List of gases: Difference between revisions
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|[[decafluorodiethyl ether]] perfluoro ether<ref>{{cite book |last1=Burns |first1=T. H. S. |last2=Bracken |first2=A. |title=Modern Inhalation Anesthetics |date=1972 |publisher=Springer Berlin Heidelberg |isbn=9783642650574 |page=413 |url=https://link.springer.com/chapter/10.1007/978-3-642-65055-0_19 |language=en |chapter=Exploratory and Newer Compounds}}</ref> |
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|CF<sub>3</sub>CF<sub>2</sub>OCF<sub>2</sub>CF<sub>3</sub> |
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|358-21-4 |
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|[[trifluoromethyl peroxonitrate]]<ref name=yaws/> |
|[[trifluoromethyl peroxonitrate]]<ref name=yaws/> |
Revision as of 06:14, 16 June 2018
This is a list of gases at standard conditions This means the substance boils at or below 25°C at 1 atmosphere pressure and is reasonably stable. "triple" means that is a triple point, and that the substance sublimes at one atmosphere pressure.
List
name | formula | boiling pt °C | melting pt °C | CAS No |
---|---|---|---|---|
Helium-3 | 3He | −269.96 | na | 14762-55-1 |
Helium 4 | 4He | −268.928 | na | 7440-59-7 |
Hydrogen | H2 | −252.879 | −259.16 | 1333-74-0 |
Neon | Ne | −246.046 | −248.59 | 7440-01-9 |
Nitrogen | N2 | −195.795 | −210.0 | 7727-37-9 |
Carbon monoxide | CO | −191.5 | −205.02 | 630-08-0 |
Fluorine | F2 | −188.11 | −219.67 | 7782-41-4 |
Argon | Ar | −185.848 | −189.34 | 7440-37-1 |
Oxygen | O2 | −182.962 | −218.79 | 7782-44-7 |
Methane | CH4 | −182.5 | −164.00 | 74-82-8 |
Krypton | Kr | −153.415 | −157.37 | 7439-90-9 |
Nitric oxide | NO | −151.74 | −163.6 | 10102-43-9 |
Fluorine monoxide | F2O | −144.3 | −223.8 | 7783-41-7 |
Tetrafluoromethane | CF4 | −127.8 | −183.6 | 75-73-0 |
Nitrogen trifluoride | NF3 | −128.74 | −206.79 | 7783-54-2 |
Silane | SiH4 | −111.9 | −185 | 7803-62-5 |
trans-Difluorodiazine | N2F2 | −111.45 | −172 | 13776-62-0 |
Ozone | O3 | −111.35 | −193 | 10028-15-6 |
Xenon | Xe | −108.099 | −111.75 | 7440-63-3 |
cis-Difluorodiazine | N2F2 | −105.75 | 13812-43-6 | |
Ethylene | CH2=CH2 | −103.7 | −169.2 | 74-85-1 |
Phosphorus(III) fluoride | PF3 | −101.8 | −151.5 | 7783-55-3 |
Chlorine fluoride | ClF | −101.1 | −155.6 | 7790-89-8 |
Boron trifluoride | BF3 | −99.9 | −126.8 | 7637-07-2 |
Fluorosilane | SiH3F | −98.6 | 13537-33-2 | |
Trifluorosilane | SiHF3 | −95 | −131 | 13465-71-9 |
trifluoromethylhypofluorite[1] | CF3OF | −95 | −215 | 373-91-1 |
Diborane | B2H6 | −92.49 | −164.85 | 19287-45-7 |
Acetylene | CH≡CH | −84.7 | −81.5 | 74-86-2 |
Ethane | CH3CH3 | −88.5 | −182.8 | 74-84-0 |
Germane | GeH4 | −88.1 | −165 | 7782-65-2 |
Nitrous oxide | N2O | −88.48 | −90.8 | 10024-97-2 |
Phosphine | PH3 | −87.75 | −133.8 | 7803-51-2 |
Trifluoramine oxide | NOF3 | −87.5 | −161 | 13847-65-9 |
Tetrafluorosilane | SiF4 | −86 | −90.2 | 7783-61-1 |
Trifluoronitrosomethane | CF3NO | −85 | −196.6 | 334-99-6 |
Hydrogen chloride | HCl | −85 | −114.17 | 7647-01-0 |
1,1-Difluoroethene | CF2:CH2 | −85.5 | −144 | 75-38-7 |
Phosphorus(V) fluoride | PF5 | −84.6 | −93.8 | 7647-19-0 |
Carbonyl fluoride | COF2 | −84.5 | −111.2 | 353-50-4 |
Trifluoromethane | CHF3 | −82.1 | −155.2 | 75-46-7 |
Chlorotrifluoromethane | CClF3 | −81.5 | −181 | 75-72-9 |
bis(difluoroboryl)methane[1] | BF2CF2BF2 | −81.4 ? | 55124-14-6 | |
Trifluoroisocyanomethane | CF3NC | −80 | 105879-13-8 | |
Difluoromethylborane | CH3BF2 | −78.5 | 373-64-8 | |
Carbon dioxide | CO2 | −78.464 | −56.561 | 124-38-9 |
Fluoromethane | CH3F | −78.4 | −137.8 | 593-53-3 |
Hexafluoroethane | CF3CF3 | −78.1 | −100.015 | 76-16-4 |
