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Standard electrode potential (data page)

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  The values of standard electrode potentials are given in the table below in volts relative to the standard hydrogen electrode and are for the following conditions:

  • A temperature of 298.15 K (25 °C);
  • An effective concentration of 1 mol/L for each aqueous species or a species in a mercury amalgam;
  • A partial pressure of 101.325 kPa (absolute) (1 atm, 1.01325 bar) for each gaseous reagent. This pressure is used because most literature data are still given for this value rather than for the current standard of 100 kPa.
  • An activity of unity for each pure solid, pure liquid, or for water (solvent).
  • Although many of the half cells are written for multiple electron transfers, the tabulated potentials are for a single electron transfer. All of the reactions should be divided by the stoichiometric coefficient for the electron to get the corresponding corrected reaction equation.
  • Divide the potentials by 0.059 V to get pe° values, which are necessary for Nernst Equation and other thermodynamic calculations.

Legend: (s) – solid; (l) – liquid; (g) – gas; (aq) – aqueous (default for all charged species); (Hg) – amalgam.

Half-reaction (V) Ref.
Oxidant Reductant
& -9
Zz 9
Sr+ + e Sr −4.10 [1]
Ca+ + e Ca −3.8 [1]
Pr3+ + e Pr2+ −3.1 [1]
3 N2(g) + 2H+ + 2e 2HN3(aq) −3.09 [2][3]
Li+ + e Li(s) −3.0401 [3][4]
N2(g) + 4H2O + 2e 2 NH2OH(aq) + 2OH −3.04 [2]
Cs+ + e Cs(s) −3.026 [3]
Ca(OH)2 + 2e Ca + 2 OH −3.02 [1]
Er3+ + e Er2+ −3.0 [1]
Ba(OH)2 + 2e Ba + 2 OH −2.99 [1]
Rb+ + e Rb(s) −2.98 [3]
K+ + e K(s) −2.931 [3]
Ba2+ + 2e Ba(s) −2.912 [3]
La(OH)3(s) + 3e La(s) + 3OH −2.90 [3]
Fr+ + e Fr −2.9 [1]
Sr2+ + 2e Sr(s) −2.899 [3]
Sr(OH)2 + 2e Sr + 2 OH −2.88 [1]
Ca2+ + 2e Ca(s) −2.868 [3][4]
Li+ + e LiC6(s) −2.84 [3]
Eu2+ + 2e Eu(s) −2.812 [3]
Ra2+ + 2e Ra(s) −2.8 [3]
Ho3+ + e Ho2+ −2.8 [1]
Bk3+ + e Bk2+ −2.8 [1]
Yb2+ + 2e Yb −2.76 [1]
Na+ + e Na(s) −2.71 [3][5]
Mg+ + e Mg −2.70 [1]
Nd3+ + e Nd2+ −2.7 [1]
Mg(OH)2 + 2e Mg + 2 OH −2.690 [1]
Sm2+ + 2e Sm −2.68 [1]
Be2O32− + 3 H2O + 4e 2 Be + 6 OH −2.63 [1]
Pm3+ + e Pm2+ −2.6 [1]
Dy3+ + e Dy2+ −2.6 [1]
No2+ + 2e No −2.50 [1]
HfO(OH)2 + H2O + 4e Hf + 4 OH −2.50 [1]
Th(OH)4 + 4e Th + 4 OH −2.48 [1]
Md2+ + 2e Md −2.40 [1]
Tm2+ + 2e Tm −2.4 [1]
