Isotopes of tungsten
Naturally occurring tungsten (atomic symbol W) consists of five isotopes. Four are considered stable (182W, 183W, 184W, and 186W) and one is slightly radioactive, 180W, with an extremely long half-life of 1.8 ± 0.2 Ea (1018 years). On average, two alpha decays of 180W occur per gram of natural tungsten per year so for most practical purposes tungsten can be considered stable. Theoretically, all five can decay into isotopes of element 72 (hafnium) by alpha emission, but only 180W has been observed to do so. The other naturally occurring isotopes have not been observed to decay, and lower bounds for their half lives have been established:
- 182W, t1/2 > 7.7×1021 years
- 183W, t1/2 > 4.1×1021 years
- 184W, t1/2 > 8.9×1021 years
- 186W, t1/2 > 8.2×1021 years
Thirty-three artificial radioisotopes of tungsten have been characterized with mass numbers ranging from 157 to 194, the most stable of which are 181W with a half-life of 121.2 days, 185W with a half-life of 75.1 days, 188W with a half-life of 69.4 days and 178W with a half-life of 21.6 days. All of the remaining radioactive isotopes have half-lives of less than 24 hours, and most of these have half-lives that are less than 8 minutes. Tungsten also has 11 meta states with mass numbers of 158, 179, with 3, 180, with 2, 183, 185, 186, with 2, and 190, the most stable being 179m1W (t1/2 6.4 minutes).
Relative atomic mass: 183.84(1).
Table
nuclide symbol |
Z(p) | N(n) | isotopic mass (u) |
half-life[n 1] | decay mode(s)[1][n 2] |
daughter isotope(s)[n 3] |
nuclear spin |
representative isotopic composition (mole fraction) |
range of natural variation (mole fraction) |
---|---|---|---|---|---|---|---|---|---|
excitation energy | |||||||||
158W | 74 | 84 | 157.97456(54)# | 1.37(17) ms | α | 154Hf | 0+ | ||
158mW | 1889(8) keV | 143(19) µs | 8+ | ||||||
159W | 74 | 85 | 158.97292(43)# | 8.2(7) ms | α (82%) | 155Hf | 7/2−# | ||
β+ (18%) | 159Ta | ||||||||
160W | 74 | 86 | 159.96848(22) | 90(5) ms | α (87%) | 156Hf | 0+ | ||
β+ (14%) | 160Ta | ||||||||
161W | 74 | 87 | 160.96736(21)# | 409(16) ms | α (73%) | 157Hf | 7/2−# | ||
β+ (23%) | 161Ta | ||||||||
162W | 74 | 88 | 161.963497(19) | 1.36(7) s | β+ (53%) | 162Ta | 0+ | ||
α (47%) | 158Hf | ||||||||
163W | 74 | 89 | 162.96252(6) | 2.8(2) s | β+ (59%) | 163Ta | 3/2−# | ||
α (41%) | 159Hf | ||||||||
164W | 74 | 90 | 163.958954(13) | 6.3(2) s | β+ (97.4%) | 164Ta | 0+ | ||
α (2.6%) | 160Hf | ||||||||
165W | 74 | 91 | 164.958280(27) | 5.1(5) s | β+ (99.8%) | 165Ta | 3/2−# | ||
α (.2%) | 161Hf | ||||||||
166W | 74 | 92 | 165.955027(11) | 19.2(6) s | β+ (99.96%) | 166Ta | 0+ | ||
α (.035%) | 162Hf | ||||||||
167W | 74 | 93 | 166.954816(21) | 19.9(5) s | β+ (>99.9%) | 167Ta | 3/2−# | ||
α (<.1%) | 163Hf | ||||||||
168W | 74 | 94 | 167.951808(17) | 51(2) s | β+ (99.99%) | 168Ta | 0+ | ||
α (.0319%) | 164Hf | ||||||||
169W | 74 | 95 | 168.951779(17) | 76(6) s | β+ | 169Ta | (5/2−) | ||
170W | 74 | 96 | 169.949228(16) | 2.42(4) min | β+(99%) | 170Ta | 0+ | ||
α (1%) | 166Hf | ||||||||
171W | 74 | 97 | 170.94945(3) | 2.38(4) min | β+ | 171Ta | (5/2−) | ||
172W | 74 | 98 | 171.94729(3) | 6.6(9) min | β+ | 172Ta | 0+ | ||
173W | 74 | 99 | 172.94769(3) | 7.6(2) min | β+ | 173Ta | 5/2− | ||
174W | 74 | 100 | 173.94608(3) | 33.2(21) min | β+ | 174Ta | 0+ | ||
175W | 74 | 101 | 174.94672(3) | 35.2(6) min | β+ | 175Ta | (1/2−) | ||
176W | 74 | 102 | 175.94563(3) | 2.5(1) h | EC | 176Ta | 0+ | ||
177W | 74 | 103 | 176.94664(3) | 132(2) min | β+ | 177Ta | 1/2− | ||
178W | 74 | 104 | 177.945876(16) | 21.6(3) d | EC | 178Ta | 0+ | ||
179W | 74 | 105 | 178.947070(17) | 37.05(16) min | β+ | 179Ta | (7/2)− | ||
179m1W | 221.926(8) keV | 6.40(7) min | IT (99.72%) | 179W | (1/2)− | ||||
