueous phase liquids (LNAPL) when the source of the liquid consists predominantly of petroleum or fuel products. This recovered chemical can then be reused or recycled in a more environmentally sustainable or green manner than the alternatives described above. This technology is also known as cryogenic cooling and compression (C3-Technology).

Nanoremediation

Using nano-sized reactive agents to degrade or immobilize contaminants is termed nanoremediation. In soil or groundwater nanoremediation, nanoparticles are brought into contact with the contaminant through either in situ injection or a pump-and-treat process. The nanomaterials then degrade organic contaminants through redox reactions or adsorb to and immobilize metals such as lead or arsenic. In commercial settings, this technology has been dominantly applied to groundwater remediation, with research into wastewater treatment. Research is also investigating how nanoparticles may be applied to cleanup of soil and gases.

Nanomaterials are highly reactive because of their high surface area per unit mass, and due to this reactivity nanomaterials may react with target contaminants at a faster rate than would larger particles. Most field applications of nanoremediation have used nano zero-valent iron (nZVI), which may be emulsified or mixed with another metal to enhance dispersion.

That nanoparticles are highly reactive can mean that they rapidly clump together or react with soil particles or other material in the environment, limiting their dispersal to target contaminants. Some of the important challenges currently limiting nanoremediation technologies include identifying coatings or other formulations that increase dispersal of the nanoparticle agents to better reach target contaminants while limiting any potential toxicity to bioremediation agents, wildlife, or people.

Bioremediation

The treatment of environmental problems through biological means is known as bioremediation and the specific use of plants for example by using phytoremediation. Bioremediation is sometimes used in conjunction with a pump and treat system. In bioremediation, either naturally occurring or specially bred bacteria are used to consume contaminants from extracted groundwater. This is sometimes referred to as a bio-gac system. Many times the groundwater is recycled to allow for continuously flowing water and enhanced bacteria population growth. Occasionally the bacteria can build up to such a point that they can affect filtration and pumping. The vessel should then be partially drained. Care must be taken to ensure that a sharp change in the groundwater chemistry does not kill the bacteria (such as a sudden change in pH).

Dual-phase extraction utilizes a soil vapor extraction system that produces a high vacuum resulting in the extraction of both contaminated vapors as well as a limited amount of contaminated groundwater. This method is somewhat inefficient due to large amount of energy required by pulling water by vacuum compared to pushing water with a submersible pump.

Mycoremediation is a form of bioremediation, the process of using fungi to return an environment (usually soil) contaminated by pollutants to a less contaminated state.

In an experiment conducted in conjunction with Batelle, a major contributor in the bioremediation industry, a plot of soil contaminated with diesel oil was inoculated with mycelia of oyster mushrooms; traditional bioremediation techniques (bacteria) were used on control plots. After four weeks, more than 95% of many of the PAH (polycyclic aromatic hydrocarbons) had been reduced to non-toxic components in the mycelial-inoculated plots. It appears that the natural microbial community participates with the fungi to break down contaminants into carbon dioxide and water. Wood-degrading fungi are particularly effective in breaking down aromatic pollutants (toxic components of petroleum), as well as chlorinated compounds (certain persistent pesticides; Battelle, 2000). Hair mats inoculated with oyster mushrooms were successfully employed in the clean-up of the San Francisco Bay area oil spill in 2007.

The key to mycoremediation is determining the right fungal species to target a specific pollutant. Certain strains have also been reported to successfully degrade the nerve gases VX and sarin.

Mycofiltration is a very similar process, using mycelial mats to filter toxic waste and microorganisms from polluted water.

Cleaning with collapsing air microbubbles

Cleaning of oil contaminated sediments with self collapsing air microbubbles have been recently explored as a chemical free technology. Air microbubbles generated in water without adding any surfactant could be used to clean oil contaminated sediments. This technology holds promise over the use of chemicals (mainly surfactant) for traditional washing of oil contaminated sediments.

Community consultation and information

In preparation for any significant remediation there should be extensive community consultation. The proponent should both present information to and seek information from the community. The proponent needs to learn about "sensitive" (future) uses like childcare, schools, hospitals, and playgrounds as well as community concerns and interests information. Consultation should be open, on a group basis so that each member of the community is informed about issues they may not have individually thought about. An independent chairperson acceptable to both the proponent and the community should be engaged (at proponent expense if a fee is required). Minutes of meetings including questions asked and the answers to them and copies of presentations by the proponent should be available both on the internet and at a local library (even a school library) or community centre.

Incremental health risk

Incremental health risk is the increased risk that a receptor (normally a human being living nearby) will face from (the lack of) a remediation project. The use of incremental health risk is based on carcinogenic and other (e.g., mutagenic, teratogenic) effects and often involves value judgements about the acceptable projected rate of increase in cancer. In some jurisdictions this is 1 in 1,000,000 but in other jurisdictions the acceptable projected rate of increase is 1 in 100,000. A relatively small incremental health risk from a single project is not of much comfort if the area already has a relatively high health risk from other operations like incinerators or other emissions, or if other projects exist at the same time causing a greater cumulative risk or an unacceptably high total risk. An analogy often used by remediators is to compare the risk of the remediation on nearby residents to the risks of death through car accidents or tobacco smoking.