Difluorosilane | SiH2F2 | −77.8 | −122 | 13824-36-7 |
Tetrafluoroethene | CF2=CF2 | −76 | −131.14 | 116-14-3 |
Fluoroacetylene | FCCH | −74 | −196 | 2713-09-9 |
Tetrafluorohydrazine | N2F4 | −74 | −164.5 | 10036-47-2 |
Nitryl fluoride | NO2F | −72.4 | −166 | 10022-50-1 |
Fluoroethene | CH2FCH3 | −72 | −160.5 | 75-02-5 |
Chlorotrifluorosilane | SiClF3 | −70 | −138 | 14049-36-6 |
Trifluoroacetonitrile | CF3CN | −68.8 | 353-85-5 | |
Nitrogen chloride difluoride | NClF2 | −67 | −195 | 13637-87-1 |
Hydrogen bromide | HBr | −66.38 | −86.80 | 10035-10-6 |
Borane carbonyl | BH3CO | −64 | −137 | 13205-44-2 |
Sulfur hexafluoride | SF6 | −63.8 | −49.596 triple | 2551-62-4 |
Arsine | AsH3 | −62.5 | −166 | 7784-42-1 |
thiocarbonyl fluoride[2] | CSF2 | −62.1 | −163.5 | 420-32-6 |
Radon | Rn | −61.7 | −71 | 10043-92-2 |
difluorocyanamide[1][3] | NF2CN | −61 | −196 | 7127-18-6 |
Nitrosyl fluoride | ONF | −59.9 | −132.5 | 7789-25-5 |
Hydrogen sulfide | H2S | −59.55 | −85.5 | 7783-06-4 |
Bromotrifluoromethane | CBrF3 | −57.75 | −167.78 | 75-63-8 |
Difluoroaminooxyperfluoromethane[1][4] | CF3ONF2 | −57.63 | 4217-93-0 | |
Methylsilane | CH3SiH3 | −57.5 | −156.5 | 992-94-9 |
Difluorine dioxide | F2O2 | −57 dec | −163.5 | 7783-44-0 |
Sulfuryl fluoride | SO2F2 | −55.4 | −135.8 | 2699-79-8 |
trans-1,2-Difluoroethene | CHF=CHF | −53.1 | 1630-78-0 | |
Trifluoroethene | CF2=CHF | −53 | 359-11-5 | |
Arsenic(V) fluoride | AsF5 | −52.8 | −79.8 | 7784-36-3 |
Phosphorothioc trifluoride | PSF3 | −52.25 | −148.8 | 2404-52-6 |
Difluoromethane | CH2F2 | −52 | −136 | 75-10-5 |
difluoroamino carbonyl fluoride[5][6] | F2NCOF | −52 | −152.2 | 2368-32-3 |
Stannane | SnH4 | −51.8 | −146 | 2406-52-2 |
Carbon oxysulfide | OCS | −50.2 | −138.8 | 463-58-1 |
Ketene | −49.7 | −151 | 463-51-4 | |
Sulfur fluoride oxide | SOF4 | −48.5 | −99.6 | 13709-54-1 |
3,3,3-Trifluoro-1-propyne | CF3CCH | −48.3 | 661-54-1 | |
Pentafluoroethane | CF3CHF2 | −48.1 | −100.6 | 354-33-6 |
Propene | C3H6 | −47.6 | −185.2 | 115-07-1 |
Phosphorus(III) chloride difluoride | PClF2 | −47.3 | −164.8 | 14335-40-1 |
Carbonyl chloride fluoride | COClF | −47.2 | −148 | 353-49-1 |
1,1,1-Trifluoroethane | CF3CH3 | −47 | −111.8 | 420-46-2 |
trifluoromethylhypochlorite[1] | CF3OCl | −47 | −164 | 22082-78-6 |
Perchloryl fluoride | ClO3F | −46.75 | −147 | 7616-94-6 |
Selenium hexafluoride | SeF6 | −46.6 | −34.6 triple | 7783-79-1 |
Cyanogen fluoride | FCN | −46 | −82 | 1495-50-7 |
Fluorine nitrate | FNO3 | −46 | −175 | 7789-26-6 |
Pentafluoronitrosoethane[7] | C2F5NO | −45.7 | 354-72-3 | |
difluoromethylene dihypofluorite[8] | CF2(OF)2 | −45.8 | −142 | 16282-67-0 |
cis-1,2-Difluoroethene | CHF=CHF | −45 | 1630-77-9 | |
Thionyl fluoride | SOF2 | −43.8 | −110.5 | 7783-42-8 |
Phosphorus(V) chloride tetrafluoride | PClF4 | −43.4 | −132 | 13498-11-8 |
Methyldiborane | CH3B2H5 | −43 | 23777-55-1 | |
Propane | C3H8 | −42.25 | −187.7 | 74-98-6 |
Hydrogen selenide | HSe | −41.25 | −65.73 | 7783-07-5 |
Chlorodifluoromethane | CHClF2 | −40.7 | −175.42 | 75-45-6 |
Sulfur tetrafluoride | SF4 | −40.45 | −125 | 7783-60-0 |
hexafluorodiazomethane cis[9] | CF3NNCF3 | −40 | −127 | 73513-59-4 |
Phosphoryl fluoride | POF3 | −39.7 sub | −39.1 triple | 13478-20-1 |
Chloropentafluoroethane | CF3CClF2 | −39.1 | −99 | 76-15-3 |
Tellurium hexafluoride | TeF6 | −38.9 | −37.6 triple | 7783-80-4 |
(Trifluoromethyl)silane | CF3SiH3 | −38.3 | −124 | 10112-11-5 |
heptafluoroethanamine[1] | C2F5NF2 | −38.1 | −183 | 354-80-3 |
trifluoromethanethiol[10] | CF3SH | −37.99 | −157.11 | 1493-15-8 |
Fluoroethane | CH3CH2F | −37.7 | −143.2 | 353-36-6 |
Bis(trifluoromethyl)peroxide | CF3OOCF3 | −37 | 927-84-4 | |
