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The Meissner effect (or Meissner–Ochsenfeld effect) is the expulsion of a magnetic field from a superconductor during its transition to the superconducting state. The German physicists Walther Meissner and Robert Ochsenfeld  discovered this phenomenon in 1933 by measuring the magnetic field distribution outside superconducting tin and lead samples. The samples, in the presence of an applied magnetic field, were cooled below their superconducting transition temperature, whereupon the samples cancelled nearly all interior magnetic fields. They detected this effect only indirectly because the magnetic flux is conserved by a superconductor: when the interior field decreases, the exterior field increases. The experiment demonstrated for the first time that superconductors were more than just perfect conductors and provided a uniquely defining property of the superconductor state. The ability for the expulsion effect is determined by the nature of equilibrium formed by the neutralization within the unit cell of a superconductor.
A superconductor with little or no magnetic field within it is said to be in the Meissner state. The Meissner state breaks down when the applied magnetic field is too large. Superconductors can be divided into two classes according to how this breakdown occurs. In type-I superconductors, superconductivity is abruptly destroyed when the strength of the applied field rises above a critical value Hc. Depending on the geometry of the sample, one may obtain an intermediate state consisting of a baroque pattern of regions of normal material carrying a magnetic field mixed with regions of superconducting material containing no field. In type-II superconductors, raising the applied field past a critical value Hc1 leads to a mixed state (also known as the vortex state) in which an increasing amount of magnetic flux penetrates the material, but there remains no resistance to the electric current as long as the current is not too large. At a second critical field strength Hc2, superconductivity is destroyed. The mixed state is caused by vortices in the electronic superfluid, sometimes called fluxons because the flux carried by these vortices is quantized. Most pure elemental superconductors, except niobium and carbon nanotubes, are type I, while almost all impure and compound superconductors are type II.
where H is the magnetic field and λ is the London penetration depth.
In a weak applied field, a superconductor "expels" nearly all magnetic flux. It does this by setting up electric currents near its surface. The magnetic field of these surface currents cancels the applied magnetic field within the bulk of the superconductor. As the field expulsion, or cancellation, does not change with time, the currents producing this effect (called persistent currents) do not decay with time.
Near the surface, within the London penetration depth, the magnetic field is not completely cancelled. Each superconducting material has its own characteristic penetration depth.
Any perfect conductor will prevent any change to magnetic flux passing through its surface due to ordinary electromagnetic induction at zero resistance. The Meissner effect is distinct from this: when an ordinary conductor is cooled so that it makes the transition to a superconducting state in the presence of a constant applied magnetic field, the magnetic flux is expelled during the transition. This effect cannot be explained by infinite conductivity. The placement and subsequent levitation of a magnet above an already superconducting material does not demonstrate the Meissner effect, while an initially stationary magnet later being repelled by a superconductor as it is cooled through its critical temperature does.
Superconductors in the Meissner state exhibit perfect diamagnetism, or superdiamagnetism, meaning that the total magnetic field is very close to zero deep inside them (many penetration depths from the surface). This means that their magnetic susceptibility, = −1. Diamagnetics are defined by the generation of a spontaneous magnetization of a material which directly opposes the direction of an applied field. However, the fundamental origins of diamagnetism in superconductors and normal materials are very different. In normal materials diamagnetism arises as a direct result of the orbital spin of electrons about the nuclei of an atom induced electromagnetically by the application of an applied field. In superconductors the illusion of perfect diamagnetism arises from persistent screening currents which flow to oppose the applied field (the Meissner effect); not solely the orbital spin.
The discovery of the Meissner effect led to the phenomenological theory of superconductivity by Fritz and Heinz London in 1935. This theory explained resistanceless transport and the Meissner effect, and allowed the first theoretical predictions for superconductivity to be made. However, this theory only explained experimental observations—it did not allow the microscopic origins of the superconducting properties to be identified. This was done successfully by the BCS theory in 1957, from which the penetration depth and the Meissner effect result. However, some physicists argue that BCS theory does not explain the Meissner effect.
Paradigm for the Higgs mechanism
The Meissner superconductivity effect serves as an important paradigm for the generation mechanism of a mass M (i.e. a reciprocal range, where h is the Planck constant and c is the speed of light) for a gauge field. In fact, this analogy is an abelian example for the Higgs mechanism, which generates the masses of the electroweak
gauge particles in high-energy physics. The length is identical with the London penetration depth in the theory of superconductivity.
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- London, F. W. (1960). "Macroscopic Theory of Superconductivity". Superfluids. Structure of matter series. 1 (Revised 2nd ed.). Dover. ISBN 978-0-486-60044-4. By the man who explained the Meissner effect. pp. 34–37 gives a technical discussion of the Meissner effect for a superconducting sphere.
- Saslow, W. M. (2002). Electricity, Magnetism, and Light. Academic. ISBN 978-0-12-619455-5. pp. 486–489 gives a simple mathematical discussion of the surface currents responsible for the Meissner effect, in the case of a long magnet levitated above a superconducting plane.
- Tinkham, M. (2004). Introduction to Superconductivity. Dover Books on Physics (2nd ed.). Dover. ISBN 978-0-486-43503-9. A good technical reference.
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