Paris Green

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For the Boardwalk Empire episode, see Paris Green (Boardwalk Empire).
Paris Green
Schweinfurter Grün.svg
Identifiers
CAS number 12002-03-8 YesY
PubChem 22833492
UN number 1585
Jmol-3D images Image 1
Properties
Molecular formula Cu(C2H3O2)2·3Cu(AsO2)2
Molar mass 1013.79444 g/mol
Appearance Emerald green crystalline powder
Density >1.1 g/cm3 (20 °C)
Melting point >345 °C
Boiling point decomposes
Solubility in water insoluble
Solubility soluble but unstable in acids
insoluble in alcohol
Hazards
MSDS CAMEO MSDS
EU classification Toxic T Dangerous for the Environment (Nature) N
R-phrases R23/25 R50/53
S-phrases (S1/2) S20/21 S28 S45 S60 S61
LD50 22 mg/kg
Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
 YesY (verify) (what is: YesY/N?)
Infobox references
Paris GreenHow to read this color infobox
About these coordinates     Color coordinates
Hex triplet #50C878
sRGBB  (rgb) (80, 200, 120)
CMYKH   (c, m, y, k) (60, 0, 40, 22)
HSV       (h, s, v) (140°, 60%, 78%)
Source [Unsourced]
B: Normalized to [0–255] (byte)
H: Normalized to [0–100] (hundred)

Paris Green (copper(II) acetate triarsenite) is an inorganic compound more precisely known as copper(II) acetoarsenite. It is a highly toxic emerald-green crystalline powder[2] that has been used as a rodenticide and insecticide, and also as a pigment, despite its toxicity. It is also used as a blue colorant for fireworks.[3] The color of Paris Green is said to range from a pale, but vivid, blue green when very finely ground, to a deeper true green when coarsely ground.

Preparation[edit]

Paris Green may be prepared by combining copper(II) acetate and arsenic trioxide.[4]

Uses[edit]

Insecticide[edit]

Paris Green was once used to kill rats in Parisian sewers, hence the common name.[citation needed] It was also used in America and elsewhere as an insecticide for produce, such as apples, around 1900, where it was blended with lead arsenate. This quite toxic mixture is said "to have burned the trees and the grass around the trees". Paris Green was heavily sprayed by airplane in Italy, Sardinia, and Corsica during 1944 and in Italy in 1945 to control malaria.[5]

Pigment[edit]

Paris Green was once a popular pigment used in artists' paints.

Related pigments[edit]

Similar natural compounds are the minerals chalcophyllite Cu18Al2(AsO4)3(SO4)3(OH)27·36(H2O), conichalcite CaCu(AsO4)(OH), cornubite Cu5(AsO4)2(OH)4·(H2O), cornwallite Cu5(AsO4)2(OH)4·(H2O), and liroconite Cu2Al(AsO4)(OH)4·4(H2O). These vivid minerals range from greenish blue to slightly yellowish green.

Scheele's green is a chemically simpler, less brilliant, and less permanent, synthetic copper-arsenic pigment used for a rather short time before Paris Green was first prepared, which was approximately 1814. It was popular as a wallpaper pigment and would degrade, with moisture and moulds, to arsine gas. Paris Green may have also been used in wallpaper to some extent and may have also degraded similarly. Both pigments were once used in printing ink formulations.

The ancient Romans used one of them, possibly conichalcite, as a green pigment. The Paris Green paint used by the Impressionists is said to have been composed of relatively coarse particles. Later, the chemical was produced with increasingly small grinds and without carefully removing impurities; its permanence suffered. It is likely that it was ground more finely for use in watercolors and inks, too.

See also[edit]

Gallery[edit]

Illustrations of Paris Green
Paris Green pigment 
Mixing "Paris green" and road dust preparatory to dusting streams and breeding places of mosquitoes during World War II 

References[edit]

  1. ^ "Health & Safety in the Arts -- Painting & Drawing Pigments". Environmental Management Division, City of Tucson AZ. Retrieved 2011-02-07. 
  2. ^ "Hazardous Substance Fact Sheet". NJ Dept. of Health and Senior Services. Retrieved 2011-02-07. 
  3. ^ "How to Use Copper in Pyro Star Compositions to Create Blue Fireworks Stars". Skylighter. Retrieved 2011-02-07. 
  4. ^ "H.Wayne Richardson, "Copper Compounds" in Ullmann's Encyclopedia of Industrial Chemistry 2005, Wiley-VCH, Weinheim. doi:10.1002/14356007.a07_567
  5. ^ Justin M. Andrews, Sc. D. (1963). "Preventive Medicine in World War II, Chapter V. North Africa, Italy, and the Islands of the Mediterranean". Washington, D.C. USA: Office of the Surgeon General, Department of the Army. p. 281. Retrieved 2008-09-30. 

External links[edit]