β+ (.28%) | 179Ta | ||||||||
179m2W | 1631.90(8) keV | 390(30) ns | (21/2+) | ||||||
179m3W | 3348.45(16) keV | 750(80) ns | (35/2−) | ||||||
180W[n 4] | 74 | 106 | 179.946704(4) | 1.8(0.2)×1018 y | α | 176Hf | 0+ | 0.0012(1) | |
180m1W | 1529.04(3) keV | 5.47(9) ms | IT | 180W | 8− | ||||
180m2W | 3264.56(21) keV | 2.33(19) µs | 14− | ||||||
181W | 74 | 107 | 180.948197(5) | 121.2(2) d | EC | 181Ta | 9/2+ | ||
182W | 74 | 108 | 181.9482042(9) | Observationally Stable [n 5] | 0+ | 0.2650(16) | |||
183W | 74 | 109 | 182.9502230(9) | Observationally Stable [n 6] | 1/2− | 0.1431(4) | |||
183mW | 309.493(3) keV | 5.2(3) s | IT | 183W | 11/2+ | ||||
184W | 74 | 110 | 183.9509312(9) | Observationally Stable [n 7] | 0+ | 0.3064(2) | |||
185W | 74 | 111 | 184.9534193(10) | 75.1(3) d | β− | 185Re | 3/2− | ||
185mW | 197.43(5) keV | 1.597(4) min | IT | 185W | 11/2+ | ||||
186W | 74 | 112 | 185.9543641(19) | Observationally Stable [n 8] | 0+ | 0.2843(19) | |||
186m1W | 1517.2(6) keV | 18(1) µs | (7−) | ||||||
186m2W | 3542.8(21) keV | >3 ms | (16+) | ||||||
187W | 74 | 113 | 186.9571605(19) | 23.72(6) h | β− | 187Re | 3/2− | ||
188W | 74 | 114 | 187.958489(4) | 69.78(5) d | β− | 188Re | 0+ | ||
189W | 74 | 115 | 188.96191(21) | 11.6(3) min | β− | 189Re | (3/2−) | ||
190W | 74 | 116 | 189.96318(18) | 30.0(15) min | β− | 190Re | 0+ | ||
190mW | 2381(5) keV | <3.1 ms | (10−) | ||||||
191W | 74 | 117 | 190.96660(21)# | 20# s [>300 ns] |
3/2−# | ||||
192W | 74 | 118 | 191.96817(64)# | 10# s [>300 ns] |
0+ |
- ^ Bold for isotopes with half-lives longer than the age of the universe (nearly stable)
- ^ Abbreviations:
EC: Electron capture
IT: Isomeric transition - ^ Bold for stable isotopes, bold italics for nearly-stable isotopes (half-life longer than the age of the universe)
- ^ Primordial radionuclide
- ^ Believed to undergo α decay to 178Hf with a half-life over 7.7×1021 y
- ^ Believed to undergo α decay to 179Hf with a half-life over 4.1×1021 y
- ^ Believed to undergo α decay to 180Hf with a half-life over 8.9×1021 y
- ^ Believed to undergo α decay to 182Hf with a half-life over 8.2×1021 y
Notes
- Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
- Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC, which use expanded uncertainties.
References
- ^ "Universal Nuclide Chart". nucleonica.
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- Isotope masses from:
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- Isotopic compositions and standard atomic masses from:
- J. R. de Laeter; J. K. Böhlke; P. De Bièvre; H. Hidaka; H. S. Peiser; K. J. R. Rosman; P. D. P. Taylor (2003). "Atomic weights of the elements. Review 2000 (IUPAC Technical Report)". Pure and Applied Chemistry. 75 (6): 683–800. doi:10.1351/pac200375060683.
- M. E. Wieser (2006). "Atomic weights of the elements 2005 (IUPAC Technical Report)". Pure and Applied Chemistry. 78 (11): 2051–2066. doi:10.1351/pac200678112051.
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- Half-life, spin, and isomer data selected from the following sources. See editing notes on this article's talk page.
- G. Audi; A. H. Wapstra; C. Thibault; J. Blachot; O. Bersillon (2003). "The NUBASE evaluation of nuclear and decay properties" (PDF). Nuclear Physics A. 729: 3–128. Bibcode:2003NuPhA.729....3A. doi:10.1016/j.nuclphysa.2003.11.001.
- National Nuclear Data Center. "NuDat 2.1 database". Brookhaven National Laboratory. Retrieved September 2005.
{{cite web}}
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(help) - N. E. Holden (2004). "Table of the Isotopes". In D. R. Lide (ed.). CRC Handbook of Chemistry and Physics (85th ed.). CRC Press. Section 11. ISBN 978-0-8493-0485-9.
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