Emissions standards

Standards are set for the levels of dust, noise, odour, emissions to air and groundwater, and discharge to sewers or waterways of all chemicals of concern or chemicals likely to be produced during the remediation by processing of the contaminants. These are compared against both natural background levels in the area and standards for areas zoned as nearby areas are zoned and against standards used in other recent remediations. Just because the emission is emanating from an area zoned industrial does not mean that in a nearby residential area there should be permitted any exceedances of the appropriate residential standards.

Monitoring for compliance against each standards is critical to ensure that exceedances are detected and reported both to authorities and the local community.

Enforcement is necessary to ensure that continued or significant breaches result in fines or even a jail sentence for the polluter.

Penalties must be significant as otherwise fines are treated as a normal expense of doing business. Compliance must be cheaper than to have continuous breaches.

Transport and emergency safety assessment

Assessment should be made of the risks of operations, transporting contaminated material, disposal of waste which may be contaminated including workers' clothes, and a formal emergency response plan should be developed. Every worker and visitor entering the site should have a safety induction personalised to their involvement with the site.

Impacts of funding remediation

The rezoning is often resisted by local communities and local government because of the adverse effects on the local amenity of the remediation and the new development. The main impacts during remediation are noise, dust, odour and incremental health risk. Then there is the noise, dust and traffic of developments. Then there is the impact on local traffic, schools, playing fields, and other public facilities of the often vastly increased local population.

Examples of major remediation projects

Homebush Bay, New South Wales, Australia

Homebush Bay, New South Wales, Australia has been the subject of a controversial remediation project.[2]

In this case the proposed rezoning, remediation and redevelopment has a wealth of material available through the internet from http://rhodesnsw.org:

1. Numerous investigations and reports by Australian and International consultants
2. For the former Union Carbide site, a previous remediation by excavation and containment in a clay capped sarcophagus, separated from the Bay by a bentonite wall.
3. A Parliamentary Inquiry by the Upper House of the Parliament of New South Wales, a state of Australia;
4. Two Commissions of Inquiry, one for each of the major dioxin contaminated sites, both contaminated by the operations of Union Carbide;
5. Resolutions by the relevant local government bodies (originally Concord council and after the Municipality of Concord was merged with Drummoyne Council to form the City of Canada Bay, by that Council);
6. Campaigns by local residents' groups, Greenpeace Australia, Nature Conservation Council of NSW, and Inner West (of Sydney branch of the) Greens
7. published submissions by Planning NSW and Environmental Protection Agency of NSW;
8. Comprehensive Environmental Impact studies published in digital format and available on CD from Planning NSW.

This rezoning, remediation and redevelopment of land contaminated by Union Carbide, ICI and others also involves the remediation of a strip of dioxin contaminated sediments in Homebush Bay, New South Wales. The Homebush Bay area was home to the main events of the Sydney 2000 Summer Olympics. The soil contamination was addressed in the Commission of Inquiry into the Lednez site formerly owned by Union Carbide, but not to the satisfaction of local community activists.

The remediation of Homebush Bay is important because of its impact on the food chain which extends through benthos not only to local protected and threatened species of birds, but also to JAMBA and CAMBA protected species and species which use other Ramsar-protected wetlands. Ultimately human health is affected through the food chain. Homebush Bay has a complete fishing ban, there is a commercial fin fishing ban west of the Gladesville Bridge, and based on submissions of the remediator and NSW Waterways and EPA the complete fishing ban ought be extended to the whole of the Parramatta River west of Homebush Bay and at least as far east as the Ryde Traffic Bridge.

Bakar Ex Cokeing Plant Site, Croatia

An E.U. contract for immobilization a polluted area of 20.000 m3 in BAKAR Croatia based on Solidification/Stabilization with ImmoCem is currently in progress. After 3 years of intensive research by the Croatian government the E.U. funded the immobilization project in BAKAR. The area is contaminated with large amounts of TPH, PAH and metals. For the immobilization the contractor chose to use the mix-in-plant procedure.

See also

General links

• Biodegradation
• In-situ capping of subaqueous waste
• In Situ Oxidation
• In-situ thermal desorption
• Electrokinetic remediation
• Electrical resistance heating
• Environmental degradation
• Environmental restoration
• Groundwater remediation
• Natural attenuation
• Mold Remediation
• Phase I Environmental Site Assessment
• Phytoremediation
• Restoration ecology
• Soil contamination
• Soil Vapor Extraction
• Solidification / Stabilization (S/S) with Cement

Legislation about remediation

• Superfund (United States)
• Contaminated Land Management Act (New South Wales, Australia)
• Contaminated Sites Act 2003 (Western Australia, Australia)
• 'Wet Bodembescherming' (Soil Protection Act, Netherlands)
• 'Wet Verontreiniging Oppervlaktewater' (Surfacewater Pollution Act, Netherlands)
• 'Environmental Management Act' (Canada)

Environmental groups with information

• CHEJ (US - Grew out of Love Canal controversy)
• Greenpeace (International organisation with National sites)

Environmental protection agencies

• United States Environmental Protection Agency
• NSW EPA (NSW, Australia)
• Environment Canada
• Canadian EPA Summary Table

External links

• U.S. EPA's Contaminated Site Clean-Up Information (CLU-IN)