La3+ + 3e La(s) −2.379 [3]
Y3+ + 3e Y(s) −2.372 [3]
Mg2+ + 2e Mg(s) −2.372 [3]
ZrO(OH)2(s) + H2O + 4e Zr(s) + 4OH −2.36 [3]
Pr3+ + 3e Pr −2.353 [1]
Ce3+ + 3e Ce −2.336 [1]
Er3+ + 3e Er −2.331 [1]
Ho3+ + 3e Ho −2.33 [1]
H2AlO3 + H2O + 3e Al + 4 OH −2.33 [1]
Nd3+ + 3e Nd −2.323 [1]
Tm3+ + 3e Tm −2.319 [1]
Al(OH)3(s) + 3e Al(s) + 3OH −2.31
Sm3+ + 3e Sm −2.304 [1]
Fm2+ + 2e Fm −2.30 [1]
Am3+ + e Am2+ −2.3 [1]
Dy3+ + 3e Dy −2.295 [1]
Lu3+ + 3e Lu −2.28 [1]
Tb3+ + 3e Tb −2.28 [1]
Gd3+ + 3e Gd −2.279 [1]
H2 + 2e 2 H −2.23 [1]
Es2+ + 2e Es −2.23 [1]
Pm2+ + 2e Pm −2.2 [1]
Tm3+ + e Tm2+ −2.2 [1]
Dy2+ + 2e Dy −2.2 [1]
Ac3+ + 3e Ac −2.20 [1]
Yb3+ + 3e Yb −2.19 [1]
Cf2+ + 2e Cf −2.12 [1]
Nd2+ + 2e Nd −2.1 [1]
Ho2+ + 2e Ho −2.1 [1]
Sc3+ + 3e Sc(s) −2.077 [6]
AlF63− + 3e Al + 6 F −2.069 [1]
Am3+ + 3e Am −2.048 [1]
Cm3+ + 3e Cm −2.04 [1]
Pu3+ + 3e Pu −2.031 [1]
Pr2+ + 2e Pr −2.0 [1]
Er2+ + 2e Er −2.0 [1]
Eu3+ + 3e Eu −1.991 [1]
Lr3+ + 3e Lr −1.96 [1]
Cf3+ + 3e Cf −1.94 [1]
Es3+ + 3e Es −1.91 [1]
Pa4+ + e Pa3+ −1.9 [1]
Am2+ + 2e Am −1.9 [1]
Th4+ + 4e Th −1.899 [1]
Fm3+ + 3e Fm −1.89 [1]
Np3+ + 3e Np −1.856 [1]
Be2+ + 2e Be −1.847 [1]
H2PO2 + e P + 2 OH −1.82 [1]
U3+ + 3e U −1.798 [1]
Sr2+ + 2e Sr/Hg −1.793 [1]
H2BO3 + H2O + 3e B + 4 OH −1.79 [1]
ThO2 + 4H+ + 4e Th + 2 H2O −1.789 [1]
HfO2+ + 2 H+ + 4e Hf + H2O −1.724 [1]
HPO32− + 2 H2O + 3e P + 5 OH −1.71 [1]
SiO32− + H2O + 4e Si + 6 OH −1.697 [1]
Al3+ + 3e Al(s) −1.662 [1]
Ti2+ + 2e Ti(s) −1.63 [5]
ZrO2(s) + 4H+ + 4e Zr(s) + 2H2O −1.553 [7]
Zr4+ + 4e Zr(s) −1.45 [7]
Ti3+ + 3e Ti(s) −1.37 [8]
TiO(s) + 2H+ + 2e Ti(s) + H2O −1.31
Ti2O3(s) + 2H+ + 2e 2 TiO(s) + H2O −1.23
Zn(OH)42− + 2e Zn(s) + 4OH −1.199 [7]
Mn2+ + 2e Mn(s) −1.185 [7]
Fe(CN)64− + 6H+ + 2 e Fe(s) + 6HCN(aq) −1.16 [9]
Te(s) + 2e Te2− −1.143 [10]
V2+ + 2e V(s) −1.13 [10]
Nb3+ + 3e Nb(s) −1.099
Sn(s) + 4H+ + 4e SnH4(g) −1.07
SiO2(s) + 4H+ + 4e Si(s) + 2H2O −0.91
B(OH)3(aq) + 3H+ + 3e B(s) + 3H2O −0.89
Fe(OH)2(s) + 2e Fe(s) + 2OH −0.89 [9]
Fe2O3(s) + 3H2O + 2e 2Fe(OH)2(s) + 2OH −0.86 [9]
TiO2+ + 2H+ + 4e Ti(s) + H2O −0.86
2H2O + 2e H2(g) + 2OH −0.8277 [7]
Bi(s) + 3H+ + 3e BiH3 −0.8 [7]
Zn2+ + 2e Zn(Hg) −0.7628 [7]
Zn2+ + 2e Zn(s) −0.7618 [7]
Ta2O5(s) + 10H+ + 10e 2 Ta(s) + 5H2O −0.75
Cr3+ + 3e Cr(s) −0.74
Ag2S(s) + 2e 2Ag(s) + S2-(aq) −0.69
[Au(CN)2] + e Au(s) + 2 CN −0.60
Ta3+ + 3e Ta(s) −0.6
PbO(s) + H2O + 2e Pb(s) + 2OH −0.58
2 TiO2(s) + 2H+ + 2e Ti2O3(s) + H2O −0.56