perfluorodimethylamine[11] | (CF3)2NF | −37 | 359-62-6 | |
Perfluoropropane | C3F8 | −36.8 | −147.7 | 76-19-7 |
Germanium(IV) fluoride | GeF4 | −36.5 | −15 triple | 7783-58-6 |
Cyclopropene | C3H4 | −36 | 2781-85-3 | |
Trifluoromethyl fluoroformate[12] | CF3OC(O)F | −36 | −120 | 3299-24-9 |
trifluoromethyl isocyanate[13] | CF3NCO | −36 | 460-49-1 | |
Hydrogen iodide | HI | −35.5 | −50.76 | 10034-85-2 |
Sulfur fluoride hypofluorite | SOF6 | −35.1 | −86 | 15179-32-5 |
Trifluoromethyl difluoromethyl ether | CF3OCHF2 | −35.0 | −157 | 3822-68-2 |
Propadiene = allene | CH2=C=CH2 | −34.8 | −136 | 463-49-0 |
Chlorine | Cl2 | −34.04 | −101.5 | 7782-50-5 |
trifluoromethyl fluoroformate[1][14] | CF3OC(O)F | −34 | 3299-24-9 | |
Tetrafluorodiborane | B2F4 | −34 | −56 | 13965-73-6 |
Ammonia | NH3 | −33.33 | −77.73 | 7664-41-7 |
Trifluoronitromethane[15] | CF3NO2 | −32 | 335-02-4 | |
Dichlorodifluorosilane | SiCl2F2 | −32 | −44 | 18356-71-3 |
(Difluoroamino)difluoroacetonitrile[16] | NF2C2CN | −32 | 5131-88-4 | |
Hexafluoromethanediamine[1][17] | (NF2)2CF2 | −31.9 | −161.9 | 4394-93-8 |
bis(trifluoromethyl)diazene trans[1] | CF3NNCF3 | −31.1 | 372-63-4 | |
Cyclopropane | C3H6 | −31 | −127.6 | 75-19-4 |
Chlorosilane | SiH3Cl | −30.4 | −118 | 13465-78-6 |
Perfluoropropene | CF2=CFCF3 | −30.2 | −156.6 | 116-15-4 |
Chloroacetylene | HCCCl | −30 | −126 | 593-63-5 |
methyltrifluorosilane | CH3SiF3 | −30 | −73 | 373-74-0 |
Dichlorodifluoromethane | CCl2F2 | −29.8 | −157.7 | 75-71-8 |
tetrafluorodiaziridine[1] | CF4N2 | −29 | 17224-09-8 | |
Perfluorooxetane | −28.6 | −117 | 425-82-1 | |
Chlorotrifluoroethene | CClF=CF2 | −28.3 | −158.14 | 79-38-9 |
2,3,3,3-tetrafluoropropene[1] | CF3CF=CH2 | −28.3 | −152.2 | 754-12-1 |
Methyldifluorophosphine | CH3PF2 | −28 | −110 | 753-59-3 |
Hexafluoropropene[1] | CF3CF=CF2 | −28 | 116-15-4 | |
Perfluoroacetone | CF3COCF3 | −27.4 | −125.45 | 684-16-2 |
Trifluoro(trifluoromethyl)oxirane | −27.4 | 428-59-1 | ||
Thiazyl trifluoride | N≡SF3 | −27.1 | −72.6 | 15930-75-3 |
Trifluoroacetyl chloride | CF3COCl | −27 | −146 | 354-32-5 |
3,3,3-Trifluoropropene | CF3CH=CH2 | −27 | 677-21-4 | |
Phosphonium chloride | PH4Cl | −27 sub | 24567-53-1 | |
Formyl fluoride | HCOF | −26.5 | −142.2 | 1493-02-3 |
1,1,1,2-Tetrafluoroethane | CF3CH2F | −26.1 | −103.296 | 811-97-2 |
trifluoromethyl trifluorovinyl ether[1] | −26 | 5930-63-2 | ||
Methyl trifluoromethyl ether | CF3OCH3 | −25.2 | −149.1 | 421-14-7 |
bis(Trifluoromethyl)nitroxide[18] | (CF3)2NO | −25 | −70 | 2154-71-4 |
Dimethyl ether | CH3OCH3 | −24.8 | −141.49 | 115-10-6 |
1,1,1,4,4,4-Hexafluoro-2-butyne | CF3C≡CCF3 | −24.6 | −117.4 | 692-50-2 |
1-Chloro-1-fluoroethene[1] | CClF=CH2 | −24.1 | 2317-91-1 | |
1,1-Difluoroethane | CHF2CH3 | −24.05 | −118.6 | 75-37-6 |
2-Fluoropropene | CH3CF=CH2 | −24 | 1184-60-7 | |
Borirane | C2H4BH | −24 | −129 | 39517-80-1 |
Chloromethane | CH3Cl | −23.8 | −97.4 | 74-87-3 |
trifluoronitrosoethylene[19] | CF2=CFNO | −23.7 | 2713-04-4 | |
Propyne | CH3CCH | −23.2 | −103.0 | 74-99-7 |
Diazomethane | CH3NNCH3 | −23 | −145 | 334-88-3 |
Methylgermane | CH3GeH3 | −23 | −158 | 1449-65-6 |
Difluoramine | NHF2 | −23 | −116 | 10405-27-3 |
1-Propen-1-one | CH3CH=CO | −23 | −80 | 6004-44-0 |
Vinylsilane | CH2=CHSiH3 | −22.8 | 7291-09-0 | |
Trifluoroiodomethane | CF3I | −22.5 | −110 | 2314-97-8 |
Ethynylsilane | HC≡CSiH3 | −22.5 | 1066-27-9 | |
chloromethane sulfonyl chloride[1] | CH2ClS(O)(O)Cl | −22 | 3518-65-8 | |
trifluoromethyl peroxychloride[1] | CF3OOCl | −22 | −132 | 32755-26-3 |
Carbon oxyselenide | COSe | −21.7 | −124.4 | 1603-84-5 |
Trifluoromethanesulfonyl fluoride | CF3SOF | −21.7 | 335-05-7 | |
