Lithium tetrachloroaluminate
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IUPAC name
lithium tetrachloroaluminate
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Other names
lithium aluminium chloride; LAC
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Identifiers | |
3D model (JSmol)
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ChemSpider | |
ECHA InfoCard | 100.034.396 |
EC Number |
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PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
LiAlCl4 | |
Molar mass | 175.72 g·mol−1 |
Appearance | white crystals |
Melting point | 146 |
Hazards | |
GHS labelling: | |
Danger | |
H302, H312, H314, H332 | |
P260, P261, P264, P270, P271, P280, P301+P312, P301+P330+P331, P302+P352, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P310, P312, P321, P322, P330, P363, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Lithium tetrachloroaluminate (LAC, lithium aluminium chloride) is an inorganic compound, a tetrachloroaluminate of lithium, with the formula LiAlCl4.[1]
Solution of lithium tetrachloroaluminate in thionyl chloride is the liquid cathode and electrolyte of some lithium batteries, e.g. the lithium-thionyl chloride cell. Another cathode-electrolyte formulation is lithium tetrachloroaluminate+thionyl chloride+sulfur dioxide+bromine.
Other salts used in lithium battery electrolytes are lithium bromide, lithium perchlorate, lithium tetrafluoroborate, and lithium hexafluorophosphate; less common ones are lithium chloride, lithium iodide, lithium chlorate, lithium nitrate, lithium hexafluoroarsenate, lithium hexafluorosilicate, lithium bis(trifluoromethanesulfonyl)imide, and lithium trifluoromethanesulfonate.[2]
References
- ^ Perenthaler, E.; Schulz, Heinz; Rabenau, A. "Crystal structures of lithium tetrachloroaluminate and sodium tetrachloroaluminate as a function of temperature" Zeitschrift für Anorganische und Allgemeine Chemie (1982), 491, 259-65. doi:10.1002/zaac.19824910133
- ^ USA US20080280197 A1, Masaki Machida, "Spirally wound non-aqueous electrolyte secondary battery", published 13 Nov 2008, assigned to Sony Corporation