Ga3+ + 3e Ga(s) −0.53
U4+ + e U3+ −0.52 [11]
H3PO2(aq) + H+ + e P(white)[note 1] + 2H2O −0.508 [7]
H3PO3(aq) + 2H+ + 2e H3PO2(aq) + H2O −0.499 [7]
H3PO3(aq) + 3H+ + 3e P(red)[note 1] + 3H2O −0.454 [7]
Fe2+ + 2e Fe(s) −0.44 [5]
2 CO2(g) + 2H+ + 2e HOOCCOOH(aq) −0.43
Cr3+ + e Cr2+ −0.42
Cd2+ + 2e Cd(s) −0.40 [5]
GeO2(s) + 2H+ + 2e GeO(s) + H2O −0.37
Cu2O(s) + H2O + 2e 2 Cu(s) + 2OH −0.360 [7]
PbSO4(s) + 2e Pb(s) + SO42− −0.3588 [7]
PbSO4(s) + 2e Pb(Hg) + SO42− −0.3505 [7]
Eu3+ + e Eu2+ −0.35 [11]
In3+ + 3e In(s) −0.34 [10]
Tl+ + e Tl(s) −0.34 [10]
Ge(s) + 4H+ + 4e GeH4(g) −0.29
Co2+ + 2e Co(s) −0.28 [7]
H3PO4(aq) + 2H+ + 2e H3PO3(aq) + H2O −0.276 [7]
V3+ + e V2+ −0.26 [5]
Ni2+ + 2e Ni(s) −0.25
As(s) + 3H+ + 3e AsH3(g) −0.23 [10]
AgI(s) + e Ag(s) + I −0.15224 [7]
MoO2(s) + 4H+ + 4e Mo(s) + 2H2O −0.15
Si(s) + 4H+ + 4e SiH4(g) −0.14
Sn2+ + 2e Sn(s) −0.13
O2(g) + H+ + e HO2•(aq) −0.13
Pb2+ + 2e Pb(s) −0.126 [5]
WO2(s) + 4H+ + 4e W(s) + 2H2O −0.12
P(red) + 3H+ + 3e PH3(g) −0.111 [7]
CO2(g) + 2H+ + 2e HCOOH(aq) −0.11
Se(s) + 2H+ + 2e H2Se(g) −0.11
CO2(g) + 2H+ + 2e CO(g) + H2O −0.11
SnO(s) + 2H+ + 2e Sn(s) + H2O −0.10
SnO2(s) + 4H+ + 4e SnO(s) + 2H2O −0.09
WO3(aq) + 6H+ + 6e W(s) + 3H2O −0.09 [10]
P(white) + 3H+ + 3e PH3(g) −0.063 [7]
Fe3+ + 3e Fe(s) −0.04 [9]
HCOOH(aq) + 2H+ + 2e HCHO(aq) + H2O −0.03
2H+ + 2e H2(g) 0.0000 = 0
AgBr(s) + e Ag(s) + Br +0.07133 [7]
S4O62− + 2e 2 S2O32− +0.08
Fe3O4(s) + 8H+ + 8e 3 Fe(s) + 4H2O +0.085 [12]
N2(g) + 2H2O + 6H+ + 6e 2 NH4OH(aq) +0.092
HgO(s) + H2O + 2e Hg(l) + 2OH +0.0977
Cu(NH3)42+ + e Cu(NH3)2+ + 2 NH3 +0.10 [10]
Ru(NH3)63+ + e Ru(NH3)62+ +0.10 [11]
N2H4(aq) + 4H2O + 2e 2 NH4+ + 4OH +0.11 [2]
H2MoO4(aq) + 6H+ + 6e Mo(s) + 4H2O +0.11
Ge4+ + 4e Ge(s) +0.12
C(s) + 4H+ + 4e CH4(g) +0.13 [10]
HCHO(aq) + 2H+ + 2e CH3OH(aq) +0.13
S(s) + 2H+ + 2e H2S(g) +0.14
Sn4+ + 2e Sn2+ +0.15
Cu2+ + e Cu+ +0.159 [10]
HSO4 + 3H+ + 2e SO2(aq) + 2H2O +0.16
UO22+ + e UO2+ +0.163 [11]
SO42− + 4H+ + 2e SO2(aq) + 2H2O +0.17
TiO2+ + 2H+ + e Ti3+ + H2O +0.19
SbO+ + 2H+ + 3e Sb(s) + H2O +0.20
AgCl(s) + e Ag(s) + Cl +0.22233 [7]
H3AsO3(aq) + 3H+ + 3e As(s) + 3H2O +0.24
GeO(s) + 2H+ + 2e Ge(s) + H2O +0.26
UO2+ + 4H+ + e U4+ + 2H2O +0.273 [11]
Re3+ + 3e Re(s) +0.300
Bi3+ + 3e Bi(s) +0.308 [7]
Cu2+ + 2e Cu(s) +0.337 [10]
VO2+ + 2H+ + e V3+ + H2O +0.34
[Fe(CN)6]3− + e [Fe(CN)6]4− +0.36
Fc+ + e Fc(s) +0.4 [13]
O2(g) + 2H2O + 4e 4OH(aq) +0.401 [5]
