Jump to content

Thallium(III) nitrate

From Wikipedia, the free encyclopedia

This is an old revision of this page, as edited by Fswitzer4 (talk | contribs) at 12:46, 9 June 2020 (Validated CAS and added FDA UNII). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

Thallium(III) nitrate
Names
IUPAC name
thallium(3+) trinitrate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.918 Edit this at Wikidata
UNII
  • InChI=1S/3NO3.Tl/c3*2-1(3)4;/q3*-1;+3 ☒N
    Key: KLBIUKJOZFWCLW-UHFFFAOYSA-N ☒N
  • [Tl+3].O=[N+]([O-])[O-].[O-][N+]([O-])=O.[O-][N+]([O-])=O
Properties
Tl(NO3)3
Molar mass 390.398
Appearance colorless solid
Melting point 103 °C (217 °F; 376 K)
Boiling point decomposes
decomposes
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 4: Very short exposure could cause death or major residual injury. E.g. VX gasFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
4
0
0
OX
Safety data sheet (SDS) Mallinckrodt Baker
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Thallium(III) nitrate, also known as thallic nitrate, is a thallium compound with chemical formula Tl(NO3)3.[1] It is normally found as the trihydrate. It is a colorless and highly toxic solid. It is a strong oxidizing agent useful in organic synthesis. Among its many transformations, it oxidizes methoxyl phenols to quinone acetals, alkenes to acetals, and cyclic alkenes to ring-contracted aldehydes.[2]

References

  1. ^ MSDS for thallium(III) nitrate[permanent dead link]
  2. ^ Mukund P. Sibi, Luiz F. Silva Jr., Vânia M. T. Carneiro "Thallium(III) Nitrate Trihydrate" Encyclopedia of Reagents for Organic Synthesis 2008 John Wiley & Sons. doi:10.1002/047084289X.rt085.pub2
Stub icon

This inorganic compound–related article is a stub. You can help Wikipedia by expanding it.

Retrieved from "https://en.wikipedia.org/w/index.php?title=Thallium(III)_nitrate&oldid=961608114"