Chloryl trifluoride | ClO2F3 | −21.6 | −81.2 | 38680-84-1 |
Carbonyl bromide fluoride | COBrF | −21 | 753-56-0 | |
Bromopentafluoroethane | C2BrF5 | −21 | 354-55-2 | |
Cyanogen | NCCN | −21 | −27.83 | 460-19-5 |
Methyl silyl ether | CH3OSiH3 | −21 | −98.5 | 2171-96-2 |
carbonic bromide fluoride[1] | CBrFO | −20.6 | 753-56-0 | |
trifluoromethylsulfur pentafluoride[1] | CF3SF5 | −20.4 | −87 | 373-80-8 |
Chlorotrifluorogermane | GeClF3 | −20.3 | −66.2 | 14188-40-0 |
Trimethylborane | (CH3)3B | −20.2 | −159.93 | 593-90-8 |
Dimethylsilane | CH3)2SiH2 | −20 | −150 | 1111-74-6 |
1,1,2,2-Tetrafluoroethane | −20 | −89 | 359-35-3 | |
Formaldehyde | H2CO | −19.1 | −92 | 50-00-0 |
Hexafluorodisilane | SiF3SiF3 | −19.1 | −18.7 triple | 13830-68-7 |
Sulfur chloride pentafluoride | SClF5 | −19.05 | −64 | 13780-57-9 |
1-Chloro-2,2-difluoroethene | CHCl=CF2 | −18.8 | −138.5 | 359-10-4 |
1,1,1,2,2-Pentafluoropropane | CF3CF2CH3 | −18 | 1814-88-6 | |
Difluoroamino sulfur pentafluoride[20] | NF2SF5 | −17.5 | 13693-10-2 | |
Stibine | SbH3 | −17 | −88 | 7803-52-3 |
1,1,2,2,3,3,3-Heptafluoropropane[21] | CF2HCF2CF3 | −17 | −148.5 | 2252-84-8 |
1,1,1,2,3,3,3-Heptafluoropropane | CF3CHFCF3 | −16.34 | −126.8 | 431-89-0 |
Phosphorus(III) bromide difluoride | PBrF2 | −16.1 | −133.8 | 15597-40-7 |
Methylphosphine | CH3PH2 | −16 | 593-54-4 | |
N,N-difluoromethanamine[1][22] | CH3NF2 | −16 | −114.8 | 753-58-2 |
Fluorine perchlorate | FOClO3 | −16 | −167.3 | 10049-03-3 |
1,3,3,3-tetrafluoropropene[1] | CF3CH=CHF | −16 | −104.53 | 1645-83-6 |
Disiloxane | (CH3)2O | −15.2 | −144 | 13597-73-4 |
cis-1-Fluoropropene | CH3CH=CHF | −15 | 19184-10-2 | |
trans-1-Fluoropropene | CH3CH=CHF | −15? | 20327-65-5 | |
Nitryl chloride | NO2Cl | −15 | −145 | 13444-90-1 |
Disilane | Si2H6 | −14.8 | −129.4 | 1590-87-0 |
Bromodifluoromethane | CHBrF2 | −14.6 | −145 | 1511-62-2 |
Chloroethene | CH2=CHCl | −13.8 | −153.84 | 75-01-4 |
Chlorine pentafluoride | ClF5 | −13.1 | −103 | 13637-63-3 |
1,1,1-Trifluoropropane | CF3CH2CH3 | −13 | 421-07-8 | |
1-Chloro-1,1,2,2-tetrafluoroethane | CClF2CH2 | −13 | −117 | 354-25-6 |
Carboimidic difluoride | CF2NH | −13 dec | −90 | 2712-98-3 |
Plumbane | PbH4 | −13 | 15875-18-0 | |
pentafluoroiodoethane[23] | CF3CF2I | −12.5 | −92 | 354-64-3 |
Methyl nitrite | CH3NO2 | −12 | −16 | 624-91-9 |
1-Chloro-1,2,2,2-tetrafluoroethane | CHClFCF3 | −11.96 | −199.15 | 2837-89-0 |
Isobutane | −11.7 | −159.42 | 75-28-5 | |
Trifluoromethoxy sulfur pentafluoride[24] | CF3OSF5 | −11 | −143 | 1873-23-0 |
Thiothionyl fluoride | SSF2 | −10.6 | −164.6 | 101947-30-2 |
Sulfur dioxide | SO2 | −10.05 | −75.5 | 7446-09-5 |
2-Fluoropropane | CH3CHFCH3 | −10 | 420-26-8 | |
pentafluoroethyl hypochlorite[25] | C2F5OCl | −10± | 22675-67-8 | |
Fluoroformyl sulfurpentafluoride[26] | SF5C(O)F | −10 | ||
trifluoromethyl fluoroformyl peroxide[27] | CF3OOC(O)F | −10~ | 16118-40-4 | |
Perfluorodimethoxymethane | −10 | −161 | 53772-78-4 | |
1-Chloro-1,1-difluoroethane | CClF2CH3 | −9.6 | −130.8 | 75-68-3 |
Chlorofluoromethane | CH2ClF | −9.1 | −133.0 | 593-70-4 |
Pentafluoroethyl isocyanate[28] | C2F5NCO | −9 | 356-74-1 | |
Selenium dioxydifluoride | SeO2F2 | −8.4 | −99.5 | 14984-81-7 |
Fluoro(trifluoro-methyl)diazine[1] | CF4N2O | −7.63 | 815-10-1 | |
Isobutene | −7.0 | −140.7 | 115-11-7 | |
3-Fluoropropene | −7 | 818-92-8 | ||
bis(trifluromethyl)amine[1] | (CF3)2NH | −7 | 371-77-7 | |
Ethoxytrifluorosilane[29] | CH3H2OSiF3 | −7 | −122 | 460-55-9 |
tris(trifluoromethyl)-amine[11] | (CF3)3N | −6.5 | 432-03-1 | |
Methylamine | CH3NH2 | −6.4 | −93.42 | 74-89-5 |
1-Butene | −6.3 | −185.33 | 106-98-9 | |
Diphosphorus tetrafluoride | P2F4 | −6.2 | −86.5 | 13824-74-3 |
