Isotopes of zirconium
Naturally occurring zirconium (Zr) is composed of four stable isotopes, and one extremely long-lived radioisotope (96Zr), which decays via double beta decay with the observed half-life of 2.0×1019 years [1]; it can also undergo single beta decay which is not yet observed, but the theoretically predicted value of T½ is 2.4×1020 years [2]. The second most stable radioisotope is 93Zr which has a half-life of 1.53 million years. Eighteen other radioisotopes have been observed. Most of these have half-lives that are less than a day except for 95Zr (64.02 days), 88Zr (63.4 days), and 89Zr (78.41 hours). The primary decay mode is electron capture for isotopes lighter than 92Zr, and the primary mode for heavier isotopes is beta decay.
Standard atomic mass: 91.224(2) u.
Zircornium is the heaviest element that can be formed from symmetric fusion, from either 45Sc, or 46Ca producing 90Zr and 92Zr respectively. All heavier elements are formed either through asymmetric fusion or during the collapse of supernovae.
Table
nuclide symbol |
Z(p) | N(n) | isotopic mass (u) |
half-life | nuclear spin |
representative isotopic composition (mole fraction) |
range of natural variation (mole fraction) |
---|---|---|---|---|---|---|---|
excitation energy | |||||||
78Zr | 40 | 38 | 77.95523(54)# | 50# ms [>170 ns] | 0+ | ||
79Zr | 40 | 39 | 78.94916(43)# | 56(30) ms | 5/2+# | ||
80Zr | 40 | 40 | 79.9404(16) | 4.6(6) s | 0+ | ||
81Zr | 40 | 41 | 80.93721(18) | 5.5(4) s | (3/2-)# | ||
82Zr | 40 | 42 | 81.93109(24)# | 32(5) s | 0+ | ||
83Zr | 40 | 43 | 82.92865(10) | 41.6(24) s | (1/2-)# | ||
84Zr | 40 | 44 | 83.92325(21)# | 25.9(7) min | 0+ | ||
85Zr | 40 | 45 | 84.92147(11) | 7.86(4) min | 7/2+ | ||
85mZr | 292.2(3) keV | 10.9(3) s | (1/2-) | ||||
86Zr | 40 | 46 | 85.91647(3) | 16.5(1) h | 0+ | ||
87Zr | 40 | 47 | 86.914816(9) | 1.68(1) h | (9/2)+ | ||
87mZr | 335.84(19) keV | 14.0(2) s | (1/2)- | ||||
88Zr | 40 | 48 | 87.910227(11) | 83.4(3) d | 0+ | ||
89Zr | 40 | 49 | 88.908890(4) | 78.41(12) h | 9/2+ | ||
89mZr | 587.82(10) keV | 4.161(17) min | 1/2- | ||||
90Zr | 40 | 50 | 89.9047044(25) | STABLE | 0+ | 0.5145(40) | |
90m1Zr | 2319.000(10) keV | 809.2(20) ms | 5- | ||||
90m2Zr | 3589.419(16) keV | 131(4) ns | 8+ | ||||
91Zr | 40 | 51 | 90.9056458(25) | STABLE | 5/2+ | 0.1122(5) | |
91mZr | 3167.3(4) keV | 4.35(14) µs | (21/2+) | ||||
92Zr | 40 | 52 | 91.9050408(25) | STABLE | 0+ | 0.1715(8) | |
93Zr | 40 | 53 | 92.9064760(25) | 1.53(10)E+6 a | 5/2+ | ||
94Zr | 40 | 54 | 93.9063152(26) | STABLE [>1.1E+17 a]] | 0+ | 0.1738(28) | |
95Zr | 40 | 55 | 94.9080426(26) | 64.032(6) d | 5/2+ | ||
96Zr | 40 | 56 | 95.9082734(30) | 20(4)E+18 a | 0+ | 0.0280(9) | |
97Zr | 40 | 57 | 96.9109531(30) | 16.744(11) h | 1/2+ | ||
98Zr | 40 | 58 | 97.912735(21) | 30.7(4) s | 0+ | ||
99Zr | 40 | 59 | 98.916512(22) | 2.1(1) s | 1/2+ | ||
100Zr | 40 | 60 | 99.91776(4) | 7.1(4) s | 0+ | ||
101Zr | 40 | 61 | 100.92114(3) | 2.3(1) s | 3/2+ | ||
102Zr | 40 | 62 | 101.92298(5) | 2.9(2) s | 0+ | ||
103Zr | 40 | 63 | 102.92660(12) | 1.3(1) s | (5/2-) | ||
104Zr | 40 | 64 | 103.92878(43)# | 1.2(3) s | 0+ | ||
105Zr | 40 | 65 | 104.93305(43)# | 0.6(1) s | |||
106Zr | 40 | 66 | 105.93591(54)# | 200# ms [>300 ns] | 0+ | ||
107Zr | 40 | 67 | 106.94075(32)# | 150# ms [>300 ns] | |||
108Zr | 40 | 68 | 107.94396(64)# | 80# ms [>300 ns] | 0+ | ||
109Zr | 40 | 69 | 108.94924(54)# | 60# ms [>300 ns] | |||
110Zr | 40 | 70 | 109.95287(86)# | 30# ms [>300 ns] | 0+ |
Notes
- Geologically exceptional samples are known in which the isotopic composition lies outside the reported range. The uncertainty in the atomic mass may exceed the stated value for such specimens.
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC which use expanded uncertainties.
References
- Isotope masses from Ame2003 Atomic Mass Evaluation by G. Audi, A.H. Wapstra, C. Thibault, J. Blachot and O. Bersillon in Nuclear Physics A729 (2003).
- Isotopic compositions and standard atomic masses from Atomic weights of the elements. Review 2000 (IUPAC Technical Report). Pure Appl. Chem. Vol. 75, No. 6, pp. 683-800, (2003) and Atomic Weights Revised (2005).
- Half-life, spin, and isomer data selected from these sources. Editing notes on this article's talk page.
- Audi, Bersillon, Blachot, Wapstra. The Nubase2003 evaluation of nuclear and decay properties, Nuc. Phys. A 729, pp. 3-128 (2003).
- National Nuclear Data Center, Brookhaven National Laboratory. Information extracted from the NuDat 2.1 database (retrieved Sept. 2005).
- David R. Lide (ed.), Norman E. Holden in CRC Handbook of Chemistry and Physics, 85th Edition, online version. CRC Press. Boca Raton, Florida (2005). Section 11, Table of the Isotopes.