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Potassium metabisulfite

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This is an old revision of this page, as edited by Piojo (talk | contribs) at 06:39, 5 December 2018 (Corrected the units for wine--we should not be measuring a powder by volume. Also suggested that the given amount is HIGH. It is almost at the maximum legal limit for red wine in the EU.). The present address (URL) is a permanent link to this revision, which may differ significantly from the current revision.

Potassium metabisulfite
Potassium metabisulfite
Names
Other names
Potassium pyrosulfite
Dipotassium disulfite
Potassium metabisulphite
Dipotassium disulphite
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.037.072 Edit this at Wikidata
E number E224 (preservatives)
RTECS number
  • TT4920000
UNII
  • InChI=1S/2K.H2O5S2/c;;1-6(2)7(3,4)5/h;;(H,1,2)(H,3,4,5)/q2*+1;/p-2 checkY
    Key: RWPGFSMJFRPDDP-UHFFFAOYSA-L checkY
  • InChI=1/2K.H2O5S2/c;;1-6(2)7(3,4)5/h;;(H,1,2)(H,3,4,5)/q2*+1;/p-2
    Key: RWPGFSMJFRPDDP-NUQVWONBAF
  • [K+].[K+].[O-]S(=O)S([O-])(=O)=O
Properties
K2O5S2
Molar mass 222.31 g·mol−1
Appearance White crystalline powder
Odor Pungent (sulfur dioxide)
Density 2.34 g/cm3 (solid)
Melting point 190 °C (374 °F; 463 K) decomposes
450 g/l (20 °C)
Solubility Insoluble in ethanol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
 Irritant, asthma risk
GHS labelling:
GHS05: CorrosiveGHS07: Exclamation mark
Danger
H315, H318, H335
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P310, P312, P321, P332+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
Safety data sheet (SDS) ICSC 1175
Related compounds
Other anions
 Potassium bisulfite
Potassium sulfite
Other cations
 Sodium metabisulfite
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Potassium metabisulfite, K2S2O5, also known as potassium pyrosulfite, is a white crystalline powder with a pungent sulfur odour. The main use for the chemical is as an antioxidant or chemical sterilant. It is a disulfite and is chemically very similar to sodium metabisulfite, with which it is sometimes used interchangeably. Potassium metabisulfite is generally preferred out of the two as it does not contribute sodium to the diet.

Potassium metabisulfite has a monoclinic crystal structure which decomposes at 190 °C, yielding potassium sulfite and sulfur dioxide:

K2S2O5(s) → K2SO3(s) + SO2(g)

Uses

It is used as a food additive, also known as E224.[1] It is restricted in use and may cause allergic reactions in some sensitive persons.[2]

Potassium metabisulfite is an inhibitor of the polyphenol oxidase enzyme.[3]

Wine

Potassium metabisulfite is a common wine or must additive, in which it forms sulfur dioxide gas (SO2). This both prevents most wild microorganisms from growing, and it acts as a potent antioxidant, protecting both the color and delicate flavors of wine.

A high dose would be 3 grams of potassium metabisulfite per six-gallon bucket of must (yielding roughly 75 ppm of SO2) prior to fermentation; then 6 grams per six-gallon bucket (150 ppm of SO2) at bottling. Most commercial wineries do not add more than 30 ppm at bottling.[citation needed] Some countries impose regulations on how much SO2 wines are allowed to contain.[4]

Winemaking equipment is sanitized by spraying with a 1% SO2 (2 tsp potassium metabisulfite per L) solution.

Beer

Potassium metabisulfite is sometimes used in the brewing industry to inhibit the growth of wild bacteria and fungi. This is called 'stabilizing'. It is also used to neutralize chloramine that has been added to tap water at the source as a disinfectant. It is used both by homebrewers and commercial brewers alike. It is not used as much for brewing beer, because the wort is almost always boiled, which kills most microorganisms. It can also be added to strike water (the water used to mash the malted barley) in order to remove chloramines which can cause phenolic off flavors in beer.

Other uses

  • Potassium metabisulfite is sometimes added to lemon juice as a preservative.
  • Potassium metabisulfite is used in the textile industry for dyeing and cotton printing.
  • Potassium metabisulfite is sometimes used to precipitate gold from solution in aqua regia (as an alternative to sodium sulfite).
  • It is a component of certain photographic developers and solutions used in photographic fixing.[5]
  • It is used as a bleaching agent in the production of Coconut cream.
  • It is used in some pickles as a preservative.
  • It is used in tint etching iron-based metal samples for microstructural analysis. [6]

Safety

Potassium metabisulfite causes skin irritation, serious eye irritation, and may cause respiratory irritation.[7] Hence, it should be manipulated under individual protective elements, such as gloves, coat, mask and glasses. Also, it should be manipulated under alkaline conditions as potassium metabisulfite reacts with acids, liberating toxic gases.

See also

References

  1. ^ List of E-number food additives
  2. ^ Metcalfe, Dean D.; Simon, Ronald A. (2003). Food allergy: adverse reactions to food and food additives. Malden, MA: Wiley-Blackwell. pp. 324–339. ISBN 978-0-632-04601-0.
  3. ^ Del Signore A, Romeoa F, Giaccio M (May 1997). "Content of phenolic substances in basidiomycetes". Mycological Research. 101 (5): 552–556. doi:10.1017/S0953756296003206.
  4. ^ https://www.thekitchn.com/the-truth-about-sulfites-in-wine-myths-of-red-wine-headaches-100878
  5. ^ "Potassium Metabisulfite".
  6. ^ "Color Metallography". 2011-05-04.
  7. ^ "Material Safety Data Sheet". Guidechem.
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