Chloryl fluoride | ClO2F | −6 | −115 | 13637-83-7 |
Perfluorocyclobutane | −5.91 | −40.16 | 115-25-3 | |
Perfluoro-2-butene | −5.9 | 360-89-4 trans | ||
Nitrosyl chloride | ONCl | −5.55 | −59.4 | 2696-92-6 |
difluorocarbamoylchloride | CClF2NO | −5.5 | 16847-30-6 | |
1,3-Butadiene | −4.6 | −108.9 | 106-99-0 | |
Ethyltrifluorosilane[30] | CH3H2SiF3 | −4.4 | −105 | 353-89-9 |
difluoro-N-fluoromethanimine | F2C=NF | −4 | 338-66-9 | |
1,1-Dimethyldiborane | (CH3)2B(μ-H)2BH2 | −4 | −150.2 | 16924-32-6 |
Bromochlorodifluoromethane | −3.7 | −159.5 | 353-59-3 | |
Trifluoromethyl 1,1,2,2-tetrafluoroethyl ether | −3.3 | −141 | 2356-61-8 | |
1-Fluoropropane | −3 | −159 | 460-13-9 | |
Dimethylperoxide | −3 | −100 | 690-02-8 | |
Dichlorodifluorogermane | GeCl2F2 | −2.8 | −51.8 | 24422-21-7 |
Bromotrifluoroethene | CBrF=CF2 | −2.5 | 598-73-2 | |
trifluoromethane sulfnyl fluoride[1] | CF3SOF | −2.5 | 812-12-4 | |
Perfluorobutane | −2.1 | −129 | 355-25-9 | |
Hydrogen telluride | H2Te | −2 | −49 | 7783-09-7 |
1-chloroheptafluoropropane[31] | CF3CF2CF2Cl | −2 | 422-86-6 | |
2-chloroheptafluoropropane[31] | CF3CFClCF3 | −2 | 76-18-6 | |
1,1,1,2,2,3-hexafluoropropane | CF3CF2CFH2 | −1.44 | −98.38 | 677-56-5 |
1,1,1,3,3,3-Hexafluoropropane | CF3CH2CF3 | −1.4 | −93.6 | 690-39-1 |
pentafluoroguanidine[32] | CF5N3 | −1 | 10051-06-6 | |
Heptafluoronitrosopropane[7] | C3F7NO | −0.7 | 354-72-3 | |
trifluoromethanesulfenylchloride[1] | CF3SCl | −0.6 | 421-17-0 | |
1,1,2,2,3,3-hexafluoropropane[1] | CHF2CF2CHF2 | −0.3 | −98.38 | 680-00-2 |
Butane | 0 | −140 | 106-97-8 | |
2,2-Difluoropropane | 0 | −104.8 | 420-45-1 | |
Perfluoroisobutane | C4F10 | 0 | 354-92-7 | |
Nitrosyl bromide | NOBr | 0 | −56 | 13444-87-6 |
Xenon tetroxide | XeO4 | 0 dec | −35.9 | 12340-14-6 |
trifluoromethylsulfonyl hypofluorite[33] | CF3SO2OF | 0 | −87 | |
trifluoromethyl chloroformate[34] | CF3OC(O)Cl | 0 | 23213-83-4 | |
decafluorodiethyl ether perfluoro ether[35] | CF3CF2OCF2CF3 | 0 | 358-21-4 | |
trifluoromethyl peroxonitrate[1] | CF3OON2 | 0.4 | 50311-48-3 | |
trans-2-Butene | 0.9 | −43.3 | 624-64-6 | |
Methylcyclopropane | 1 | −177.2 | 594-11-6 | |
bis(trifluoromethyl)phosphine[36] | (CF3)2PH | 1 | ||
Methylstannane | CH3Sn3 | 1.4 | 1631-78-3 | |
trans-Dimethyldiazene = azomethane | 1.5 | −78 | 503-28-6 | |
Bromosilane | SiH3Br | 1.9 | −94 | 13465-73-1 |
Methylarsine | CH3AsH2 | 2 | −143 | 593-52-2 |
Hexafluorocyclobutene | C4F6 | 2 | −60 | 697-11-0 |
Chlorine monoxide | Cl2O | 2.2 | −120.6 | 7791-21-1 |
Cyclobutene | C4H6 | 2.5 | 822-35-5 | |
Difluorodimethylsilane | (CH3)2SiF2 | 2.5 | −87.5 | 353-66-2 |
1,1,1-trifluoroazomethane[1] | CF3NNCH3 | 2.5 | 690-21-1 | |
Trimethylamine | (CH3)3N | 2.8 | −117.1 | 75-50-3 |
1,1-Dichloro-1,2,2,2-tetrafluoroethane | CCl2CF3 | 3 | −56.6 | 374-07-2 |
Sulfur bromide pentafluoride | SBrF5 | 3.1 | −79 | 15607-89-3 |
1,1,2-Trifluoroethane | CHF2CH2F | 3.5 | −84 | 430-66-0 |
1,2-Dichloro-1,1,2,2-tetrafluoroethane | CClF2CClF2 | 3.6 | −92.52 | 76-14-2 |
cis-2-Butene | CH3CH=CHCH3 | 3.72 | −138.9 | 590-18-1 |
Bromomethane | CH2Br | 4 | −93.66 | 74-83-9 |
1,2-Dimethyldiborane | [(CH3)BH2]2 | 4 | −124.9 | 17156-88-6 |
Selenium chloride pentafluoride | SeClF5 | 4.5 | −19 | 34979-62-9 |
Trifluoromethyl phosphorodifluoridate[33] | CF3OP(O)F2 | 4.6 | −96.2 | 39125-43-4 |
bromoacetylene | C2HBr | 4.7 | 593-61-3 | |
Iodine heptafluoride | IF7 | 4.8 | 6.5 triple | 16921-96-3 |
dimethylchloroborane[1] | (CH3)2BCl | 4.9 | −39.9 | 1803-36-7 |
1,1,2,3,4,4-Hexafluoro-1,3-butadiene | 5.4 | −132 | 685-63-2 | |
Bis(difluoromethyl) ether | CHF2OCHF2 | 5.5 | 1691-17-4 | |
Methyl pentafluoroethyl ether | CH3OC2F5 | 5.6 | 22410-44-2 | |