H2MoO4 + 6H+ + 3e Mo3+ + 2H2O +0.43
CH3OH(aq) + 2H+ + 2e CH4(g) + H2O +0.50
SO2(aq) + 4H+ + 4e S(s) + 2H2O +0.50
Cu+ + e Cu(s) +0.520 [10]
CO(g) + 2H+ + 2e C(s) + H2O +0.52
I3 + 2e 3 I +0.53 [5]
I2(s) + 2e 2 I +0.54 [5]
[AuI4] + 3e Au(s) + 4 I +0.56
H3AsO4(aq) + 2H+ + 2e H3AsO3(aq) + H2O +0.56
[AuI2] + e Au(s) + 2 I +0.58
MnO4 + 2H2O + 3e MnO2(s) + 4OH 1.692
S2O32 − + 6H+ + 4e 2 S(s) + 3H2O +0.60
H2MoO4(aq) + 2H+ + 2e MoO2(s) + 2H2O +0.65
+ 2H+ + 2e +0.6992 [7]
O2(g) + 2H+ + 2e H2O2(aq) +0.70
Tl3+ + 3e Tl(s) +0.72
PtCl62− + 2e PtCl42− + 2 Cl +0.726 [11]
H2SeO3(aq) + 4H+ + 4e Se(s) + 3H2O +0.74
PtCl42− + 2e Pt(s) + 4 Cl +0.758 [11]
Fe3+ + e Fe2+ +0.77
Ag+ + e Ag(s) +0.7996 [7]
Hg22+ + 2e 2 Hg(l) +0.80
NO3(aq) + 2H+ + e NO2(g) + H2O +0.80
2FeO42− + 5H2O + 6e Fe2O3(s) + 10 OH +0.81 [9]
[AuBr4] + 3e Au(s) + 4 Br +0.85
Hg2+ + 2e Hg(l) +0.85
[IrCl6]2− + e [IrCl6]3− +0.87 [4]
MnO4 + H+ + e HMnO4 +0.90
2 Hg2+ + 2e Hg22+ +0.91 [10]
Pd2+ + 2e Pd(s) +0.915 [11]
[AuCl4] + 3e Au(s) + 4 Cl +0.93
MnO2(s) + 4H+ + e Mn3+ + 2H2O +0.95
NO3(aq) + 4H+ + 3e NO(g) + 2H2O(l) +0.958
[AuBr2] + e Au(s) + 2 Br +0.96
[HXeO6]3− + 2H2O + 2e + [HXeO4] + 4 OH +0.99 [14]
[VO2]+(aq) + 2H+ + e [VO]2+(aq) + H2O +1.0 [15]
H6TeO6(aq) + 2H+ + 2e TeO2(s) + 4H2O +1.02 [15]
Br2(l) + 2e 2 Br +1.066 [7]
Br2(aq) + 2e 2 Br +1.0873 [7]
IO3 + 5H+ + 4e HIO(aq) + 2H2O +1.13
[AuCl2] + e Au(s) + 2 Cl +1.15
HSeO4 + 3H+ + 2e H2SeO3(aq) + H2O +1.15
Ag2O(s) + 2H+ + 2e 2 Ag(s) + H2O +1.17
ClO3 + 2H+ + e ClO2(g) + H2O +1.18
[HXeO6]3− + 5H2O + 8 e Xe(g) + 11OH +1.18 [14]
Pt2+ + 2e Pt(s) +1.188 [11]
ClO2(g) + H+ + e HClO2(aq) +1.19
2 IO3 + 12H+ + 10e I2(s) + 6H2O +1.20
ClO4 + 2H+ + 2e ClO3 + H2O +1.20
O2(g) + 4H+ + 4e 2H2O +1.229 [5]
MnO2(s) + 4H+ + 2e Mn2+ + 2H2O +1.23
[HXeO4] + 3H2O + 6 e Xe(g) + 7OH +1.24 [14]
Tl3+ + 2e Tl+ +1.25
Cr2O72− + 14H+ + 6e 2 Cr3+ + 7H2O +1.33
Cl2(g) + 2e 2 Cl +1.36 [5]
CoO2(s) + 4H+ + e Co3+ + 2H2O +1.42
2 NH3OH+ + H+ + 2e N2H5+ + 2H2O +1.42 [2]
2 HIO(aq) + 2H+ + 2e I2(s) + 2H2O +1.44
BrO3 + 5H+ + 4e HBrO(aq) + 2H2O +1.45
β-PbO2(s) + 4H+ + 2e Pb2+ + 2H2O +1.460 [10]
α-PbO2(s) + 4H+ + 2e Pb2+ + 2H2O +1.468 [10]
2 BrO3 + 12H+ + 10e Br2(l) + 6H2O +1.48
2ClO3 + 12H+ + 10e Cl2(g) + 6H2O +1.49
HClO(aq) + H+ + 2e Cl(aq) + H2O +1.49 [1]
MnO4 + 8H+ + 5e Mn2+ + 4H2O +1.51
HO2 + H+ + e H2O2(aq) +1.51
Au3+ + 3e Au(s) +1.52
NiO2(s) + 4H+ + 2e Ni2+ + 2OH +1.59
