Dilithium peroxide, Lithium (I) peroxide
3D model (JSmol)
|Molar mass||45.881 g/mol|
|Appearance||fine, white powder|
|Melting point||195 °C (383 °F; 468 K)|
|Boiling point||Decomposes to Li2O|
|Solubility||insoluble in alcohol|
Std enthalpy of
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|what is ?)(|
Lithium peroxide is the inorganic compound with the formula Li2O2. It is a white, nonhygroscopic solid. Because of its high oxygen:mass and oxygen:volume ratios, the solid has been used to remove CO2 from the atmosphere in spacecraft.
- LiOH + H2O2 → LiOOH + 2 H2O
This lithium hydroperoxide has also been described as lithium peroxide monoperoxohydrate trihydrate (Li2O2·H2O2·3H2O). Dehydration of this material gives the anhydrous peroxide salt:
- 2 LiOOH → Li2O2 + H2O2 + 2 H2O
Li2O2 decomposes at about 450 °C to give lithium oxide:
- 2 Li2O2 → 2 Li2O + O2
The structure of solid Li2O2 has been determined by X-ray crystallography and density functional theory. The solid features an eclipsed "ethane-like" Li6O2 subunits with an O-O distance of around 1.5 Å.
It is used in air purifiers where weight is important, e.g., spacecraft to absorb carbon dioxide and release oxygen in the reaction:
- 2 Li2O2 + 2 CO2 → 2 Li2CO3 + O2
The reversible lithium peroxide reaction is the basis for a prototype lithium–air battery. Using oxygen from the atmosphere allows the battery to eliminate storage of oxygen for its reaction, saving battery weight and size.
The successful combination of a lithium-air battery overlain with an air-permeable mesh solar cell was announced by Ohio State University in 2014. The combination of two functions in one device (a "solar battery") is expected to reduce costs significantly compared to separate devices and controllers as are currently employed.
- "Physical Constants of Inorganic Compounds," in CRC Handbook of Chemistry and Physics, 91st Edition (Internet Version 2011), W. M. Haynes, ed., CRC Press/Taylor and Francis, Boca Raton, FL. (pp: 4-72).
- Speight, James G. (2005). Lange's Handbook of Chemistry (16th Edition). (pp: 1.40). McGraw-Hill. Online version available at: http://www.knovel.com/web/portal/browse/display?_EXT_KNOVEL_DISPLAY_bookid=1347&VerticalID=0
- Greenwood, Norman N.; Earnshaw, Alan (1984). Chemistry of the Elements. Oxford: Pergamon Press. p. 98. ISBN 0-08-022057-6.
- E. Dönges "Lithium and Sodium Peroxides" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 979.
- L. G. Cota and P. de la Mora "On the structure of lithium peroxide, Li2O2" Acta Crystallogr. 2005, vol. B61, pages 133-136. doi:10.1107/S0108768105003629
- Ulrich Wietelmann, Richard J. Bauer "Lithium and Lithium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry 2005, Wiley-VCH: Weinheim. doi:10.1002/14356007.a15_393.pub2
- Girishkumar, G.; B. McCloskey; AC Luntz; S. Swanson; W. Wilcke (July 2, 2010). "Lithium- air battery: Promise and challenges". The Journal of Physical Chemistry Letters. 1 (14): 2193–2203. doi:10.1021/jz1005384.
-  Patent-pending device invented at The Ohio State University: the world’s first solar battery.