tris(difluoroamine)fluoromethane[1] | (NF2)3CF | 5.6 | −136.9 | 14362-68-6 |
1-Bromo-2,2-difluoro-ethylene[37] | CHBr=CF2 | 5.7 | ||
Methanethiol[1] | CH3SH | 5.95 | −123 | 74-93-1 |
1-Buten-3-yne | CH2CHC≡CH | 6 | 689-97-4 | |
Ethyl methyl ether | CH3OC2H5 | 6 | −113 | 540-67-0 |
Methyl vinyl ether | CH3OCH=CH2 | 6 | −122 | 107-25-5 |
1,1,1-Trifluoro-2-chloroethane | CF3CH2Cl | 6.1 | −105.5 | 75-88-7 |
1,1,1,2,3,3-Hexafluoropropane | CF3CH2CF3 | 6.2 | 431-63-0 | |
Phosphorothioc chloride difluoride | PSClF2 | 6.3 | −155.2 | 2524-02-9 |
Trimethylsilane | (CH3)3SiH | 6.7 | −153.9 | 993-07-7 |
Carbon suboxide | OCCCO | 6.8 | −111.3 | 504-64-3 |
2-Chloropentafluoropropene[21] | CF3CCl=CF2 | 6.8 | 2804-50-4 | |
Perfluoroisobutene | 7 | 382-21-8 | ||
1,1-Difluoropropane | CHF2CH2CH3 | 7-8 | 430-61-5 | |
Chloromethylsilane | CH5ClSi | 7 | −135 | 993-00-0 |
Phosphorus(V) dichloride trifluoride | PCl2F3 | 7.1 | −125 | 13454-99-4 |
Sulfuryl chloride fluoride | SO2ClF | 7.1 | −124.7 | 13637-84-8 |
Dimethylamine | (CH3)2NH | 7.3 | −93 | 124-40-3 |
3-chloropentafluoropropene[21] | CF3CF=CF2 | 7.4 | 79-47-0 | |
Carbonyl chloride | COCl2 | 7.5 | −127.77 | 75-44-5 |
Chloropentafluoroacetone | CClF2COCF3 | 7.8 | −133 | 79-53-8 |
1-Butyne | CH3CH2C≡CH | 8.08 | −125.7 | 107-00-6 |
Dichlorosilane | SiH2Cl2 | 8.3 | −122 | 4109-96-0 |
methyl chlorosilane[1] | CH3SiH2Cl | 8.7 | −134.1 | 993-00-0 |
Dichlorofluoromethane | CHCl2F | 8.92 | −135 | 75-43-4 |
Neopentane | (CH3)4C | 9.5 | −16.5 | 463-82-1 |
trifluoromethylperchlorate | CF3OClO3 | 9.5 | 52003-45-9 | |
1-Chloro-2-fluoroethene[1] | CClF=CH2 | 9.8 | 460-16-2 | |
1,3-Butadiyne | HC≡CC≡CH | 10 | −35 | 460-12-8 |
N-Nitroso-O,N-bis(trifluoromethyl)-hydroxylamine or O-Nitroso-bis(trifluoromethy1)hydroxylamine[38][39] |
CF3(CF3O)NNO or (CF3)2NONO |
10 | 367-54-4 | |
Ethylene oxide | 10.4 | −112.46 | 75-21-8 | |
1,2-Difluoroethane[1] | CH2FCH2F | 10.5 | −118.6 | 624-72-6 |
1,2-Butadiene = methylallene | 11 | −136.20 | 590-19-2 | |
Dichloromethylborane | CH3BCl2 | 11 | 7318-78-7 | |
Chlorine dioxide | ClO2 | 11 | −59 | 10049-04-4 |
2-Chloro-2,3,3,3-tetrafluoropropanoyl fluoride[40] | CF3CFClC(O)F | 11 | 28627-00-1 | |
Trifluoromethyl hydroperoxide[1][41] | CF3OOH | 11.3 | 16156-36-8 | |
Chlorine trifluoride | ClF3 | 11.75 | −76.34 | 7790-91-2 |
1-bromoheptafluoropropane[31] | CF3CF2CF2Br | 12 | 422-85-5 | |
2-Fluoro-2-methylpropane | CH3(CH3)CFCH3 | 12.1 | 353-61-7 | |
Trichlorofluorosilane | SiCl3F | 12.25 | 14965-52-7 | |
Chloroethane | CH3CH2Cl | 12.27 | −138 | 75-00-3 |
Cyclobutane | C4H8 | 12.5 | −90.7 | 287-23-0 |
Cyanogen chloride | ClCN | 13 | −6.55 | 506-77-4 |
trans-1-Bromo-1,2-difluoroethylene[37] | CBrF=CFH | 13 | 358-99-6 | |
trifluoromethyl phosphine[1] | CF3PH2 | 13.1 | 420-52-0 | |
2,2,2-Trifluorodiazoethane[42] | CF2CHNN | 13.2 | 371-67-5 | |
2-chloro-1,1,1,2-tetrafluoropropane HCFC-244bb[43] | 13.23 | 421-73-8 | ||
pentafluoroethyl sulfur pentafluoride[44] | C2F5SF5 | 13.5 | ||
Phosphorus(III) dichloride fluoride | PCl2F | 13.85 | −144 | 15597-63-4 |
2-Chloro-1,1,1,3,3,3-hexafluoropropane[21] | CF3CHClCF3 | 14 | −120.8 | 51346-64-6 |
difluoro(difluorochloromethyl)amine | CClF2NF2 | 14.14 | 13880-71-2 | |
Nitrosyl bromide | ONBr | 14.5 | 13444-87-6 | |
N,N-difluoroethylamine[22] | CH3CH2NF2 | 14.9 | −150.3 | 758-18-9 |
Sulfur fluoride (FSSF) | FSSF | 15 | −133 | 13709-35-8 |
Trifluoromethyl phosphorodifluoroperoxoate[33] | CF3OOP(O)F2 | 15.5 | −88.6 | 39125-42-3 |
(Trifluoroacetyl)sulfur pentafluoride[26] | CF3C(O)SF5 | 15.6 | −112 | 82390-51-0 |
Vinyl bromide | CH2=CHBr | 15.8 | −137.8 | 593-60-2 |
1-Chloro-1,1,2-trifluoroethane | CClF2CH2F | 16 | 421-04-5 | |