Ce4+ + e Ce3+ +1.61
2 HClO(aq) + 2H+ + 2e Cl2(g) + 2H2O +1.63
Ag2O3(s) + 6H+ + 4e 2 Ag+ + 3H2O +1.67
HClO2(aq) + 2H+ + 2e HClO(aq) + H2O +1.67
Pb4+ + 2e Pb2+ +1.69 [10]
MnO4 + 4H+ + 3e MnO2(s) + 2H2O +1.70
AgO(s) + 2H+ + e Ag+ + H2O +1.77
H2O2(aq) + 2H+ + 2e 2H2O +1.78
Co3+ + e Co2+ +1.82
Au+ + e Au(s) +1.83 [10]
BrO4 + 2H+ + 2e BrO3 + H2O +1.85
Ag2+ + e Ag+ +1.98 [10]
S2O82− + 2e 2 SO42− +2.010 [7]
O3(g) + 2H+ + 2e O2(g) + H2O +2.075 [11]
HMnO4 + 3H+ + 2e MnO2(s) + 2H2O +2.09
XeO3(aq) + 6H+ + 6 e Xe(g) + 3H2O +2.12 [14]
H4XeO6(aq) + 8H+ + 8 e Xe(g) + 6 H2O +2.18 [14]
FeO42− + 3e + 8H+ Fe3+ + 4H2O +2.20 [16]
XeF2(aq) + 2H+ + 2e Xe(g) + 2HF(aq) +2.32 [14]
H4XeO6(aq) + 2H+ + 2e XeO3(aq) + 3H2O +2.42 [14]
F2(g) + 2e 2 F +2.87 [4][5][10]
F2(g) + 2H+ + 2e 2 HF(aq) +3.05 [10]
KrF2(aq) + 2e  Kr(g) + 2 F(aq) +3.27 [17]
  1. ^ a b Not specified in the indicated reference, but assumed due to the difference between the value -0.454 and that computed by (2×-0.499 + -0.508)/3 = -0.502 exactly matching the difference between the values for white (-0.063) and red (-0.111) phosphorus in equilibrium with PH3.

References

  1. ^ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae af ag ah ai aj ak al am an ao ap aq ar as at au av aw ax ay az ba bb bc bd be bf bg bh bi bj bk bl bm bn bo bp bq br bs bt bu Lide, David R., ed. (2006). CRC Handbook of Chemistry and Physics (87th ed.). Boca Raton, FL: CRC Press. ISBN 0-8493-0487-3.
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  11. ^ a b c d e f g h i j Bard, A.J., Faulkner, L.R.(2001). Electrochemical Methods. Fundamentals and Applications, 2nd edition (John Wiley and Sons Inc).
  12. ^ Marcel Pourbaix (1966). Atlas of Electrochemical Equilibria in Aqueous Solutions (NACE International, Houston, Texas; Cebelcor, Brussels).
  13. ^ Connelly, Neil G.; Geiger, William E. (1 January 1996). "Chemical Redox Agents for Organometallic Chemistry". Chemical Reviews. 96 (2): 877–910. doi:10.1021/cr940053x. PMID 11848774.
  14. ^ a b c d e f g WebElements Periodic Table of the Elements | Xenon | compounds information
  15. ^ a b Cotton, F. Albert; Wilkinson, Geoffrey; Murillo, Carlos A.; Bochmann, Manfred (1999), Advanced Inorganic Chemistry (6th ed.), New York: Wiley-Interscience, ISBN 0-471-19957-5
  16. ^ Redox Reactions, Western Oregon University website
  17. ^ http://acta.chem-soc.si/60/60-3-455.pdf
General

See also