cis-1-Bromo-1,2-difluoroethylene[37] | CBrF=CHF | 16 | ||
1-chloro-1-fluoroethane[1] | CHClFCH3 | 16.15 | 1615-75-4 | |
Fluorotrimethylsilane | (CH3)3SiF | 16.4 | 420-56-4 | |
Hexafluoroacetone imine[45] | CF3C(=NH)CF3 | 16.5± | −47 | 1645-75-6 |
dichloro(trifluoromethyl)amine[1] | CF3NCl2 | 16.6 | 13880-73-4 | |
Ethylamine | CH3CH2NH2 | 16.6 | −81 | 75-04-7 |
Bismuth hydride | BiH3 | 17 | −67 | 18288-22-7 |
Tungsten(VI) fluoride | WF6 | 17.1 | 1.9 | 7783-82-6 |
1-Chloro-1,2,2-trifluoroethane | CHClFCHF2 | 17.3 | 431-07-2 | |
Ethyl nitrite | C2H5NO2 | 17.5 | 109-95-5 | |
Tetraborane(10) | B4H10 | 18 | −120 | 18283-93-7 |
Bromofluoromethane | CH2BrF | 19 (CRC=23) | 373-52-4 | |
1,1-Dichloro-2,2-difluoroethene | CHCl2CHF2 | 19 | −116 | 79-35-6 |
perfluorovinylsulphur pentafluoride[46] | CF2=CFSF5 | 19 | 1186-51-2 | |
Trifluorovinyl isocyanate[47] | CF2=CFNCO | 19.5 | 41594-57-4 | |
Hydrogen fluoride | HF | 20 | −83.36 | 7664-39-3 |
Bromine fluoride | BrF | 20 dec | −33 | 13863-59-7 |
Perbromyl fluoride | BrO3F | 20 dec | −110 | 25251-03-0 |
3-Methyl-1-butene | 20.1 | −168.41 | 563-45-1 | |
Acetaldehyde | CH3CHO | 20.2 | −123.37 | 75-07-0 |
chlorotetrafluoro(trifluoromethyl)sulfur | CF3SClF4 | 20.2 | 42179-04-4 | |
trans-bis(trifluoromethyl)sulfur tetrafluoride[48] | CF3SF4CF3 | 20.5 | 42179-02-2 | |
1,1-Dimethylcyclopropane | 21 | −109.0 | 1630-94-0 | |
Acetyl fluoride | CH3C(O)F | 21 | −84 | 557-99-3 |
Perfluoroethyldimethylamine[11] | C2F5(CF3)2N | 21± | 815-28-1 | |
cis-1,2-Dichloro-1,2-difluoroethene | CClF=CClF | 21.1 | −119.6 | 598-88-9 |
Trifluoromethyl trifluoromethanesulfonate[49] | CF3SO2OCF3 | 21.2 | −108.2 | 3582-05-6 |
Nitrogen tetroxide | N2O4 | 21.15 | −9.3 | 10544-72-6 |
difluoroiodomethane | CHF2I | 21.5 | −122 | 1493-03-4 |
trans-1,2-Dichloro-1,2-difluoroethene | CClF=CClF | 22 | −93.3 | 27156-03-2 |
heptafluoroisopropyl hypochlorite[25] | (CF3)2CFOCl | 22 | 22675-68-9 | |
Perfluoroazoethane[13] | C2F5NNC2F5 | 22 | ||
bis(trifluoromethyl)sulfde[50] | (CF32S | 22.2 | 371-78-8 | |
Cyanic acid | HOCN | 23 | −86 | 420-05-3 |
2-Chloropropene | CH3CCl=CH2 | 23 | −137.4 | 557-98-2 |
1,2,2,2-Tetrafluoroethyl difluoromethyl ether | CF3CHFOCHF2 | 23 | 57041-67-5 | |
Carbonyl fluoride iodide | COFI | 23.4 | 1495-48-3 | |
1,2,2,2-tetrafluoroethyl difluoromethyl ether[1] | CF3CHFOCHF2 | 23.4 | 57041-67-5 | |
Trichlorofluoromethane | CCl3F | 23.77 | −110.48 | 75-69-4 |
Formic anhydride | C2O3H2 | 24 | 1558-67-4 | |
1-chloro-1,3,3,3-tetrafluoropropene[21] | CF3CH=CFCl | 24 | ||
1,1,2,2-tetrafluoro-1-nitro-2-nitrosoethane[51] | NO2CF2CF2NO | 24.2 | 679-08-3 | |
dibromodifluoromethane[1] | CBr2F2 | 24.45 | −141.5 | 75-61-6 |
heptafluoro-n-propyl isocyanate[7] | C3F7NCO | 24.5 | 87050-96-2 | |
Chloroheptafluorocyclobutane | C4ClF7 | 25 | −39.1 | 377-41-3 |
Dimethylphosphine | (CH3)2PH | 25 | 676-59-5 | |
Ethyl phosphine[52] | CH3CH2PH2 | 25 | 593-68-0 |
Known as gas
The following list has substances known to be gases, but with an unknown boiling point.
- Fluoramine
- bis(trifluoromethyl) trioxide CF3OOOCF3 boils between −10 and −20°C.[53]
- trifluoromethyl trifluoroethyl trioxide CF3OOOCF2CF3 boils between 10 and 20°[53]
- bis-trifluoromethyl carbonate boils between −10 and +10°[54] possibly +12, freezing −60°[55]
- Difluorodioxirane boils between −80 and −90°.[56]
- Difluoroaminosulfinyl fluoride F2NS(O)F is a gas but decomposes over several hours[57]
- trifluoromethylarsine[58]
- bis(trifluoromethy)larsine 371-74-4[58]
Possible
This list includes substances that may be gases. However reliable references are not available.
- cis-1-Fluoro-1-propene
- trans-1-Chloropropene ?
- cis-1-Chloropropene ?
- 2-Fluoroprop-1-ene
- 3-Fluoroprop-1-ene = allyl fluoride
- 1,1,1,2,3-Pentafluoropropane 20.0°
- 1,1,1,3,3-Pentafluoropropane
- 1,1,2,2,2-Pentafluoropropane
- 1,1,2,2,3-Pentafluoropropane
- 1,1,2,3,3-Pentafluoropropane
- Perfluoro-1-butene
- Perfluoro-1,3-butadiene 6-7°[59]
- Perfluoro-1,2-butadiene[60]
- Perfluoro-1,2,3-butatriene −5[61] polymerizes[62]
- Perfluoropent-2-ene
- Perfluoropent-1-ene 29-30°[63]
- Trifluoroacetyl fluoride −59 −159.5[64]
- tris(Trifluoromethyl)phosphine 17.3
- 2,3,3,3-Tetrafluoropropene −30°
- 1,3,3,3-Tetrafluoropropene −19°
- Trifluoromethanesulfonyl fluoride CF3SO2F −25°
- Trifluoromethanesulfenylfluoride CF3SF
- Difluorocarbamyl fluoride F2NCOF −52°
- N-Sulfinyltrifluoromethaneamine CF3NSO 18°
- (Chlorofluoromethyl)silane 373-67-1 274.37 K (1.22 °C)[1]
- difluoromethylsilane 420-34-8 237.56 K (−35.59 °C)[1]
- pentafluoroethyl sulfinyl fluoride C2F5S(O)F 20.8°[1]
- trifluoromethyl sulfenic trifloromethyl ester[65]
- bis(trifluoromethyl)sulfur difluoride 30341-38-9 21.2°[1]
- pentafluoro(penta-fluorethoxy)sulfur 900001-56-6 15°
- ethenol 557-75-5 10.5° =vinyl alcohol
- 1,1,1,2,2,3,4,4,4-nonafluorobutane 2-10° melt −129°[21]
- trans-2H-Heptafluoro-2-butene
- pentafluoroethylhypochlorite around −10°[25]
- trifluoromethyl pentafluoroethyl sulfide 6° 33547-10-3 [1]
- 1,1,1-Trifluoro-N-(trifluoromethoxy)methanamine 671-63-6 0.6°[1]
- 1-chloro-1,1,2,2,3,3-hexafluoropropane 422-55-9 16.7[1]
- 1-chloro-1,1,2,3,3,3-hexafluoropropane 359-58-0 17.15[1]
- 2-chloro-1,1,1,2,3,3-hexafluoropropane 51346-64-6 16.7°[1]
- 3-chloro-1,1,1,2,2,3-hexafluoropropane 422-57-1 16.7°[1]
- trifluormethyl 1,2,2,2-tetrafluoroethyl ether 2356-62-9 11°[1]
- 2-chloro-1,1,1,3,3-pentafluoropropane HFC-235da 134251-06-2 8°[1]
Near misses
This list includes substances that boil just above standard condition temperatures
- Dimethoxyborane 25.9 -130.6
- 1,4-Pentadiene 25.9
- 2-Bromo-1,1,1-trifluoroethane 26
- 1,2-Difluoroethane 26
- Hydrogen cyanide 26
- Tetramethylsilane 26.7
- Chlorosyl trifluoride 27
- 2,2-Dichloro-1,1,1-trifluoroethane 27.8
- Perfluoroethyl 2,2,2-trifluoroethyl ether 27.89
- Perfluoroethyl ethyl ether 28
- 2-Butyne 29
- Digermane 29
- Perfluoroisopropyl methyl ether 29
- Trifluoromethanesulfonyl chloride 29-32[66]
- Perfluoropentane 29.2
- Rhenium(VI) fluoride 33.8
- Chlorodimethylsilane 34.7
- 1,2-Difluoropropane 43
- 1,3-Difluoropropane 40-42
- Dimethylarsine 36
- Spiro[2.2]pentane 39
- Ruthenium(VIII) oxide 40
- Nickel carbonyl 42.1
- Trimethylphosphine 43
- Gallium(III) hydride liquid decompose at 0
- Nitroxyl unstable short lived
References
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- ^ Meyers, M. D.; Frank, S. (August 1966). "Difluorocyanamide". Inorganic Chemistry. 5 (8): 1455–1457. doi:10.1021/ic50042a040.
- ^ Shreeve, Jean'ne M.; Duncan, Leonard Clinton; Cady, George H. (October 1965). "Difluoroaminooxyperfluoromethane, CF3ONF2". Inorganic Chemistry. 4 (10): 1516–1517. doi:10.1021/ic50032a045.
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{{cite journal}}
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- ^ US Patent 3226418
- ^ HAUPTFLEISCH, John O. (2009). "SYNTHESIS OF TRIFLUORONITROMETHANE, CF3NO2: PHOTOCHEMICAL SCALE-UP AND A NEW THERMOGENERATION METHOD WITH A REFINED PURIFICATION TECHNIQUE" (PDF). University of Alabama. p. 28.
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- ^ Griffin, C. E.; Haszeldine, R. N. (1960). "279. Perfluoroalkyl derivatives of nitrogen. Part VIII. Trifluoronitrosoethylene and its polymers". Journal of the Chemical Society (Resumed): 1398. doi:10.1039/JR9600001398.
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- ^ a b c d e f Miller, William T.; Fried, John H.; Goldwhite, Harold (June 1960). "Substitution and Addition Reactions of the Fluoroölefins. IV. Reactions of Fluoride Ion with Fluoroölefins". Journal of the American Chemical Society. 82 (12): 3091–3099. doi:10.1021/ja01497a028.
- ^ a b Frazer, J.W. (November 1960). "Preparation of N,N-difluoromethylamine and N,N-difluoroethylamine". Journal of Inorganic and Nuclear Chemistry. 16 (1–2): 63–66. doi:10.1016/0022-1902(60)80088-7.
- ^ "Pentafluoroethyl iodide | C2F5I". www.chemspider.com.
- ^ Duncan, Leonard C.; Cady, George H. (June 1964). "The Preparation and Properties of Trifluoromethoxy Sulfur Pentafluoride [CF3OSF5] and cis-Bis(trifluoromethoxy)tetrafluorosulfur(VI) [(CF3 O)2SF4 ]". Inorganic Chemistry. 3 (6): 850–852. doi:10.1021/ic50016a015.
- ^ a b c Gould, Douglas E.; Anderson, Lowell Ray; Young, David Edward; Fox, William B. (March 1969). "Perhaloalkyl hypochlorites and pentafluorosulfur hypochlorite. I. Preparation and properties". Journal of the American Chemical Society. 91 (6): 1310–1313. doi:10.1021/ja01034a008.
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(help) - ^ Martin, E. L.; Sharkey, W. H. (October 1959). "1,1,4,4-Tetrafluoro-1,2,3-butatriene". Journal of the American Chemical Society. 81 (19): 5256–5258. doi:10.1021/ja01528a056.
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at position 70 (help) - ^ "Trifluoromethanesulfonyl chloride 164798". Sigma-Aldrich.